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Carbonaceous substrates
Alkalinity
Component Kherbit As-Samra WWTP Abu-Nussier
WWTP
COD tot (mg/l) 1929 1597
CODss (pCOD) (mg/l) 1336 1093
CODcol (mg/l) 139 128
CODs (mg/l) 453 376
TS (mg/l) 2100 1710
VS (mg/l) 1000 960
TSS (mg/l) 420 470
VSS (mg/l) 260 340
Carbohydrates mg COD/l 98 76
Lipids mg COD/l 419 420
Protein mg COD/l 812 769
Ammonium mg /l 80 80
VFA mg COD /l 200 150
pH 7.2 7.3
Carbonaceous constituents High bCOD or BOD means
Biodegradable Non-biodegradable
COD COD
complex Colloidal
Suspended Found in eff
VFA solids
sCODe,
Contribute to total
sludge production
TCOD= rbCOD+ sbCOD+ nbsCOD+ nbpCOD
TKN
Organic N Ammonia
60-70% of TKN
Biodegradable Nonbiodegradable
nbpON= fN (nbVSS)
Non biodegradable VSS
nbvss concentration can be estimated from
COD, sCOD, BOD sBOD and VSS
Based on the assumption that gCOD/gVSS is the same
for the biodegradable and non biodegradable VSS.
Example 8-1
Recycle flow and loading
The impact of recycle flow must be quantified and included in defining the
influent ww characteristics to the AS process
Sludge production
Oxygen requirements
Nutrient requirements
Chemical requirements
SRT
Most critical parameter for AS design
It affects:
treatment performance
Aeration tank volume
Sludge production
Oxygen requirements
Table 8-5
For BOD and Nitrifcation
For nitrification design, SRT that is calculated from
nitrification kinetics is multiplied by safety factor
Equation 8-20
CO2
Respiration
Energy
bCOD
maintenance
Growth
Oxygen is also consumed for endogenous respiration
and the amount depends on the system SRT
4.57
Where:
NOx= nitrogen oxidized, mg/l
TKNo= influent TKN concentration, mg/l
Ne= effluent NH4-N concentration, mg/l
Nutrient requirements
Inorganic nutrient (macro and micro), organic nutrients (growth
factors)
SRT WAS
MLSS RAS
OUR
Routine microscopic observation
for early detection of changes that might negatively
impact sludge settling and process performance
Dissolved oxygen control
1. Settleability
Return sludge pumping rate is set to equal the
percentage ratio of:
Volume of occupies settleable solids after 30 min of
settling / volume of clarified liquid (supernatant)
It has been shown that SOUR and the final effluent COD
can be correlated, thereby allowing prediction of final
effluent quality during.
SLR= ((Q+QR) * X) / A
Bulking sludge
Rising sludge
Nocardia foam
Bulking sludge condition: is a condition in MLSS with poor
settling characteristics has developed, which defines a condition in the
clarifier that can cause high effluent suspended solids and poor
treatment performance
The resultant sludge has low density with low settling velocities and poor
compaction
Table 8-8
The growth of filamentous organisms can
occur due to the following conditions:
A. Low dissolved oxygen
B. Low food to microorganism (F/M) ratio
C. Low pH
D. Nutrient deficiency
E. Excessive grease
F. Hydrogen sulfide ; Beggiatoa and Thiothrix grow well on
fermentation products such as VFA and reduced sulfur
compounds (sulfides and thiosulfiate) , that would be found
in septic wastewater
For control of bulking, consideration should be given to:
1. Wastewater characteristic
2. Dissolved oxygen content
3. Process loading
4. Return and waste sludge pumping rates
5. Internal plant overloading
6. Clarifier operation
Wastewater characteristics
Certain components found in ww (lipids and dissolved
sulfides) or absence of certain components, such as trace
elements, can lead to the development of a bulked
sludge.
Dark brown, almost black a) Anaerobic conditions a) Check DO levels in basin, and increase
sudsy foam with detectable within the aeration aeration / mixing. Reduce organic loading if
septic or sour odor. Mixed basin. possible.
liquor is also very dark b) Industrial waste b) Investigate pre-treatment strategies.
brown to black in color. containing dyes or inks.
Why? Denitrification
Nitrate and nitrites in the wastewater are converted to
nitrogen gas, as nitrogen gas is formed in the sludge layer,
much of it is entrapped in sludge mass and the sludge
mass becomes buoyant and rises or floats to the surface.
require
supplied
Influent wastewater
Endogenous respiration
External carbon source
Suspended growth biological nitrogen removal process
Categorized:
I. Single sludge
Means only one solids separation device (secondary clarifier)
AS tank may be divided into different zones of anoxic and
aerobic conditions and mixed liquor can be pumped from one
zone to another (internal recycle)
Why?
1. the benefits of the selector operation for control
of bulking sludge
2. The production of alkalinity before the nitrification
step
3. The ability to convert an existing biological
treatment system to nitrogen removal with
relatively short to moderate basin detention time.
Key design parameters that affect the amount of
nitrogen removed are:
1. Anoxic zone detention time
2. Mixed liquor volatile suspended solids
3. Internal recycle rate and return sludge flow
4. Influent BOD or bCOD concentration
5. The readily bCOD fraction (rbCOD)
6. Temperature.
X (bCOD)
Preanoxic
Y (fraction of rbCOD)
X (bCOD)
Preanoxic
Higher Y
Higer denitrification
rate
Process design consideration
F/Mb= BOD F/M ratio based on active biomass concentration, gBOD /g biomass
Q= influent flowrate, m3/d
So= influent BOD concentration, mg/l
Vanox= anoxic volume, m3
Xb=anoxic zone biomass
The values are general and can be used for ww with different fractions
of rbCOD and inert non biodegradable volatile solids.
SDNRb values are based only on the active heterotrophic
biomass concentration in the mixed liquor, so the rates are
applicable to many situation regardless of the amount of
non-biodegradable solids in the mixed liquor and the SRT.
Temperature correction
IR=2
IR=3-4
To compute needed IR ratio
Assuming:
All of influent TKN is biodegradable
Effluent soluble organic nitrogen concentration is
ignored, the nitrate produces is contained in the total
flow leaving the aerobic zone, which includes internal
recycle, RAS and effluent flows
Step-feed Anoxic/Aerobic Process
During the anoxic period, the tank operation is similar a preanoxic tank
because influent BOD is added continuously to drive denitrification
reaction.