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10
pH 6
0
0 1 2 3 4 5 6 7 8 9 10 11 12 13 14
10
pH 6
0
0 1 2 3 4 5 6 7 8 9 10 11 12 13 14
10
pH 6
0
0 1 2 3 4 5 6 7 8 9 10 11 12 13 14
CALCULATION:
Titration 1:
8.57
= 2
= 4.29
pKa = -logKa
4.29 = -logKa
= 5.12910-5
Titration 2:
8.68
= 2
= 3.93
pKa = -logKa
3.93 = -logKa
= 1.17510-4
M1V1=M2V2
(0.1M)(10.5mL)=(M2)(10mL)
M2=0.105 M
M1V1=M2V2
(0.1M)(9.5mL)=(M2)(10mL)
M2=0.095 M
( 0.105 M ) +( 0.095 M )
2 = 0.1M
ERROR CALCULATION
The unknown monoprotic acid is identified to be ascorbic acid The pKa value for
ascorbic acid is 4.10 and its Ka value is 7.910-5 ,theoretically. Thus, the percentage errors for
each theoretical value to the calculated value are;