P(ATM)= 50 T(K)

Gas A0 a B0
He 0.0216 0.05984 0.014
H2 0.1975 -0.00506 0.02096
O2 1.4911 0.02562 0.04624

Beartie-Bridgeman
PV - RT -/V -/V^2 -/V^3=0
Helio V F(V) F'(V) Xn+1
1 1.89936E+01 5.04094E+01 6.23212E-01
6.23212E-01 -9.37258E-02 5.10580E+01 6.25048E-01
6.25048E-01 -5.73254E-06 5.10518E+01 6.25048E-01
Volumen 6.25048E-01 -2.35176E-14 5.10518E+01 6.25048E-01
6.25048E-01 -1.75250E-15 5.10518E+01 6.25048E-01
6.25048E-01 -1.75250E-15 5.10518E+01 6.25048E-01
6.25048E-01 -1.75250E-15 5.10518E+01 6.25048E-01

Oxigeno V F(V) F'(V) Xn+1

1 1.9446E+01 4.9988E+01 6.1099E-01
0.610994948 -1.0165E-02 5.0079E+01 6.1120E-01
0.611197925 -1.4822E-08 5.0078E+01 6.1120E-01
Volumen 0.611197926 -2.2156E-15 5.0078E+01 6.1120E-01
0.611197926 -2.2156E-15 5.0078E+01 6.1120E-01
0.611197926 -2.2156E-15 5.0078E+01 6.1120E-01
0.611197926 -2.2156E-15 5.0078E+01 6.1120E-01
 373.15 Helio
b c 0.4067762
0 4.00E-07 1.29E-03
-0.4359 5.04E-06 0
0.004208 4.80E-04

Derivada
P+/V^2+2/V^3+3/V^4=0
X Hidrogeno V F(V)
1.83567E-03 1 1.8679E+01
1.12289E-07 0.633746151 -3.0491E-01
0.00000E+00 0.639467358 -2.2412E-04
0.00000E+00 Volumen 0.639471569 -1.1875E-10
0.00000E+00 0.639471569 4.2272E-15
0.00000E+00 0.639471569 -3.2113E-15
-6.25048E-01 0.639471569 4.2272E-15

X
2.0298E-04
2.9598E-10
0.0000E+00
0.0000E+00
0.0000E+00
0.0000E+00
-6.1120E-01
Hidrogeno Oxigeno
0.443840368 -0.076234608
2.79E-01 3.22E-02
-2.71E-14 5.50E-14

F'(V) Xn+1 X
51.00096220 0.633746151 0.005721207
53.29387653 0.639467358 0.000004212
53.21596678 0.639471569 0.000000000
53.21591038 0.639471569 0.000000000
53.21591038 0.639471569 0.000000000
53.21591038 0.639471569 0.000000000
53.21591038 0.639471569 -0.639471569
Metodo de la Secante P(ATM)= 50
Gas A0 a
He 0.0216 0.05984
H2 0.1975 -0.00506
O2 1.4911 0.02562

Beartie-Bridgeman
PV - RT -/V -/V^2 -/V^3=0
Helio V-1 F(V-1) V
0.5 -6.417022576 1
1 18.993631256 0.626266381
0.626266381 0.0621976408 0.62503851
0.62503851 -0.0004848216 0.625048007
Volumen 0.625048007 1.953054474E-008 0.625048007
0.625048007 5.464812630E-015 0.625048007

Hidrogeno V-1 F(V-1) V

0.5 -7.6002244016 1
1 18.6792987156 0.644603545
0.644603545 0.2729281892 0.639333755
0.639333755 -0.0073340474 0.639471657
0.639471657 4.692186873E-006 0.639471569
Volumen 0.639471569 8.137613637E-011 0.639471569
0.639471569 -3.21133341E-015 0.639471569

Oxigeno V-1 F(V-1) V

0.5 -5.5748236971 1
1 19.4456863799 0.611405077
0.611405077 0.0103737927 0.61119766
0.61119766 -1.32764108E-005 0.611197926
Volumen 0.611197926 1.972490715E-011 0.611197926
0.611197926 -2.21556127E-015 0.611197926
T(K) 373.15 Helio
B0 b c
0.014 0 0.0000004
0.02096 -0.4359 0.00000504
0.04624 0.004208 0.00048

