)Chem 109 Chapter 10(

Ques.
no. Question
1 Select the correct formula, which represent an organic compound

A NaCl B BaSO4 C HCl D C4H10

2 How many covalent bonds does carbon generally form in organic compounds?

A 2 B 3 C 4 D 6
3 Select element, whichrepresents as heteroatom in organic compounds.

A C B N C H D None
4 Identify the molecule, which have covalent bonding.

A NaCl B CH4 C Na2CO3 D H2O

5 When hydrocarbons are added to water, they are

A soluble B insoluble C Partially soluble D Convert to gas

6 Functional group Amide is:

A B C D
7 Identify the functional group in given organic compound, which is.

Carboxylic acid Ester C Aldehyde D Ketone

A B
8 Functional group which represents Alkenes is

Carbon-carbon Carbon-carbon Aldehyde group

A Hydroxyl group B triple bond
C double bond D
9 Identify thelone pairs electrons in CH3-O-CH3 organic molecule.

A 2 B 3 C 1 D 4

11 Which of the following is true for element Carbon?

A Monovalent B Divalent C Trivalent D Tetravalent

1
Ques.
no. Question
11 General molecular formula of Alkane is

A CnH2n-2 B CnH2n+2 C CnH2n D CnH2n+1

12 Numbers of Constitutional isomers of molecular formula C5H12 are..

A 2 B 3 C 4 D 5

13 Isomers are the compounds those must have same..

Molecular formula Physical properties

A Structural formula B Chemical Properties C D
14 Which structure has all of the hydrogens and lone pairs correctly added to the
compound shown below?

A B C D

15 Which represents a condensed structure for a four-carbon hydrocarbon?

A CH3CH2CH2CH3 B C4H10 C D

16 How many H atoms are bonded to the labeled carbons in the given structure?

C1 has 2Hs and C1 has 1H and C2 C1 has 2Hs and C1 has 1H and
A C2 has 2Hs B has no Hs
C C2 has 1H
D C2 has 1 H
17 How many total H atoms are present in the given organic structure?

A 12 H atoms B 18 H atoms C 17 H atoms D 19 H atoms

18 Classification of given hydrocarbon is as

Alkene Aromatic
A Alkyne B Alkane C D hydrocarbon

19 Classification of given hydrocarbon is as

Alkene Aromatic
A Alkyne B Alkane C D hydrocarbon

21 Select the compound which represent as an aldehyde?

C D
A B

2
Ques.
no. Question
21 Identify the organic compound that classified as an alcohol.
C D
A B
22 Identify the organic compound that classified as an alcohol.
C D
A B
23 Identify the organic compound that classified as an alcohol.

A Carboxylic acid B Ether C Ester D Ketone

24 The compound whose condensed structure is (CH3)3CCH2OH can be represented
as a skeletal structure as which of the following?

A B C D
25 Which structure is not possible?

A B C D
26 Which formula represents an inorganic compound?

CH3CO2CH2CH3 CaCl2
A CH3NHCH2CH3 B ClCH2CH2Cl C D
27 How many lone pairs of electrons are present but not shown in the molecule
below?

A 1 B 2 C 3 D 4

28 What is the condensed formula for the molecule shown below?

(CH3)4C
A CH3CCH3CH3CH3 B (CH3)2(CH2)2CH3 C D
29 The compound given below is classified as a/an..

A Ether B Amine C Amide D Aldehyde

31 How many covalent bonds does nitrogen typically form in organic compounds?

A 1 B 2 C 3 D 4

3
Ques.
no. Question
31 Which compound is most flammable?

A CH3CH2OH B NaCl C CO2 D HCl

32 How many hydrogen atoms are present in a cyclic alkane with six (6) carbon
atoms?
A 8 B 10 C 12 D 14
33 How many hydrogen atoms are present in an acyclic alkane with five (5) carbon
atoms?
A 8 B 10 C 12 D 14
34 Identify the formula, which represents an acyclicalkane.

A C10H20 B C12H26 C C10H18 D C9H18

35 Identify the formula, which represents a cyclic alkane.

A C11H20 B C10H18 C C9H20 D C10H20

36 Which of the following compounds is identical to the one shown below?

C D
A B

37 What is the IUPAC name of CH3CH2CH2CH2CH2CH3?

A Hexane B Heptane C Pentane D Butane

38 Which compound is a constitutional isomer of the one shown below?

A B C D

39 What is the IUPAC name of given compound?

2-Methyl-3- 3-Ethyl-2- 4-Ethyl-5-

A 4-Propylhexane B ethylhexane C methylhexane D methylheptane

41 What is the IUPAC name of given compound?

3,3-Dimethyl-4- 3-Ethyl-4- 3,3-Dimethyl-4-

A 4-Isopentylnonane B propylnonane C propylnonane D butylnonane

4
Ques.
no. Question
41 What is the IUPAC name of this compound?

3-Ethyl-5- 3-Ethyl-5- 3-Ethyl-2- 8-Ethyl-6-

A methyldecane B pentylhexane C pentylhexane D methyldecane

42 What is the IUPAC name of this compound?

Ethyl-2- 1-Ethyl-2- 1-Ethyl-2- Ethyl-methyl-

A methylcyclobutane B methylcyclopropane C methylcyclobutane D cyclopropane

43 Identify the structure of 2-methylhexane, which is..

(CH3)2CH(CH2)3CH3
A (CH3)2CHCH2CH2CH3 B (CH3)3CCH2CH2CH2CH3 C D
44 Identify the structure of 2-methylhexane, which is..

A B C D
45 Which alkane has the lowest boiling point?

A Ethane B Propane C Butane D Hexane

46 Which name is not a valid IUPAC name for an alkane?

2,3,4- 1-Ethyl-2- 1-Butyl-2- 5-Butyl-2-

A Trimethylhexane B butylpentane C ethylcyclopentane D methylnonane

47 Which compound has the lowest melting point?

CH3(CH2)5CH3 CH3(CH2)7CH3
A CH3(CH2)3CH3 B CH3(CH2)6CH3 C D
48 Which compound has the highest melting point?

