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Daily Test Series 2010 Day 2 16.03.10 P a g e | 1
Time: 20 min
CHEMISTRY
1. The nitrogen atom in each of the following tertiary amines may be removed as trimethyl amine by
repeated Hofmann eliminations (exhaustive methylation followed by heating with AgOH).Which
of the following amines requires the greater number of Hofmann sequences to accomplish this?
(a)
N
CH3
(b) N
N(CH3)2
(c)
CH3
(d) N
Ans (a)
Solution
I. CH3I
I. CH 3 I
II. AgOH,
N N II. AgOH, Δ
CH
I CH3I
CH3
II. AGOH,Δ N
N
H3C CH3
H3C CH3
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Daily Test Series 2010 Day 2 16.03.10 P a g e | 2
N2 , Z
2. X Y
H2O
CuSO 4
T (Blue colour) Y and T are respectively,
Colourless
(a) Mg(NO2)2, [Cu(NH3)4]SO4
(b) Mg3N2, [Cu(NH3)4]SO4
(c) MgO, [Cu(NH3)4]SO4
(d) Mg(NO3)2, [Mg(NH3)4]SO4
Ans (b)
Solution :
N 2 , NH 3 (Z)
Mg(X ) Mg 3 N 2 (Y )
H2O
Colourless
Cu NH 3 4 SO 4 (T)
(Bluecolour)
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Daily Test Series 2010 Day 2 16.03.10 P a g e | 3
MATHEMATICS
3. Let , , then which of the following statement is true?
4 2
(a) (sinθ) cosθ < (cosθ) cosθ < (cosθ) sinθ
(b) (cosθ) cosθ < (cosθ) sinθ < (sinθ) cosθ
(c) (cosθ) sinθ < (cosθ) cosθ < (sinθ) cosθ
(d) (cosθ) cosθ < (sinθ) cosθ < (cosθ) sinθ
Ans: (c)
Solution:
For / 4, / 2 , we have
1
0 cos sin 1
2
So, (cosθ) sinθ < (cosθ) cosθ and (cosθ) cosθ < (cosθ) cosθ combining we get
(cosθ) sinθ < (cosθ) cosθ < (sinθ) cosθ
4. If the sequence bn n 1, satisfies the recurrence relation bn 1 5bn 12n 15, n 1. Also
b1 = 25. Then b100 equal
(a) 5102 – 300
(b) 5101 – 300
(c) 5102 – 297
(d) 5101 – 297.
Ans: (d)
Solution:
The recursion relation for the sequence bn 1 5bn 12n 15
Can be transformed, with some effort, as
bn1 3n 5bn 3 n 1
Then we can apply the idea of G.P. to obtain
bn 1 3n 5n.b1 5n.25 5n 2
bn 1 1 5n 2 3n
b100 5101 3 99
5101 297
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Daily Testt Series 2010 Day 2 1
16.03.10 P a g e | 4
4
P
PHYSICS
10 rps
A b)
Ans
Solution:
W
When incidentt ray is rotatedd by an angle the reflecteed ray also rootates by in opposite sensse.
w
whose
normal is along x-axxis. The mirrror is movingg with velocitty i 4 j 2k cm/s . Finnd the
veelocity vectorr of the imagee.
a)) 2i 5 j 6k cm/s
b)) 2i 5 j 6k cm/s
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Daily Test Series 2010 Day 2 16.03.10 P a g e | 5
Solution:
We should consider velocities components along the normal to mirror only. Here normal is
along x-axis.
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