Bubble Pressure

A Binary System Acrylonitrile ,Nitromethane Confirming closely to raoult's law . V.P of

species are given by antoine equation at 75 C.

B
Antoine Equation ln p sat A T 75 C
T C

SR.NO COMPONENT A B C
1 ACRYLONITRILE 14.2724 2945.47 224
2 NITROMETHANE 14.2043 2972.64 209

X 1 P1S
Pb X 1 P1S X 2 P2S Y1
Pb

Sr No lnPsat Psat
1 4.4213297659 83.2068575
2 3.7372577465 41.9827049

X1 X2 Y1 Y2 Pb
0 1 0 1 41.98270495
0.1 0.9 0.1804720541 0.81952795 46.1051202
0.2 0.8 0.3313196904 0.66868031 50.22753545
0.3 0.7 0.4592838985 0.5407161 54.3499507
0.4 0.6 0.5692046566 0.43079534 58.47236595
0.5 0.5 0.6646469231 0.33535308 62.59478121
0.6 0.4 0.7482945497 0.25170545 66.71719646
0.7 0.3 0.8222066556 0.17779334 70.83961171
0.8 0.2 0.8879894084 0.11201059 74.96202696
0.9 0.1 0.9469140785 0.05308592 79.08444221
1 0 1 0 83.20685747
 86
Pb Vs (X,Y)
81
76
71
66
Pb Vs (X)
Pb(kPa)
61
Pb Vs (Y)
56
51
46
41
0 0.2 0.4 0.6 0.8 1 1.2

X,Y
 Dew Pressure
A Binary System Acrylonitrile ,Nitromethane Confirming closely to raoult's law . V.P of species are given
by antoine equation at 75 C.

B
Antoine Equation ln p sat A
T C 86
81
T 75 C 76
71
SR.NO COMPONENT A B C
66
1 ACRYLONITRILE 14.2724 2945.47 224 Pd(kPa)
61
2 NITROMETHANE 14.2043 2972.64 209
56

Y Pd 51
X 1 1
1
P sat
Pd 46
1 Y1 Y2

sat
P1 P2sat 41
0

Sr No lnPsat Psat
1 4.4213297659 83.20686
2 3.7372577465 41.9827

Y1 Y2 X1 X2 Y1/P1SAT Y2/P2SAT Pd
0 1 0 1 0 0.023819 41.9827
0.1 0.9 0.0530859215 0.946914 0.001202 0.021437 44.17113
0.2 0.8 0.1120105916 0.887989 0.002404 0.019055 46.60025
0.3 0.7 0.1777933444 0.822207 0.003605 0.016674 49.31208
0.4 0.6 0.2517054503 0.748295 0.004807 0.014292 52.35905
0.5 0.5 0.3353530769 0.664647 0.006009 0.01191 55.80735
0.6 0.4 0.4307953434 0.569205 0.007211 0.009528 59.74188
0.7 0.3 0.5407161015 0.459284 0.008413 0.007146 64.27327
0.8 0.2 0.6686803096 0.33132 0.009615 0.004764 69.54848
0.9 0.1 0.8195279459 0.180472 0.010816 0.002382 75.76705
1 0 1 0 0.012018 0 83.20686
of species are given

Pd Vs (X,Y)
86
81
76
71
66 Pd Vs X
Pd(kPa)
61 Pd Vs Y

56
51
46
41
0 0.2 0.4 0.6 0.8 1 1.2
X,Y
 Bubble Temperature
Given P= 80 kPa

Component A B C X1 0.3
Acetone 14.5463 2940.46 237.22 X2 0.45
Acetonitrile 14.2724 2945.47 224 X3 0.25
Nitromethane 14.2043 2972.46 209

SOLUTION

Assume Pb= 90.0001083336 kPa Changing Cell

lnPb= 4.499810874

Assume Y1= 0.5161828

Y2= 0.3787608
Changing Cell
Y3= 0.1050564
Y1+Y2+Y3= 1

T
B
C Tassume X i Ti
A ln P

Tassume XiTi 72.178 Changing Cell

55.4653314757
77.4011908241
97.2974218856 B
ln p sat A
TC

lnp1sat 5.0424894
F(1) Pb ( X P X P X P ) 0
S
1 1
S
2 2
S
3 3 lnp2 sat
4.3274682
lnp3 sat
3.632847
S
XP
F( 2) Y1 1 0 1

Pb
F(1)= 0
F(2)= -3.3E-016
X 2 P2S
F( 3) Y2 0 F(3)= -4.4E-016
Pb
 X 2 P2S
F( 3) Y2 0
Pb F(4)= 0

F(4) Y1 Y2 Y3 1 0

Result Table

Initial Final
Y1 0.1 0.5161828022
Y2 0.2 0.3787608261
Y3 0.7 0.1050563718
Pb 90 90.0001083336
F(1) 1.82E-07 0
F(2) -0.41618 -3.33067E-016
F(3) -0.17876 -4.44089E-016
F(4) 0 0
Changing Cell

p1sat 154.85503
p2sat 75.752256
p3sat 37.820339
 Dew Temperature
Given P= 80 kPa

Component A B C Y1 0.3
Acetone 14.5463 2940.46 237.22 Y2 0.45
Acetonitrile 14.2724 2945.47 224 Y3 0.25
Nitromethane 14.2043 2972.46 209

SOLUTION

Assume Pd= 87.2338292423 kPa Changing Cell

lnPd= 4.4685922057

Assume X1= 0.1375706

X2= 0.4139235
Changing Cell
X3= 0.4485058
X1+X2+X3= 1

T
B
C Tassume Yi Ti
A ln P

Tassume YiTi 79.024366 Changing Cell

54.5586524497
76.4414266174
96.3152439253 B
ln p sat A
TC

1
F(1) Pd ( )0 lnp1sat 5.2482371
Y1 Y2 Y3

P1
sat
P2
sat
P3
sat
lnp2 sat
4.5521585
lnp3 sat
3.8841315
Y Pd
F( 2) X 1 1 sat 0
P1 F(1)= -2.0E-007
Y2 Pd F(2)= -5.8E-010
F( 3) X 2 0 F(3)= -2.0E-009
P2sat
 Y2 Pd
F( 3) X 2 0
P2sat F(4)= 0

F( 4 ) X 1 X 2 X 3 1 0

Result Table

Initial Final
X1 0.1 0.1375706445
X2 0.2 0.4139235246
X3 0.7 0.4485058309
Pd 90 87.2338292423
F(1) 2.10E+01 -2.02767E-007
F(2) -0.07436 -5.77749E-010
F(3) -0.33464 -0.000000002
F(4) 0 0
 Y1/P1SAT 0.001577
Y2/P2SAT 0.004745
Y3/P3SAT 0.0051414

Changing Cell

p1sat 190.230618
p2sat 94.8368977
p3sat 48.6246912