Derivada
P+/V^2+2/V^3+3/V^4=0
F(V) V+1 V+1 - V
18.993631256 0.626266381 -0.3737336194
0.0621976408 0.62503851 -0.0012278705
-0.0004848216 0.625048007 0.000009497
1.953054474E-008 0.625048007 -3.82563425E-010
5.464812630E-015 0.625048007 0
-1.75250439E-015 0.625048007 0

F(V) V+1 V+1 - V

18.6792987156 0.644603545 -0.3553964551
0.2729281892 0.639333755 -0.0052697902
-0.0073340474 0.639471657 0.0001379026
4.692186873E-006 0.639471569 -8.81711036E-008
8.137613637E-011 0.639471569 -1.52922119E-012
-3.21133341E-015 0.639471569 0
4.227160857E-015 0.639471569 0

F(V) V+1 V+1 - V

19.4456863799 0.611405077 -0.3885949231
0.0103737927 0.61119766 -0.0002074164
-1.32764108E-005 0.611197926 2.651128750E-007
1.972490715E-011 0.611197926 -3.93907129E-013
-2.21556127E-015 0.611197926 0
-2.21556127E-015
 Hidrogeno
0.4067762 0.443840368
0.001292544 0.2785609164
0 -2.71178744E-014
Oxigeno
-0.0762346083
0.0322482284
5.50024145E-014
 P(ATM)= 50
Gas A0 a B0
He 0.0216
H2 0.1975
O2 1.4911
Beartie-Bridgeman
PV - RT -/V -/V^2 -/V^3=0
V f(V) V2
0.5 -6.417022576
Helio V F(V) V2
0.5 -6.417022576
0.626266381 0.062197641
0.62503851 -0.000484822
0.625048081 3.78632E-006
0.625048006 -2.9570E-008
Volumen 0.625048007 2.30925E-010
V f(V) V2
0.5 -7.600224402
Hidrogeno V F(V) V2
0.5 -7.600224402
0.644603545 0.272928189
0.639333755 -0.007334047
0.639475307 0.000198936
0.639471468 -5.3947E-006
0.639471572 1.46296E-007
Volumen 0.639471569 -0.000000004
0.639471569 1.07584E-010
V f(V) V2
0.5 -5.574823697
Oxigeno V F(V) V2
0.5 -5.574823697
0.611405077 0.010373793
0.61119766 -1.3276E-005
0.611197926 0.000000017
0.611197926 -2.1775E-011
0.611197926 2.98005E-014
Volumen 0.611197926 1.33715E-015
0.611197926 1.33715E-015
T(K) 373.15
b
0.05984 0.014 0
-0.00506 0.02096 -0.4359
0.02562 0.04624 0.004208
f(V2) f(V)*f(V2)
1 18.99363126 -121.8825606
F(V2) Vr
1 18.99363126 0.626266381
1 18.99363126 0.62503851
1 18.99363126 0.625048081
1 18.99363126 0.625048006
1 18.99363126 0.625048007
1 18.99363126 0.625048007
f(V2) f(V)*f(V2)
1 18.67929872 -141.9668619
F(V2) Vr
1 18.67929872 0.644603545
1 18.67929872 0.639333755
1 18.67929872 0.639475307
1 18.67929872 0.639471468
1 18.67929872 0.639471572
1 18.67929872 0.639471569
1 18.67929872 0.639471569
1 18.67929872 0.639471569
f(V2) f(V)*f(V2)
1 19.44568638 -108.4062732
F(V2) Vr
1 19.44568638 0.611405077
1 19.44568638 0.61119766
1 19.44568638 0.611197926
1 19.44568638 0.611197926
1 19.44568638 0.611197926
1 19.44568638 0.611197926
1 19.44568638 0.611197926
1 19.44568638 0.611197926
 Helio Hidrogeno
c 0.4067762
0.0000004 0.001292544
0.00000504 0
0.00048

Existe una raiz en este intervalo

F(Vr)
0.062197641
-0.000484822
3.78632E-006
-2.9570E-008
2.30925E-010
-1.8046E-012

Existe una raiz en este intervalo

F(Vr)
0.272928189
-0.007334047
0.000198936
-5.3947E-006
1.46296E-007
-0.000000004
1.07584E-010
-2.9148E-012

Existe una raiz en este intervalo

F(Vr)
0.010373793
-1.3276E-005
0.000000017
-2.1775E-011
2.98005E-014
1.33715E-015
1.33715E-015
1.33715E-015
 Oxigeno
0.443840368 -0.076234608
0.278560916 0.032248228
-2.7118E-014 5.50024E-014
 Metodo de la Biseccion

