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Transport Phenomena I
Chemical Engineering School
Universidad Industrial de Santander
Rheology and Newtonian fluids
Newtonian Fluid
Hydrodynamics
LINEAR VISCOUS FLUID =
NEWTONIAN
Taken from James f. Steffe. Rheological methods in food process Ingeneering. pag 50 https://sites.google.com/site/jfsteffe/freeman-press
NEWTONIAN FLUIDS
Newton Law (1687): The resistance which
arises from the lack of slipperiness of the parts
of the liquid, other things being equal, is
proportional to the velocity with which the parts
of the liquid are separated from one another
x V
y h
dv x
yx : shear rate
dy (<0)
The quantity yx represents the momentum flux,
dv x
yx in other words, the transmission of momentum
dy from the regions of high velocity to the regions of
low velocity.
Viscosity in Pa s
Typical No Newtonian Models for Time Independent
Fluids and No Memory
Effect of Rheological Behavior On Flow
The velocity profile shown in the figures, seeing the great effect that has
the rheological behavior of the flow in the pipeline. n>1 Dilatant or Shear-
thickenin; n=1 Newtonian, n<1 Pseudoplastic or shear thinning. In the right
side are shewed velocity profiles for Binghan fluid.
Generalized Newtonian Fluid Concept
The generalized Newtonian models have been widely used by engineers for designing
flow systems.
This model consider that viscosity is the most important material function, then a simple
extension of the Newtons law of viscosity will be sufficient.
The most common strategy deals with the use of the concept of the:
model
log slope:
n-1
m n 1
log
n 1 Shear-thinning (or pseudoplastic)
The most important region ( usually in the range : 0.15 - 0.9 )
for many industrial problems
n 1 Newtonian :
n 1 Shear-thickening ( or dilatant )
GNF model : the Power-law model of Ostwald and de Waele
m n 1
ADVANTAGES DRAWBACKS
log slope:
n-1 0 0
real
n 1
0 ( ) 0
0
0 log
0 , a zero-shear-rate viscosity
3 parameters
01, a characteristic time
log slope:
1
n-1
0 1 n
real [1 ( ) ]
2 2
Time constant
log Advantages: gives nearly quantitative fit for
many polymer solutions and
the 3-parameters version is polymer melts
used when high-shear-rate Drawbacks: no analytical solutions, even for
data (second Newtonian simple flow problems
plateau) arent available too sharp transition between the
Newtonian plateau and the shear-
thinning region
GNF model : EMPIRICISMS for ( )
The 4-parameters CARREAU-A model
POLYMER SOLUTIONS
2%PIB in Primol 355
0 9.23 102 Pa.s
5%PS in Aroclor 1242 1.5 101 Pa.s
191s
7% aluminum soap n 0.358
in decalin and m-cresol
0 1.01 102 Pa.s
5.9 102 Pa.s
0.84s
0.75%PAAm
in 95/5 w/w H2O-Gly
n 0.364
0 10.6Pa.s 0 89.6Pa.s
102 Pa.s 0.01Pa.s
8.04s 1.41s
n 0.364 n 0.2
GNF model : EMPIRICISMS for ( )
Models that partially remedy the drawbacks of the CARREAU-A model
1 1
0
1 n
0 1 ( )1n [1 ( ) ]
a a
There is a 4-parameters
version of this model, Both models fit quite well smooth
which is equivalent to the transitions between Newtonian plateau
CARREAU - YASUDA model and shear-thinning regions, which is the
case of natural polymers and polymers
with a broad molecular weight distribution
Description of the Carreau-Yasuda Model
The parameter 1 represents the shear stress value for which the viscosity is
2
0 2
The time constant or characteristic time is 0 1
2
Time constant : 0 y
Yield Stress Estimation
Indirect Metod
The first one (smaller slope) is region of The yield stress is determined using
Oscillation stress sweep measurements elastic deformation (solid like behavior), interpolation between the zero-
which serve for determination of the while the second one (larger slop) is the shear viscosity and shear thinning
linear viscoelastic range of the product region of viscous flow (liquid like region.
can also be employed for the yield behavior). The yield stress can be
stress determination. detected as a breakpoint in the slope of
two power low regressions.
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GNF model : Usefulness and Limitaions ( )
For steady state shear flows, the (flow rate - pressure drop) and (torque - angular velocity)
relationships are exact, even if the fluids are viscoelastic
The only limitations concern the fit between the experimental viscosity data and the chosen GNF
model.
The GNF model can be considered as a special case of more general form of the stress tensor,
based on continuum mechanics arguments.
If elastic effects are unimportant (De<DeC), the assumption of steady state shear flow is not
required.
There are many examples in the literature, in which the GNF model has been used outside the
region of legitimacy. The corresponding results should be considered with extreme care.
The use of GNF model is not recommended for elongational and/or rapidly changing flows.
Typical geometries used to obtain rheological properties
Taken from:z. Tadmor and C. G. Gogos. Principles of Polymer Processing. Wiley & Interscience 22
Time dependent Flow Behaviour
Time
Thixotropic
Time
Antithyxotropic
Shear-thinning
y (purely viscous)
a
thixotropic
b
area
? Measure of the thixotropy
Models for Time dependent Flow Behaviour
= =
= 2
A and B are constants. yield stress
B<0 for Thixotropic Behavior is the structural
B>0 for Anti-thixotropic
Behavior
parameter
Standards Flows
Shear Flow Uniaxial (Elongational )Flow
Layers of fluid slide past Velocity profile describes is three-
each other and do not dimensional.
mix Strong stretch occurring in the x3-
The flow is rectilinear, direction and contraction
and the velocity only occurring equally in the x1- and
varies in one direction x2-directions.
perpdicular to flow.
Pruebas Reomtricas
(s) = / G (Pa.s)
G (Pa)
Characteristic time Viscosity Rigidity
of the substance modulus
Water 10-13 s
lubrif. oils 10-5 s
Polyesters 10-2 s
Polyolefines 100 s
Mountains 1013 s
large , if T
The mountains flow before the Lord
DEBORAH, Bible, Juges 5:5 De 1, liquid behaviour
creep testing : It is the sudden
application of a constant stress to
the liquid being tested, and the
monitoring of the resulting strain
thereafter.
()
=
= 0 sin
=0 Elastic material
0< <90 Visco-elastic material
Stress and strain are in Phase: What the = 90 Viscous material
strain is at its maximun, stress also is at its
maximun
= 0 sin +
= = cos
OSCILLATORY TEST
Creep and stress relaxation test are convenient for studing material response
at long times (minutes to days), but less acurrate at shorter times (second
and less)
DEBORAH number De = / T
Situation of flow Corrresponding expression of De
2R
Sudden Average velocity V
in the small tube
contraction <v> R
CENTRE DE GENIE CHIMIQUE DES MILIEUX RHEOLOGIQUEMENT COMPLEXES Groupe ENSIC Nancy-France