CH3(CH2)5CH3 CH3(CH2)7CH3
A CH3(CH2)3CH3 B CH3(CH2)6CH3 C D
49 What is the IUPAC name of this molecule?

2-Ethyl-2,4- 2,4-Dimethyl-2- 3,3,5- 5-Ethyl-3,5-

A dimethylhexane B ethylhexane C Trimethylheptane D dimethylhexane

51 Fill in the blank "......... an atom or a group of atoms with characteristic

chemical and physical properties".
Stereoisomers Functional group
A Hydrocarbons B Constitutional isomers C D

5
Ques.
no. Question
51 Select the correct IUPAC name for: (CH3CH2)3CCH2CH2CH(CH3)2

5-Diethyl-2- 5,5-Diethyl-2- 2-Methyl-5,5- 3,3-Diethyl-6-

A methylheptane B methylheptane
C diethylheptane
D methylheptane
52 The IUPAC name of the following a cycloalkane is :

1,2-Dimethyl-1,2- 1,1-Diethyl-2,2- 1,2-Diethyl-1,2- 1,2-Diethyl-2-

A diethylcyclohexane B dimethylcyclohexane C dimethylcyclohexane D dimethylcyclohexane

53 Identify the labeled functional groups in the following compound.

1Amine, 2 alcohol, 1Amine, 2 ether, 3 1Amine, 2 alcohol, 1 Amine, 2 alcohol,

A 3 ketone B ester C 3 ester D 3 ether

54 Cyclohexane represents constitutional isomer for

3-Methyl-1-hexene 2-Methyl-2-pentene
A 1-Ethyl-2-pentene B 3-Methyl-2-pentyne C D
55 The following pair of compounds is classified as:

Identical molecules Not isomer

A Constitutional isomers B stereoisomers C D
56 Which of the following structures represents Neopentane?

C D
A B
Organic molecule which contain hetero atom is:

57 A CH -CH -CH -CH

3 2 B CH -O-CH -CH
2 3 3 2 3 C CH3-CH=CH-CH3
D CH3-CH=CH2

58 IUPAC name of the following compound is:

4-propyl-3- 4-propyl-5- 3-methyl-4- 4-ethyl-3-

A methylheptane B methylheptane
C propylheptane D methylheptane

59 The IUPAC name of the following compound is:

1-methyl-3- 1-ethyl-3- 1-ethyl-3-

A ethylcyclohexane B 3-ethyl-1-
methylcyclohexane
C methylcyclohexane D methylhexane

61 The IUPAC name of the following compound is:

1,1-diethyl-2- 1,2,3- 1-ethyl-2,2-

A
1,1-dimethyl-2-
ethylcyclopropane B methylcyclopropane C trimethylcyclopropane D dimethylcyclopropane

6
Ques.
no. Question
61 The IUPAC name of the following compound is.

1-ethyl-2,4,4- 1-ethyl-3,3,5- 1,1,3-trimethyl-4- 1,3,3-trimethyl-5-

A trimethylcyclopentane B trimethylcyclopentane C ethylcyclopentane D ethylcyclopentane

62 The IUPAC name of the following compound is.

(CH3)2CH-CH(CH3)2

1,1,2,2- 2,3-dimethyl butane 1,4-dimethylbutane

A Hexane
B tetramethylethane C D
63 The IUPAC name of the following compound is:

A 6-ethylnonane B 4-ethylnonane C 3-propyloctane D 6-propyloctane

64 General molecular formula of cycloalknaes is..

A CnH2n-2 B CnH2n+2 C CnH2n D CnH2n+1

65 . is a pairs Constitutional Isomer.

Ethanol & dimethyl Acetaldehyde &

A Butane &iso-pentane B Acetic acid & ethanol C ether D acetone

66 Alkanes are soluble in:

Inorganic solvent None of these

A Water B Organic solvent C D
67 Alkenes and alkanes are called ..

Saturated Unsaturated Aromatic Carbohydrates

A hydrocarbones B hydrocarbones C compounds D

7
 )Chem 109 Chapter 11(

Ques.
no. Question
1 Which types of compounds are saturated hydrocarbons?

Aromatic C Alkanes D Alkynes

A Alkenes B compounds
2 Which statement is true about Unsaturated Hydrocarbons

single covalent C Multiplebonds D All statement are

A bond B Alkane
(double, triple bonds) correct
3 General Molecular Formula and bond angle for Alkene is:

A CnH2nand 109 B CnH2n+2 and 120 C CnH2n-2 and 120 D CnH2n and 120

4 General molecular formula and bond angle for Alkyne are:

A CnH2n+2and 109 B CnH2nand 120 C CnH2n- 2 and 180 D CnH2n+2 and 180

5 General formula C20H38 is correspond to which of the following

A Alkanes B Alkenes C Alkynes D None of this

6 Alkene that has eleven carbons, general molecular formula is:

A C11H24 B C11H23 C C11H22 D C11H21

7 IUPAC name of the following compound is.

2,2-dimethyl-4- 4,4-dimethyl-1- C 2,2-dimethyl-4- D 4,4-dimethyl-1-

A pentene B pentene butene butene
8 IUPAC name of following compound is.
H 2C CH3

A Pentane B Pentene C Butene D 4-methyl-butene

9 IUPAC name of following compound is.

4-methyl-3- C 4-ethyl-3-heptene D 4-ethyl-4-heptene

A heptene B 4-methyl-4-heptene
11 Which is the molecular formula of an alkyne?

A C10H18 B C9H18 C C8H18 D C10H20

8
Ques.
no. Question
11 IUPAC name of following compound is.

4-methyl-2-pentyne 4-methyl-1-pentyne
A 4-methyl-2-hexyne B 4-methyl-1-hexyne C D
12 What is the IUPAC name of this compound?

