12/2/2016 FreundlichAdsorptionIsotherm|ChemistryLearning

FreundlichAdsorptionIsotherm
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WhatisFreundlichAdsorptionIsotherm?

In1909,FreundlichgaveanempiricalexpressionrepresentingtheisothermalvariationofAdsorptionofaquantityof
gas adsorbed by unit mass of solid adsorbent with pressure. This equation is known as Freundlich Adsorption
IsothermorFreundlichAdsorptionequation.

Wherexisthemassofthegasadsorbedonmassmoftheadsorbentatpressurepandk,nareconstantswhose
valuesdependuponadsorbentandgasatparticulartemperature.

ExplanationofFreundlichAdsorptionequation

Atlowpressure,extentofadsorptionisdirectlyproportionaltopressure(raisedtopowerone).

Athighpressure,extentofadsorptionisindependentofpressure(raisedtopowerzero).

Thereforeatintermediatevalueofpressure,adsorptionisdirectlyproportionaltopressureraisedtopower1/n.Here
nisavariablewhosevalueisgreaterthanone.

Usingconstantofproportionality,k,alsoknownasadsorptionconstantweget

TheaboveequationisknownasFreundlichadsorptionequation.

PlottingofFreundlichAdsorptionIsotherm

AsperFreundlichadsorptionequation

Takinglogbothsidesofequation,weget,

Theequationaboveequationiscomparablewithcomparablewithequationofstraightline,y=mx+cwhere,m
representsslopeofthelineandcrepresentsinterceptonyaxis.
Plottingagraphbetweenlog(x/m)andlogp,wewillgetastraightlinewithvalueofslopeequalto1/nandlogkas
yaxisintercept.

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12/2/2016 FreundlichAdsorptionIsotherm|ChemistryLearning

log(x/m)vs.logpgraph

LimitationofFreundlichAdsorptionIsotherm

ExperimentallyitwasdeterminedthatextentofadsorptionvariesdirectlywithpressuretillsaturationpressurePsis
reached. Beyond that point rate of adsorption saturates even after applying higher pressure. Thus Freundlich
AdsorptionIsothermfailedathigherpressure.

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