Gas Ao a Bo b
He 0.0213 0.05984 0.014 0
H2 0.1975 -0.00506 0.02096 -0.4359
O2 1.4911 0.02562 0.04624 0.004208

R 0.082
T(k) 373.15
P(atm) 50
Volumen 0.6111979098

Valores iniciales
f(v)
v1 -1 -80.19249839 i
V2 1 18.99334921 0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
 80
70
60
50
40
Axis Title 30
20
10
0
0 0.5
-10
-20

Resultado El volumen de He a las cond

cx10-4
0.0000004 0.4070762 0.001274592 0
0.00000504 0.443840368 0.2785609164 -2.711787436E-014
0.00048 -0.076234608 0.0322482284 5.5002414475E-014

Helio

V1 V2 Vr f(Vr)
-1 1
-1 1 0
0 1 0.5 0.5 -6.412771048
0.500 1 0.75 0.25 6.3582147753
0.500 0.75 0.625 0.125 -0.000119807
0.625 0.5 0.5625 0.0625 -3.197394311
0.625 0.5625 0.59375 0.03125 -1.596851365
0.625 0.59375 0.609375 0.015625 -0.798045786
0.625 0.609375 0.6171875 0.0078125 -0.398977019
0.625 0.6171875 0.62109375 0.00390625 -0.199522468
0.625 0.62109375 0.623046875 0.001953125 -0.099814712
0.625 0.623046875 0.6240234375 0.0009765625 -0.049965661
0.625 0.6240234375 0.6245117188 0.0004882813 -0.025042335
0.625 0.6245117188 0.6247558594 0.0002441406 -0.012580972
0.625 0.6247558594 0.6248779297 0.0001220703 -0.006350365
0.625 0.6248779297 0.6249389648 6.10351563E-005 -0.00323508
0.625 0.6249389648 0.6249694824 3.05175781E-005 -0.001677442
0.625 0.6249694824 0.6249847412 1.52587891E-005 -0.000898624
0.625 0.6249847412 0.6249923706 7.62939453E-006 -0.000509216
0.625 0.6249923706 0.6249961853 3.81469727E-006 -0.000314512
0.625 0.6249961853 0.6249980927 1.90734863E-006 -0.00021716
0.625 0.6249980927 0.6249990463 9.53674316E-007 -0.000168484
0.625 0.6249990463 0.6249995232 4.76837158E-007 -0.000144146
0.625 0.6249995232 0.6249997616 2.38418579E-007 -0.000131977
0.625 0.6249997616 0.6249998808 1.19209290E-007 -0.000125892
2.625 0.6249998808 1.6249999404 1.0000000596 50.397822861
2.265 1.6249999404 1.9449999702 0.3200000298 66.437583017
1.9449999702 1.6249999404 1.7849999553 0.1600000149 58.419582729
1.7849999553 1.6249999404 1.7049999478 0.0800000075 54.409237745
 Grafica

Chart Title
80
70
60
50
40
30
20
10
0
0 0.5 1 1.5 2 2.5
-10
-20

Volumen (Vr)