5-Ethyl-4-methyl-4- 3-Ethyl-4-methyl-3- 3-Ethyl-4-methyl-4- 3-Ethyl-4-methyl-3-

A heptene B hexene
C heptene
D heptene
13 IUPAC name of following compound is.

3,7-dimethyl-5- 2-ethyl-6-methyl-3- 2,6-diethyl-5-nonyne 3,7-dimethyl-4-

A nonyne B octyne
C D nonyne
14 What is the IUPAC name of this compound?

C Ethylpropene 2-ethylpentene
A cis-3-Pentene B cis-2-Pentene D
15 What is the IUPAC name of this compound?

2-Methyl-1,3- 3-Methyl-1,3- phenol

A Methylbenzene B cyclohexadiene
C cyclohexadiene
D
16 What is the structure of 2-methyl-3-hexene?

(CH3)2C=CH(CH2 )CH3 (CH3)2CHCH=CHCH2CH3

A B C D
17 Correct IUPAC name of the following compound is:

A 2-ethyloctane B 2-ethyloctanal C 6-ethyl-6-octene D 3-ethyl-2-octene

18 Correct IUPAC name of the following compound is:

6-ethyl-7-methyl- 7-ethyl-6-methyl-3- C 6-ethyl-7- 7-ethyl-6-methyloctene

A 3-octene B octene methyloctene
D
19 Select the correct structure for IUPAC named 1,4-dimethylcyclohexane :
C D
A B
21 What is the IUPAC name for the compound CH3CH=CHCH2CH3?

3-Pentene 2-Pentene
A Pentene B 2,3-Pentene C D

9
Ques.
no. Question
21 The compounds 1-pentene and (z) or cis-2-pentene are an example of a pair of
Constitutional Identical
A Isotopes B Stereoisomers C isomers
D molecules
22 The molecules (z) or cis-2-pentene and (E) or trans-2-pentene are an example of a
pair of
Constitutional Identical
A Isotopes B Stereoisomers C isomers
D molecules
23 Which statement is true about stereoisomer in given structure:

D E, and A= B D E, and A B None of this

A D=E,and A= B B C D
24 Which name is correct for the given molecule below:

cis-2-methyl-3- trans-3,4-dimethyl- cis-5-methyl-4- trans-5-methyl-

A heptene B 3-hexene
C heptene
D 4-heptene
25 Stereoisomers are isomers that differ only in the.

3-D arrangement of 2-D arrangement of 1-D arrangement of All of this

A atoms B atoms
C atoms
D
26 Relation between (I) and (II) are:

Constitutional Identical molecules None of the above

A Stereoisomers B Isomers
C D
27 Relation between (I) and (II) molecules will be as:

Constitutional Stereoisomers All of this

A same molecules B isomers
C D
28 Which statement is true about Polysubstituted Benzene is:

When Benzene ring When Benzene ring When Benzene ring Above all
C D
A have one substituent B have two substituent have three or more statements are
only only substituent true
29 Which structure is trans-3-hexene?

A B C D
31 Which name is a valid IUPAC name of an unsaturated hydrocarbon?

2,3-Dimethyl-3- trans-3-Pentyne 2-Methyl-2-

A hexyne B trans-1-Hexene C D butene

10
Ques.
no. Question
31 What is the product of the reaction 2-pentene + H2
Pd
?
A Pentane B 2-Pentane C Ethane+ Propane D 2-Pentyne

32 Hydrogenation of Alkene in the presence of Pd catalyst means:

Addition of H2 at
Removing of H2from C There will be no
D Addition of water
A Alkene double B Alkane
reaction at Alkene double
bond bond
33 During Hydrogenation of Alkene, which catalyst is necessary:

A H2SO4 as catalyst B HNO3 as catalyst C Pd metal catalyst D HCl as catalyst

34 During Hydration (addition of H2O) of Alkene, which catalyst is necessary

A H2SO4 as catalyst B Pt metal catalyst C Pd metal catalyst D Zn as catalyst

35 What product is formed from the reaction below?

C D No reaction
A B
36 Product (A) in given reaction is:

CH3

A B CH3
C CH3
D
CH3

37 During hydrogenation of 1-pentene in the presence of Pd catalyst, the product [A] is:

A Propane B Butane C Pentane D Hexane

38 Which statement is correct for the hydrogenation of Alkene:

Pd catalyst is Pd catalyst is needed Pd catalyst is NOT Pd catalyst is NOT

C D
A needed and Alkene B and Alkene convert to needed, Alkene needed and Alkene
convert to Alkyne Alkane convert to Alkyne convert to Alkane
39 What product is formed in the hydration reaction shown below?

A B C D
41 Complete the following reaction and find compound [A]:
CH 2 H 2O / H 2SO4
A

CH3 CH 3

A B
OH C OH D OH

11
Ques.
no. Question
41 Which statement is correct about Polymers:

Polymers are large Polymers made None of the

Polymers are molecules made of
C of one unit of
D above
A small molecule B repeating units of monomers
monomers
42 Given below is a Polymer, the name of monomer from which it made is?

Styrene Propyl Benzene

A Methyl Benzene B Ethyl Benzene C D
43 What monomer is used to form the polymer below?

C D
A B
44 Polymerization is the joining together of.to make polymers.

Compound None of the above

A Monomer B Atoms C D
45 During polymerization of vinyl chloride, the polymer name is:

Polystyrene Polyethylene
A Polyvinylacetate B Polyvinylchloride C D
46 Benzene is.. With three double bonds.

