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1. The average rate of disappearance of ozone in the reaction 2O3(g) 3O2(g) is found to be 8.9 103 atm over a
certain interval of time. What is the rate of appearance of O 2 during this interval?
A) 1.3 102 atm/time
B) 8.9 103 atm/time
C) 5.9 103 atm/time
D) 2.7 102 atm/time
E) 1.8 102 atm/time
2. The rate constant k is dependent on
A) the concentration of the reactant.
B) the concentration of the product.
C) the temperature.
D) the order of the reaction.
E) none of these
3. The rate expression for a particular reaction is Rate = k[A][B]2. If the initial concentration of B is increased from
0.1 M to 0.3 M, the initial rate will increase by which of the following factors?
A) 3
B) 27
C) 4
D) 6
E) 9
4. A first-order reaction is 43% complete at the end of 18 min. What is the value of the rate constant?
A) 3.1 x 10-2 min-1
B) 0.21 min-1
C) 0.031 min-1
D) 4.7 10-2 min-1
E) 1.4 10-2 min-1
5. For the first of the reactions in the table of data, determine -[B]/t.
A) 4.00 105
B) 8.00 105
C) 1.60 104
D) 2.00 105
E) none of these
6. What is the order of the reaction with respect to B?
A) 1
B) 4
C) 3
D) 2
E) 0
7. What is the order of the reaction with respect to A?
A) 1
B) 4
C) 3
D) 2
E) 0
8. What is the overall order of the reaction?
A) 1
B) 4
C) 3
D) 2
E) 0
9. What are the proper units for the rate constant for the reaction?
A) s1
B) mol L1 s1
C) L mol1 s1
D) L3 mol3 s1
E) L2 mol2 s1
10. What is the numerical value of the rate constant?
A) 4.00 104
B) 4.00 103
C) 4.00 102
D) 4.00 101
E) none of these
11. Use the following initial rate data for the reaction in aqueous solution to determine the rate law.
[Br2 ]
(M/s)
+ t
[CH3COCH3]0 (M) [Br2]0 (M) [H ]0 (M)
A) Rate = k[Br2][H+]
B) Rate = k[CH3COCH3][Br2]
C) Rate = k[CH3COCH3][H+]
D) Rate = k[CH3COCH3][Br2][H+]
E) Rate = k[CH3COCH3][Br2][H+]2
12. The reaction of (CH3)3CBr with hydroxide ion proceeds with the formation of (CH3)3COH.
(CH3)3CBr (aq) + OH (aq) (CH3)3COH (aq) + Br (aq)
The following data were obtained at 55C.
[(CH3)3CBr]0 [HO]0 Initial Rate
4 0.30 0.20 ?
16. If the reaction 2HI H2 + I2 is second order, which of the following will yield a linear plot?
A) log [HI] vs. time
B) 1/[HI] vs. time
C) [HI] vs. time
D) ln [HI] vs. time
Use the following to answer questions 17-20:
For the reaction a A products, select the reaction order(s) that best fit(s) the observations.
21. The reaction A B + C is known to be zero order in A with a rate constant of 3.6 102 mol/L s at 25 C. An
experiment was run at 25C where [A]0 = 3.4 103 M. What is the half-life for the reaction?
A) 4.7 102 s
B) 1.9 101 s
C) 1.8 102 s
D) 8.2 104 s
E) 6.1 102 s
22. For which order reaction is the half-life of the reaction proportional to 1/k (k is the rate constant)?
A) zero order
B) first order
C) second order
D) all of these
E) none of these
Use the following to answer questions 23-24:
For a reaction aA products, [A]0 = 4.0 M, and the first three successive half-lives are 48, 96, and 192 min.
25. The reaction A B + C is known to be zero order in A with a rate constant of 4.8 102 mol/L s at 25 C. An
experiment was run at 25C where [A]0 = 2.2 M. What is the concentration of B after 6.0 s?
A) 8.5 101 M
B) 1.9 M
C) 1.1 101 M
D) 2.9 101 M
E) 2.2 M
26. At a particular temperature, N2O5 decomposes according to a first-order rate law with a half-life of 3.0 s. If the
initial concentration of N2O5 is 1.0 1016 molecules/cm3, what will be the concentration in molecules/cm3
after 10.0 s?
A) 9.9 1014
B) 1.8 1012
C) 7.3 109
D) 6.3 103
E) 9.4 102
C2H5Cl products
Experiment shows that the decomposition is first order. The following data show kinetics information for this
reaction.
Time (s) ln [C2H5Cl] (M)
1.0 -1.625
2.0 -1.735
27. What was the initial concentration of the ethylene chloride?
A) 0.29 M
B) 0.35 M
C) 0.11 M
D) 0.02 M
E) 0.22 M
28. What would the concentration be after 5.0 s?
A) 0.13 M
B) 0.08 M
C) 0.02 M
D) 0.19 M
E) 0.12 M
31. When ethyl chloride, CH3CH2Cl, is dissolved in 1.0 M NaOH, it is converted into ethanol, CH3CH2OH, by the
reaction
CH3CH2Cl + OH CH3CH2OH + Cl
At 25C the reaction is first order in CH3CH2Cl, and the rate constant is 1.0 103 s1. If the activation
parameters are A = 3.4 1014 s1 and Ea = 100.0 kJ/mol, what will the rate constant be at 28C? (R = 8.314
J/mol K)
A) 1.5 103 s1
B) 8.9 102 s1
C) 1.1 103 s1
D) 9.2 103 s1
E) 3.8 1014 s1
32. The rate law for a reaction is found to be Rate = k[A]2[B]. Which of the following mechanisms gives this rate
law?
I. A+B E (fast)
E + B C + D (slow)
III. A + A E (slow)
E + B C + D (fast)
A) I only
B) II only
C) III
D) two of these
E) none of these
33. The experimental rate law for the decomposition of nitrous oxide (N 2O) to N2 and O2 is Rate = k[N2O]2. Two
mechanisms are proposed:
I. N2O N2 + O
N2O + O N2 + O2
34. The rate constant for a reaction increases from 10.0 s-1 to 100. s-1 when the temperature is increased from 317 K
to 427 K. What is the activation energy for the reaction in kJ/mol? (R = 8.314 J/mol K)
A) 23.6 kJ/mol
B) 10.2 kJ/mol
C) 1.74 kJ/mol
D) 21.1 kJ/mol
E) 0.0756 kJ/mol
35. The activation energy for the reaction H2(g) + I2(g) 2HI(g) is changed from 184 kJ/mol to 59.0 kJ/mol at 600.
K by the introduction of a Pt catalyst. Calculate the value of the ratio rate(catalyzed)/rate(uncatalyzed).
A) 1.00
B) 7.62 1010
C) 1.38
D) 0.321
E) none of these
36. The reaction 2H2O2 2H2O + O2 has the following mechanism:
H2O2 + I H2O + IO
H2O + IO H2O + O2 + I
What is the catalyst in the reaction?
A) H2O
B) I
C) H2O2
D) IO
Answers:
13. B 14. C 15. A 16. B 17. B 18. E 19. A 20. A 21. A 22. D 23. A 24. B
25. D 26. A 27. E 28. A 29. C 30. E 31. A 32. B 33. C 34. A 35. B 36. B