umen de He a las condiciones dadas es aproximadamente 0.6249988

 Hidrogeno

i V1 V2 Vr
0 -1 1
1 -1 1 0
2 0 1 0.5 0.5
3 0.5 1 0.75 0.25
4 0.5 0.75 0.625 0.125
5 0.625 0.75 0.6875 0.0625
6 0.625 0.6875 0.65625 0.03125
7 0.625 0.65625 0.640625 0.015625
8 0.625 0.640625 0.6328125 0.0078125
9 0.625 0.632813 0.6289065 0.003906
10 0.625 0.628907 0.6269535 0.001953
11 0.6269535 0.628907 0.62793025 0.00097675
12 0.628907 0.62793025 0.628418625 0.000488375
13 0.628907 0.628418625 0.6286628125 0.0002441875
14 0.627931 0.6286628125 0.6282969063 0.0003659062
15 0.627931 0.6282969063 0.6281139531 0.0001829531
16 0.627931 0.6281139531 0.6280224766 9.1476562E-005
17 0.627931 0.6280224766 0.6279767383 4.5738281E-005
18 0.627931 0.6279767383 0.6279538691 2.2869141E-005
19 0.6279767383 0.6279538691 0.6279653037 1.1434570E-005
20 0.6279538691 0.6279653037 0.6279595864 5.7172852E-006
21 0.6279595864 0.6279538691 0.6279567278 2.8586426E-006
22 0.6279595864 0.6279567278 0.6279581571 1.4293213E-006
23 0.6279595864 0.6279581571 0.6279588718 7.1466064E-007
24 0.6279595864 0.6279588718 0.6279592291 3.5733032E-007
25 0.6279592291 0.6279588718 0.6279590504 1.7866516E-007
26 0.6279590504 0.6279588718 0.6279589611 8.9332581E-008
27 0.6279589611 0.6279588718 0.6279589164 4.4666290E-008
28 0.6279589164 0.6279588718 0.6279588941 2.2333145E-008
 29 0.6279589164 0.6279588941 0.6279589053 1.1166573E-008
30 0.6279589164 0.6279589053 0.6279589108 5.5832863E-009
31 0.6279589164 0.6279589108 0.6279589136 2.7916431E-009
32 0.6279589164 0.6279589136 0.627958915 1.3958216E-009
33 0.6279589164 0.627958915 0.6279589157 6.9791073E-010
34 0.6279589164 0.6279589157 0.6279589161 3.4895542E-010
35 0.6279589164 0.6279589161 0.6279589163 1.7447765E-010

Grafica

Chart Title

2.5 6

f(vr)
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
-2

-4

-6

-8 Volumen(Vr)

Resultado El volumen de H2 a las condiciones dadas es 0.627958916

 Oxigeno

f(Vr) i V1 V2 Vr
0 -1 1
1 -1 1 0
-6.555620965 2 0 1 0.5
6.1532223272 3 0.5 1 0.75
-0.167257447 4 0.5 0.75 0.625
2.999450452 5 0.5 0.625 0.5625
1.4179056443 6 0.5625 0.625 0.59375
0.625804502 7 0.59375 0.625 0.609375
0.2293974469 8 0.609375 0.625 0.6171875
0.0311141709 9 0.609375 0.6171875 0.61328125
-0.068051009 10 0.609375 0.61328125 0.611328125
-0.01845375 11 0.609375 0.611328125 0.610351563
0.0063433964 12 0.609375 0.610351563 0.609863281
0.0187415997 13 0.609375 0.609863281 0.609619141
0.0001632427 14 0.609619141 0.609863281 0.609741211
-0.009126143 15 0.609619141 0.609741211 0.609680176
-0.013770888 16 0.609680176 0.609741211 0.609710693
-0.016093274 17 0.609680176 0.609710693 0.609695435
-0.01725447 18 0.609695435 0.609710693 0.609703064
-0.016673872 19 0.609703064 0.609710693 0.609706879
-0.016964171 20 0.609703064 0.609706879 0.609704971
-0.01710932 21 0.609704971 0.609706879 0.609705925
-0.017036746 22 0.609704971 0.609705925 0.609705448
-0.017000458
-0.016982314
-0.016991386 Chart Title
-0.016995922
8
-0.01699819
6
-0.016999324
4
2
f(Vr)
0
0 0.1 0.2 0.3 0.4 0.5
-2
 Chart Title
8
6
4
-0.016998757
2
-0.016998474 f(Vr)
-0.016998332 0
0 0.1 0.2 0.3 0.4 0.5
-0.016998261 -2
-0.016998226 -4
-0.016998208 -6
-0.016998199 -8

Volumen (Vr)

Resultado El volumen de O2 a las condiciones dadas es 0.60975

0.7 0.8

das es 0.627958916
 f(Vr)

0.5 -5.4538928411
0.25 6.9852065155
0.125 0.7610784086
0.0625 -2.347975349
0.03125 -0.793773631
0.015625 -0.0164220427
0.0078125 0.3723103565
0.00390625 0.1779396057
0.001953125 0.0807576317
0.0009765625 0.0321675055
0.0004882813 0.007872659
0.0002441406 -0.00427471
0.0001220703 0.00179897
6.1035156E-005 -0.0012378711
3.0517578E-005 0.0002805491
1.5258789E-005 -0.0004786611
7.6293945E-006 -0.000099056
3.8146973E-006 9.07465732E-005
1.9073486E-006 -4.1547059E-006
9.5367432E-007 4.32959334E-005
4.7683716E-007 1.95706137E-005

art Title

0.4 0.5 0.6 0.7 0.8

art Title

0.4 0.5 0.6 0.7 0.8

Volumen (Vr)

s dadas es 0.60975