Aromatic Linear in shape Polar compound

A compound B Tetrahedralin shape C D
47 Which statement is true about Benzene:

Benzene is planer Benzene is Option (a) and

molecule and
Benzene is planer C planer molecule
D (b) are correct
A have bond angle B molecule and have Bond
and have bond
angle 90
109 angle 120
48 The compounds o-chlorophenol and m-chlorophenol are examples of

Molecules those Molecules that are Molecules that Molecules

A are identical. B constitutional isomers
C are stereoisomers
D thatare isotopes.
49 Which structure is m-bromoaniline:

NH 2 NH 2 NH 2
NH 2 C Br
D
A B Br
Br

50 Aminobenzene structure is given below which is also known as:

Aniline None of the

A Phenol B Methyl benzene C D above

12
Ques.
no. Question
51 What is the structure of ortho-dichlorobenzene?

C D
A B
52 What is the IUPAC name of the compound below?

1,3-Dichloro-2- 1,3-Dichloro-2- 2,6-Dichlorophenol 1,5-Dichlorophenol

A oxybenzene B hydroxylbenzene
C D
53 Following benzene is disubstituted, name of compound is:

A p-chlorotoluene B o-chlorophenol C o-chlorotoluene D p-chloroaniline

54 Name of given compound is:

p-fluorobromo o-fluorobromo o-bromofluoro p-bromofluoro

A benzene B benzene
C benzene
D benzene
55 Benzene is disubstituted, name of compound is:

o-chlorophenol o-chlorobenzene
A p-chlorophenol B m-chlorophenol C D
56 4-bromo-2-chloro-1-ethylbenzene is :
Br Br Br
Br C CH 2 CH 3 D
A B Cl Cl
Cl CH 2 CH 3 Cl
CH 2CH3

57 What is the name of Polysubstituted Benzene given below

H 3C Cl

Br

2-chloro-3- 4-bromo-3- 4-bromo-5- 4-bromo-3-

A bromotoluene B chloroaniline
C chlorotoluene
D chlorotoluene
58 Which statement concerning the compound 1-ethylcyclohexene is false?
It contains a two It is a saturated
It contains a ring of It contains one
C carbon substituent
D hydrocarbon.
A six carbons. B C=C bond. on the parent carbon
chain

13
 ) Chem 109 Chapter 12(

Ques.
no. Question
1 Identify the Alcohols functional group, which refers to
Carboxylate C Sulfhydryl group D Carbonyl group
A group B Hydroxyl group

2 Which is a secondary alcohol?

C D
A B
3 Identify the primary alcohol, which refers to.
C D
A B
4 Classify the given compound as the type of alcohol which refers to

Tertiary alcohol None of the above

A Secondary alcohol B Primary alcohol C D
5 What is the shape around the oxygen atom in an alcohol?

Tetrahedral bond Trigonal planar None of the above

C D
A angle of B Trigonal pyramidal
109.5(bent shape)
6 Which alcohol is most soluble in water?
CH3(CH2)11OH All of the above
A (CH3)2CHCH2OH B CH3(CH2)6OH C D
7 Compound which has the higher boiling point is
A B C D
8 What is the major product of the dehydration of the compound given below?

C D
A B
9 Identify the commonly used reagent for alcohol dehydration.
A K2Cr2O7 B H2SO4 C Cl2 D H2O

11 What is/are the carbonyl product(s) formed when the alcohol given below is oxidized
with K2Cr2O7 / H2SO4?

No reaction
C D
A CH3(CH2)4COOH B

14
Ques.
no. Question
11 What is/are the carbonyl product(s) formed when the alcohol given below is oxidized
with K2Cr2O7 / H2SO4?

No reaction
C D
A B
12 Identify the correct compound with functional group of ether.
None of the above
A B C D
13 Chemical reaction as shown below, identify the final product.
OH
K2Cr2O7 / H2SO4
H 3C CH 3

2,5-dimethylcyclo 2,5-dimethyl 2,5-dimethyl 2,5-dimethyl

A pentanol B cyclopentanone
C cyclopentanal
D cyclopentane
14 Identify the compound which has the highest boiling point.
CH3(CH2)2O(CH2)2 CH3(CH2)5CH3 None of this
A CH3(CH2)4CH2OH B CH3
C D
15 What is the common name of CH3(CH2)2O(CH2)2CH3

Dipropyl ether Ethylmethyl ether

A Diethyl ether B Butyl butyl ether C D
16 What is the structure of Butylmethylether?

A B C D
17 What is the IUPAC name of the compound given below?
CH 3 OH
H 2C C CH 2CH 2 C CH2CH2CH 2CH 3

CH 3 CH 2CH 3 CH2CH 3
3,6-Diethyl-3- 3,6-Diethyl-3- 5,8-Diethyl-8- 3-Butyl-6-ethyl-6-
A methyl-8-decanol B methyl-8-decanol
C methyl-5-decanol
D methyl-3-octanol
18 Identify the product when CH3CH2CH2CH2OH is oxidize
O H O O
H H
C D H

A CH3 CH 2C

H
O CH 3
B CH 3CH2 C C OCH3 CH 3CH2C C OH CH3 CH 2C C CH 3

H H H

19 What will be the product when ethanol is dehydration by conc. H2SO4.

H H

H3 C OH
H H HO H H3 C H H3C H
A B C D
H H H CH 3 H CH3 H OH

21 Which compound can oxidize and finally convert to a carboxylic acid?

C D
A B

15
Ques.
no. Question
21 What is the IUPAC name of the compound below?
CH 3
HO OH

2-Methylcyclo 2-Methyl-3- 2,6-dihydroxy 1-Methyl-2,6-

A hexane-1,3-diol B hydroxyphenol
C toluene
D cyclohexanediol
22 Which statement is incorrect for the following given organic compound?

Its name is 2- Its molecular It can be oxidized to

A It is a tertiary alcohol B methyl-2-pentanol
C formula is C6H14O
D give a ketone
23 Choose the correct statement for the following chemical reaction.

An H atom and an OH The OH group was Two H atoms were

group have been
The OH group was C replaced by an H
D removed from the
A removed from the B removed from the
atom reactant
reactant
reactant
24 Which of the following represents the general condensed formula for an aldehyde?

