Escolar Documentos
Profissional Documentos
Cultura Documentos
Remarks:
Checked by :
---------------------------
Date :
ABSTRACT / SUMMARY
The purpose of this experiment to determine the value of the Ka acid and
determine the endpoint of a titration curve. The unknown acid was titrated by sodium
hydroxide which divided by two parts because of we had two unknown acid. The first
part experiment is to determine the weak unknown acid by titrate the acid with sodium
hydroxide. The second parts we used the phenolphthalein ( three drop into unknown
acid ) as the indicator to get the permanent pink. The permanent pink indicate that the
acid was change to the base by droping the sodium hydroxide in the burette. Then we
record the reading of burette when the colour turn to pink and record the pH.. Using the
information we collected, we were able to graph the titration curve ( pH versus total
volume of NaOH added ). We then used the titration curve to determine the Ka. But in
our cases the result shown that was a bit different compared to the theory. The higher
pH that we got was slightly below than pH 12 that cause the different in graph and the
scatter chart.
unknown acid. The equivalence point was reached when the moles of the acid and the
moles of the titrant base added were equal and the half-equivalence point when the
moles of acid and the moles of the conjugate base are equal. So the pH is equal to pKa.
The Henderson-Heselbach equation, pH = pKa + log [A-] / [HA] can be used to solve for
the pH cof the solution. After the pH is found we can determine the Ka by using the
formula 10^-pKa.
Based on the result we can conclude that the unknown weak acid can define in
above method, the graph will be the main thing to us to get the equivalence point. The
such as in the quality of drinking water, food preservation, soil conditions for agriculture
and physicological functions. The strength of an acid was measured based on its ability
to donate protons to base. The acid ionization constant, Ka, was quantitative measured
of the strength of an acid. The Ka value was characteristic of an acid and can be used
to identify an unknown acid. The Ka value indicated the relative strength of an acid. The
larger the Ka value the stronger the acid and vice versa.
The experiment started with 10 ml of two unknown acid solutions and required to
determine the acid ionization constants, Ka of weak acid solutions by titration with 0.1 M
sodium hydroxide, NaOH and by measured the pH of the weak acid. We also should
identify the unknown weak acid solutions from the calculated Ka values obtained during
the experiment. The endpoint of a titration was the point in a titration where no more
titrant was to be added which shown by the colour change of indicator. In this
experiment we used the sodium hydroxide,NaOH to titrate the unknown acid by adding
1 mL at a time which the pH was recorded after each mL added. We added titrant to the
To determine the value Ka of the weak acid from the titration that we done in
experiment 2.
To indicate the type of weak acid that we had go through in this experiment by
To figure out the value of sodium hydroxide dropped in the acid solutions which
When the moles of acid in the solution equals to the moles of base added in the titration
the equivalence point occurred. For example, as stoichiometry amount of one mole of
strong base, sodium hydroxide (NaOH), can neutralize one mole of weak acid,acetic
acid (CHCOH).
pH = - log [HO]
In this experiment, titration of unknown acid with sodium hydroxide solution will be done.
Primary standard acid solution was prepared to standardized the sodium hydroxide
solution. Titration of the solution with a primary standard should be done to standardized
the base. Standardized sodium hydroxide solution will be used to titrate 10.00mL
aliquots of unknown acid.
APPARATUS
METHODOLOGY / PROCEDURE
Part A
The experiment beginning with taking 0.1 M of sodium hydroxide to put into the
burette, the burette must be rinsed and cleaned first before we put the sodium hydroxide
in there. 10 ml of unknown acid was prepared and then transferred into the beaker. The
beaker was then placed on a stir plate and a magnetic stirrer was inserted into the
beaker and let to stir the solution. A pH meter was calibrated using buffer solution before
the electrode was being rinsed well with distilled with water and blotted dried. The pH
electrode was inserted into the beaker and the position of the electrode was adjusted so
that the magnetic stirrer does not hit it. Titrate the 0.1 M of NaOH with the weak acid and
measuring the pH of the weak acid. Then, identify the unknown weak acid solution from
the calculated Ka values obtained during the experiment. Plot the graph of pH versus
sodium hydroxide. The equivalence point was determined on each graph. The volume
of base that corresponds to the equivalence point was found. This value was divided by
two to determine the amount of base needed to reach half way to the equivalence point.