A RCOOH B RCHO C RCOR D RCH2OH

25 What is the common name of the compound shown below?

Phenol Benzaldehyde
A HydroxyBenzene B Acetaldehyde C D
26 What is the IUPAC name of the compound shown below?

5-Chloro-3- 3-Chloro-5- 2-Chloro-4- 2-Chloro-4-

A methylhexanal B methylhexanone
C methylhexanal
D methylhexanone
27 What is the IUPAC name of the compound shown below?

A 2-Pentanone B Cyclopentanone C Cyclopropanone D Cyclobutanone

28 Identify the organic compound, which has highest boiling point.

A CH3(CH2)5CH3 B CH3(CH2)4CHO C CH3(CH2)4CH2OH D CH3CH2OH

29 Which compound is highly miscible in water?

CH3(CH2)4COCH2C CH3CH2CHO CH3CH2CH3

A CH3(CH2)5CHO B H3
C D
31 Which compound is soluble in heptane, but not soluble in water?

CH3CH2CHO None of the above

A (CH3)2CH(CH2)5CHO B CH3CH2CH3 C D

16
Ques.
no. Question
31 Identify the Tollens reagent, which is
Ag2O in aqueous Cl2
A K2Cr2O7 B H2SO4 C NH4OH
D
32 Which compound(s) would give a positive Tollens reagent test?

Ketones Ethers
A Alcohols B Aldehydes C D
33 What is the product of the reduction of an aldehyde?

Carboxylic acids Amines

A Primary alcohols B Ketones C D
34 What is the IUPAC name of the given organic compound?
CH2CH2 CH 2CH 2CH3

O Cl

4-Chloro-3- 4-Chloro-3- 4-Chloro-3-

A pentylcycloheptanone B 1-Chloro-2-pentyl- C pentylcyclohexanone D pentylhexanone
4-cyclohexanone
ne

35 Which statement is true about organic compounds when refer as Isomers?

They differ in the They have the same All of the above
way that atoms are They have different C molecular formula but D statements are
A connected to one B functional groups the different structures correct
another

36 Which molecule is chiral?

A B C D
37 Identify number of Chirality Centers in given organic compound.
CH 3

OH

A 1 B 2 C3 D 4

38 Identify number of Chirality Centers in given organic compound.

Br
OH

Cl

A 1 B 2 C 3 D 4

39 Identify the Chirality Centers at labelled carbon C1 and C2

C1 is a chirality C1 is not a C1 and C2 are both Neither C1 nor

center and C2 is chirality center
C chirality centers
D C2 are chirality
A not a chirality B and C2 is a centers
center chirality center
41 How many Chirality Centers are present in the compound given below?

CH2 CH 3
O CH 3

A 2 B 3 C 4 D 5

17
Ques.
no. Question
41 Consider the stereoisomers (AE) drawn below: Which structure is an enantiomer
of structure A?

A Structure B B Structure C C Structure D D Structure E

42 Select the enantiomers stereoisomers of glyceraldehyde, using Fischer projection
formula.
HOCH2CHCHO
OH
OH CHO CHO OH
OH OH
CHO CHO H CHO OHC H C HOH2C OH HO CH 2OH D HO OH HO OH

A H OH HO H

CH2 OH
B CH 2OH CH2OH
H H
CH 2OH CH2OH
CH 2 OH

43 Fill in the blank with correct statement; Enantiomers are stereoisomers because
of..
Nonsuperimposable Cistrans All of the above
Not mirror images of C D
A each other B mirror images of isomers of
each other each other
44 Identify the product when Cyclohexanol is dehydrated in the presence of H2SO4.

A B C D
1. 45 Identify the product when given alcohol is carry to oxidization

A B C D No reaction

46 Fischer projections of both enantiomers for given compound will be

C D
A B

18
Ques.
no. Question
47 The IUPAC name for the following compound is
CH3

2-methylcyclo
A pentanal
2-methylcyclo
B pentanol C 1-methylcyclo D 2-methylcyclo
pentanone pentanone

48 Identify the product when given Alcohol is dehydrated in the presence of H2SO4.

C D
A B
2.49 Select the compounds 1, 2 and 3 in order of increasing boiling point, which is..

None of the above

A B C D
3.50 Select the compound that is water soluble.

C D
A B

19
 )Chem 109 Chapter 13(

Ques.
no. Question
1 Which of these compounds is a secondary amide?

A B C D

2 What is the IUPAC name of the compound given below?

2-Methyl-2- 2-Methyl-2-propyl-1- 2,2-Dimethyl 2,2-Dimethyl-1-

A propylpropanoic acid B propanoic acid C pentanoic acid D pentanoic acid

3 Which statement about the labeled carbons in the compound below is true?

C1 is an carbon and C2 is an carbon C3 is an carbon and C2 is an carbon and

A C2 is a carbon B and C1 is a carbon
C C2 is a carbon
D C3 is a carbon

4 What is the common name of the compound given below?

3-Bromoaceto o-Bromobenzene 3-Bromo-1-

A m-Bromobenzoic acid B benzenoic acid C carboxylic acid D acetobenzoic acid

5 What is the IUPAC name of the compound given below?

Propyl heptanoate 4-Decanoate

A Heptyl propanoate B Hexyl propanoate C D
6 The general test for carboxylic acids is:

Acidity test Oxidation test

A Reduction test B Iodoform test C D
7 Reaction between an alcohol and a carboxylic acid is called:

Esterification Reduction
A Neutralization B Dehydration C D
8 What is the IUPAC name of the compound given below?

N,N-dimethyl N,N-dimethyl Dimethyl Dimethylamino

A propanamide B ethylamide C propanamide D propanamide

9 What is the structure of 2-chloro-3-hydroxy-4-methylpentanoic acid?

C D
A B
11 Which compound has the highest boiling point?

CH3CH2CH2CH2CH2COO (CH3)2CHCH2CH2CH2OH CH3(CH2)6CH3

A (CH3)2CHCH2CHO B H C D

20
Ques.
no. Question
11 Which amide has the lowest boiling point?

CH3(CH2)4CONHCH3
A CH3(CH2)5CONH2 B CH3CH2CON(CH2CH3)2 C D CH3(CH2)7CONH2

12 Which types of compounds are formed when Carboxylic acids react with bases such
as NaOH?
A Alcohols B Carboxylate salts C Esters D amides
13 Hydrolysis of an ester by an aqueous base is called as:

A Esterification B Saponification C Neutralization D Dehydration

14 Which of the following properly describes soaps?

Salts of carboxylic acids Salts of carboxylic acids Carboxylic acids

A Fatty acids B that have a long C that have a short D
hydrocarbon chain hydrocarbon chain

15 What organic product is formed when a carboxylic acid reacts with an alcohol in the
presence of conc. sulfuric acid?

A Ether B Ester C Ketone D Amide

16 Identify the products of hydrolysis in the following amide.

C6H5COOH + C6H5COOH + C6H5COONa + C6H5CON(CH3)2 +

A (CH3)2NH B CH3NH2
C (CH3)2NH +H2O
D H2O +NaOH
17 Arrange the following compounds in order to increasing boiling points.

A b > c> a B b > a> c C a > c> b D a > b> c

18 What are the products of the reaction shown?

Pentyl cyclopentanoate Cyclopentyl pentanoate

A Hexyl cyclopentanoate B Cyclopentyl hexanoate C D
19 Which reagent, when reacted with dimethylamine, would produce the compound
shown below?

C D N(CH3)3
A B
21 What products are formed in the acid hydrolysis of the ester shown below?

Propanoic acid and Acetic acid and

Ethanol and acetic Acetic acid and C D
A acid B water
ethanol ethane

21
Ques.
no. Question
21 What products are formed in the base hydrolysis of the ester shown below with NaOH?

Acetic acid and sodium Methanol and sodium Sodium acetate and
A Ethanol and acetic acid B ethoxide C propanoate D water

22 The IUPAC name of the compound CH3CH2CONHCH3 is:

N-methyl All are correct
A Methylpropylamine B Butylamine C propanamide
D
23 Which compound is the most soluble in water?
CH3(CH2)6CH3 CH3(CH2)6NH2
A CH3CH2CH2COOH B CH3 (CH2)6COOH C D
24 Which statement concerning carboxylic acids is incorrect?
The presence of Carboxylic acid with
The functional group of
a carboxylic acid is
Carboxylic acids are C carboxylic acid D a strong base
A abbreviated as COOH B hydrogen ion donors. increases [H3O+] in
an aqueous solution
produces a water-
insoluble
or CO2H.
relative to water. carboxylate salt.

25 Identify the reagents which can be used to carry out the following reaction.
?
CH3COOH CH3COOC2H5
C2H5OH H2SO4 CH3OH H2SO4
A C2H5OH B CH3OH C D
26 Select the correct name of the following structure (CH3)2 CH CH2 CH2 COOH
4-Methylpentanoic Hexanoic acid 2-Methyl
A Pentanoic acid B acid
C D pentanoic acid
27 Classify the following amine as:
N CH3

Secondary Quaternary
A Primary amine B Tertiary amine
amine
C D amine

28 What is the IUPAC name of the compound shown below?

N-propyl-1- N-hexyl-1- Hexylpropylamine

A Propylhexylamine B hexanamine
C propanamine
D
29 What amide is formed when pentanoic acid is heated with ethylamine
C D
A B
31 Which compound has the highest boiling point?
(CH3)2CH(CH2)4OH CH3(CH2)6CH3
A (CH3)2CHCH2COOCH3 B CH3(CH2)6NH2 C D

22
Ques.
no. Question
31 What is the IUPAC name of the amine salt shown below?

N-Ethyl-N-methyl-1- N-Ethyl-N-methyl-N- N-Methyl-N-

A Ethylmethylpropyla
mmonium chloride B propanammonium C propylammonium D propylethanammoniu
chloride chloride m chloride

32 Which amine has the highest boiling point?

CH3(CH2)5NHCH2CH3
A CH3(CH2)5CH2NH2 B HN(CH2CH3)2 C D (CH2CH3)3 N

33 What products are formed when (Dimethyl amine) reacts with HCl?

A (CH3)2NH+Cl- B (CH3)2NH2 C (CH3)2NH2+Cl- D (CH3)3N+Cl-

34 What is the name of the compounds with the general formula of R4N+ X?
Tertiary Quaternary Tetraammonium Tertiary ammonia
A ammonium salts B ammonium salts
C salts
D salts
35 Which of these functional groups is not present in atorvastatin?

A Carboxylic acid B Benzene C Ketone D Amine

36 What are the products in the acidbase reaction shown below?

A B C D
37 Identify the organic compound which is more soluble in water:
CH3(CH2)6COONa CH3(CH2)6COOH
A CH3(CH2)4COOH B CH3(CH2)5COOH C D
38 Select the organic compound which has the higher boiling point.
CH3COOCH3 CH3(CH2)3OH
A CH3CH2COOH B CH3(CH2)2OCH3 C D
39 Methyl formate is a/an:
Alcohol Ester
A Aldehydes B Carboxylic acid C D
41 Na2CO3 solution gives strong effervescences with:
Alcohol Ester
A Aldehydes B Carboxylic acid C D

23
 )Chem 109 Chapter 14(

Ques.
no. Questions
1 What is the name of the bond formed between glucose and galactosemonosaccharides to produce
the disaccharide lactose?
A -1,2-glycosidic bond B -1,4-glycosidic bond C -1,4-glycosidic bond D -1,2-glycosidic bond

2 Select the cyclic structures which represents -D-fructose:

A B C D

3 When D-glucose is treated with Benedict's reagent (a blue solution)..

A No reaction takes place B Brick red ppt is formed C Violet colour is formed D Odour of formaldehyde

4 Number of chirality center(s) in Ketotriose is/ are

A 0 B 1 C 2 D 3
5 Which of the following monosaccharides represents L-Aldopentose?