The pH at this volume of base is converted to [H +] to give the Ka of the acid.
Part B
A sample of the unknown acid was obtained. 100 mL of distilled water was
measured out with a graduated cylinder and it was poured into a 250 mL conical flask.
The sample of acid was dissolved in the water, and it was stirred to mix thoroughly. The
solution was divided into two equal portions by using a graduated cylinder, and do so as
accurately as possible. Some drops were added into the first flask. The portion in the
flask was titrated to a phenolphthalein endpoint with sodium hydroxide solution adding
the sodium hydroxide slowly while swirling the flask. As the endpoint approaches, the
sodium hydroxide solution were added drop by drop until the solution has a permanent
pink color. The titrated solution was mixed with the other half of the acid solution and the
pH of the resulting solution was determined. Again, since half of the acid has been
titrated, [H+] = [HA] = [A-]. Using Equation 2 and canceling out the values for [HA] and
[A-], the Ka value is once again determined from the [H +] value. From the observed pH,
the Ka of the unknown acid was calculated.
RESULTS
Part A
TRIAL 1 TRIAL 2
NaOH added (ml) pH NaOH added (ml) pH
0 3.35 0 3.34
1 4.36 1 4.43
2 6.44 2 8.63
3 9.97 3 10.03
4 10.27 4 10.36
5 10.47 5 10.57
6 10.6 6 10.69
7 10.69 7 10.77
8 10.78 8 10.85
9 10.84 9 10.9
10 10.89 10 10.94
11 10.94 11 10.98
12 10.99 12 11.02
13 11.03 13 11.06
14 11.05 14 11.09
15 11.09 15 11.12
16 11.11 16 11.15
17 11.14 17 11.16
18 11.16 18 11.18
19 11.18 19 11.21
20 11.2 20 11.22
21 11.21 21 11.24
22 11.23 22 11.26
23 11.24 23 11.27
24 11.26 24 11.28
25 11.27 25 11.3
26 11.29 26 11.31
27 11.3 27 11.32
28 11.31 28 11.33
29 11.32 29 11.34
30 11.33 30 11.35
31 11.34 31 11.36
32 11.36 32 11.37
33 11.37 33 11.38
34 11.38 34 11.39
35 11.39 35 11.4
36 11.4 36 11.41
37 11.41 37 11.42
38 11.41 38 11.43
39 11.42 39 11.44
40 11.43 40 11.44
41 11.43 41 11.45
42 11.44 42 11.45
43 11.45 43 11.46
44 11.45 44 11.46
45 11.46 45 11.47
46 11.46 46 11.48
47 11.47 47 11.48
48 11.47 48 11.49
49 11.48 49 11.49
50 11.48 50 11.5
Part B
First Second
experiment experiment
Volume of NaOH added 2.1 ml 2.1 ml
pH 10.05 9.96
Calculations
DISSCUSION
RECOMENDATIONS
To get the accurate value of result in the experiment, there are a few
recommendations and precaution that need to be considered through the experiments.
First, look at the lower meniscus in the light coloured solution and upper
meniscus in the dark coloured solution because of visibility. Besides, look at the
meniscus of solution at eye level to avoid parallax error. Then, do not forget to add
distilled water to the vinegar.
Usually an air bubble is present in the nozzle of the burette, it must be removed
before taking the initial reading. When chemicals are spilled on skin, wash for at least 15
minutes with running water.
Next, in order to get an accurate value, the experiment must be repeat at least two times
to get the average reading. The eye of the observer must be perpendicular to the scale
while taking the reading to avoid parallax error. The value with no parallax error is
accurate value.
Lastly, all the solution used in this experiment should be thrown into the waste
disposal bin.
https://docs.google.com/document/d/1yGpLZMNsR2PAW4axyX1_ZfHMIB6Dgv
Z6XZkcnDvTWLA/edit?pli=1
https://www.scribd.com/doc/39166239/Identifying-an-Unknown-Weak-Acids-
Experiment