A B C D

6 The structure given below corresponds to a disaccharide in the form of :

A -glycoside B -glycoside C -glycoside D None of the above

7 The hydrolysis of monosaccharides gives.
One unit of glucose
One unit of glucose and
A one unit of fructose B Two units of glucose C and one unit of D None of the above
galactose
8 The hydrolysis of maltose gives two units of glucose (C6H12O6), molecular formula of maltose
is..
A C12H23O12 B C12H22O11 C C12H22O10 D C12H12O6
9 When a D-aldotetrose is treated with H2/Pd, final product will be..

A B C D

11 D-glucose and D-fructose are monosaccharides that represent a pair of..

A Constitutional isomers B Cis-trans isomers C Enantiomers D Identical molecules

24
Ques.
no. Questions
11 Cellulose is an unbranched polymer composed of repeating of glucose units joined in a.
14--glycosidic 14--glycosidic 12--glycosidic 12--glycosidic
A linkage B linkage C linkage D linkage
12 -Isomer of cyclic form of the given sugar will be as

A B C D

13 Which of the following monosaccharides represents L-ketopentose?

A B C D

14 The following given sugar is classified as

A -isomer B -isomer C D-isomer D L-isomer

15 The number of Chirality Center(s) of the structure below is/ are :

A 2 B 4 C 6 D 8
16 Select the correct structure of L-Glucose in given options.

A B C D

17 Identify the cyclic structures of -D-fructose:

A B C D

25
Ques.
no. Questions
18 What is the product formed when D-glucose is treated with Cu+2 / OH?

A B C D

19 Select the product formed when a D-aldopentose is treated with H2 / Pd, is

A B C D

20 The structure below corresponds to a disaccharide in the form of :

A -glycoside B -glycoside C -glycoside D None of the above

21 All carbohydrates contain one or more Chirality Centers except:
A Dihydroxy acetone B Glycerladehyde C Glucose D Fructose
Identify the monosaccharides which represents D-aldopentose.
22
A B C D

23 Classify the given monosaccharide as:

A Ketopentose B Aldopentose C Ketohexose D Aldohexose

24 Numbers of Chirality Centers of the given sugar is/ are.

A One B Four C Three D Two

26
Ques.
no. Questions
25 Select the -isomer of cyclic form of the given sugar:

A B C D

26 Select the correct reagents for the following reaction:

A Cu+2/ OH- B HNO3 C H2/ Pd D H2O / H+

27 Identify the Enantiomer of the given sugar:

A B C D

28 Identify the product when aldopentose (shown below) is treated with Benedict,s reagent.

A B C D

29 Select the correct glycosidic linkage in cellulose:

A -(1-4) B -(1-4) C -(1-2) D -(1-2)

30 D-glucose and L-glucose are monosaccharides that represent a pair of..

Constitutional
A isomers B Cis-trans isomers C Enantiomers D Identical molecules

27
Ques.
no. Questions
31 Identify two compounds of the following that are enantiomers..

A A, B B A, D C B, C D C, D
32 Select the pair of constitutional isomers in given structures....

A A,B B A,C C B,C D None of the above

33 Which carbohydrates cannot be converted to simpler compounds by hydrolysis?

A Disaccharides B Monosaccharides C Polysaccharides D Starches
34 Monosaccharides with a carbonyl group at C1 are called?
A Anomers B Aldoses C Ketoses D Alditols
35 Classify the compound shown below?

A Aldohexose B Ketohexose C Aldopentose D Ketopentose

36 Classify the compound shown below?

A Tetraketose B Ketotriose C Ketotetrose D Aldotriose

37 Which monosaccharide is an aldotriose?

A B C D

28
Ques.
no. Questions
38 How many chirality centers are present in the compound shown below?

A 2 B 4 C 5 D 6

39 The structures of galactose (left) and glucose (right) are shown below. How are the two
monosaccharides related?

A Structural isomers B Stereoisomers C Enantiomers D Anomers

40 Which Haworth projection represents the -anomer of the monosaccharide shown below?

A B C D

41 Which labeled carbon atom in the structure below is the anomeric carbon?

A A B B C C D D
42 Which product is formed when the compound below is treated with H2, in presence of Pd
catalyst?

A B C D

43 Formation of whichcolor in the Benedict's test indicates a reducing sugar is present in solution?

A Blue B Brick red C Bright yellow D Silver

29
Ques.
no. Questions
44 Which product is formed when the compound below is treated with Benedict's reagent?

A B C D

45 Which product is formed when the compound below is treated with Benedict's reagent?

A B C D

46 Which of the following joins togetherthe monosaccharide units that formDisaccharides and
polysaccharides?

A Hydrogen bonding B Glycosidic linkages C Hemiacetal bonds D Dipole-dipole forces

47 How many acetals are present in the disaccharide shown below?

A 1 B 2 C 3 D 4

48 What is the structure of cellulose?

Unbranched skeleton of Branched skeleton of Unbranched skeleton Branched skeleton of

glucose molecules glucose molecules of glucose molecules glucose molecules
A joined by 14- B joined by 14- C joined by 14- D joined by 14-
glycoside linkages glycoside linkages glycoside linkages glycoside linkages
49 Which structure is a three-carbon alditol?

A B C D

30
Ques.
no. Questions
50 Which naturally-occurring monosaccharide forms the Haworth structure shown below?

A B C D

51 The Fischer projections of two monosaccharides are shown below. Which term best describes the
relationship between the two?

Constitutional
A Enantiomers B Anomers C isomers D Diastereomers

52 When a monosaccharide forms a cyclic hemiacetal, the carbon atom that is part of the hemiacetal
is a new chirality center, called the anomeric carbon.
A True B False

53 The anomer of a cyclic monosaccharide has the OH group drawn down, below the ring.
A True B False
54 The monosaccharide shown below is an anomer.

B
A True False

55 At equilibrium, a solution of glucose in water is an equal mixture of the anomer, the anomer,
and the acyclic aldehyde.
A True B False
56 Certain monosaccharidesnotably aldopentoses and ketohexosesform five-membered rings,
not six-membered rings, in solution.
A True B False
57 The monosaccharide shown below is an anomer.

A True B False

31
Ques.
no. Questions
58 The carbonyl group of an aldose is reduced to a secondary alcohol using hydrogen (H 2), in
presence of palladium (Pd) metal.
A True B False
59 An alditol contains an OH group on every carbon atom.
A True B False
60 Carbohydrates that are oxidized with Benedict's reagent are called reducing sugars, because they
reduce the Cu2+ in Benedict's reagent to Cu+ during the reaction.
A True B False
61 All aldoses and ketoses are reducing sugars.
A True B False
62 All disaccharides contain at least one acetal that joins the rings together.
B
A True False

63 The disaccharide shown below has an-glycosidic linkage.

A True B False
64 Hydrolysis of the disaccharide below yields the indicated products.

A True B False
65 Cellulose is a highly branched polymer composed of repeating glucose units joined in a 14-
glycosidic linkage.
A True B False
66 In aldohexoses, it is the OH group on C5 that reacts with the aldehyde carbonyl to form two
cyclic hemiacetals, called anomers.
A True B False

67 -D-galactose and -D-galactose are enantiomers.

A True B False
68 The structure shown has four (4) chirality centers and is a D monosaccharide.

A True B False

32
Ques.
no. Questions
69 Glucose and other naturally occurring sugars are D sugars.

A True B False
70 When the monosaccharide below is oxidized by Benedict's reagent, the indicated product results.

A True B False
71 Carbohydrates are structurally defined as polyhydroxyaldehydes ORpolyhydroxyketones, or
compounds that can be hydrolyzed to any of them.

A True B False
72 Disaccharides contain two carbonyl groups.

A True B False
73 Monosaccharides with a carbonyl group at C2 are called ketoses.

A True B False
74 All carbohydrates, except for dihydroxyacetone, contain one or more chirality centers.

A True B False
75 The two monosaccharides shown below are related as enantiomers.

A True B False

33
 )Chem 109 Chapter 16(

Ques.
no. Question
1 Which is the simplest amino acid?

A Serine B Glutamine C Cysteine D Glycine

2 What is the three-letter abbreviation of asparagine?

A Asp B Asg C Asn D Arg

3 What is the charge on a zwitterion?

A Positive B Neutral C Negative D None of this

4 What is the charge on an amino acid at a pH below its pI?

A Positive B Neutral C Negative D None of this

5 How many different dipeptides can be formed when one valine reacts with one glycine?

A 1 B 2 C 3 D 4
6 How many different tripeptides can be formed when one isoleucine, one alanine, and
one glycine react?

A 3 B 6 C 18 D 27

7 What is the C-terminal amino acid in the tetrapeptide glycylalanyisoleucylmethionine?

A Alanine B Glycine C Methionine D Isoleucine

8 What is the N-terminal amino acid in the tetrapeptide glycylalanyisoleucylmethionine?

A Alanine B Glycine C Methionine D Isoleucine

9 How many chirality centers are in leu-enkephalin (structure shown)?

C 5 D 6
A 3 B 4

11 All amino acids have at least one chirality center.

A True B False C D

34
Ques.
no. Question
11 Humans can synthesize only twenty of the amino acids needed for proteins.

A True B False C D
+
12 D-Amino acids have the NH3 group on the left side in the Fischer projection.

A True B False C D
13 The Fischer projection below represents a naturally occurring amino acid.

A True B False C D
14 A dipeptide contains two amino acids joined together by two amide bonds.

A True B False C D
15 The amide bonds in peptides and proteins are called peptide bonds.

A True B False C D
16 By convention, the C-terminal amino acid is always written at the right end of the
peptide chain and the N-terminal amino acid at the left.

A True B False C D
17 Acidic amino acids have lower pIvalues than basic amino acids.

A True B False C D
18 Glycine exists primarily in its neutral form at a pH ~ 6.

A True B False C D
19 The peptide leucylphenylalanylvalylvaline is abbreviated as LeuPhenAlaValVal.

A True B False C D
21 Amino acids with an additional COOH group in the side chain are classified as acidic
amino acids.

A True B False C D

35
Ques.
no. Question
21 Fill in the blank. Proteins are

Amino acids connected Polypeptide chains Polypeptide chains None of the

C D
A through hydrogen bonds B connected through connected through above
linkage amide linkages glycosidic linkages
22 After addition of an acid in zwitter ion of an amino acid (X) has net positive charge is
1, the pH of amino acid will be..

A pH=6 B pH2 C pH2 D pH=10

23 Classification of the given amino acid is..

H

OOC - CH2 C COO

NH3

A Neutral B Basic C Acidic D Zwitterion

24 Classification of the given amino acid is..
H

H3N C COO

CH2CH2CONH2

A Neutral B Basic C Acidic D Zwitterion

25 The net charge of the zwitterion of an amino acid is :

A -1 B -2 C zero D +1
26 The pH at which the amino acid exists primarily in its neutral form is called as

A Hydrogen bond B
Melting point C Isoelectric point D Boiling point
27 Two amino acids joined together by one peptide bond are called as

A Tripeptide B Dipeptide C Polypeptide D Tetrapeptide

28 Neutral amino acid at pH =11 shows predominated form which will be as

C Cationic D all of them

A Zwitterion B Anionic form (-1)
form(+1)
29 Select the amino acid which does not have Chirality Center.

A Alanine B Glycine C Histidine D Aspartic acid

31 One peptide structure is given below; classification of this peptide is

A Dipeptide B Tetrapeptide C Monopeptide D Tripeptide

36
37