APNDICE B. P edades de especies purq.

Tabla 8.2: Constantes de la ecuacin de Antoine para las presiones de vapor de especies
puras
lnPsat/kPa:A--=:-
t/"c + c
Calor latente de vaporizacin en el punto de ebullicin normal (AE,), y punto de ebullicin normal (r,,)
Parmetros de 1a ecuacin intervalo de
, de Antoie temperatura LH,, tit
Nombre FrmuIa AI B OC
kJlmol oC
Acetona -..-".. . C3H6O 14.3145 2756.22 228.060 29.10 s6.2
cido actico C2HaO2 15.0717 3580.80 224.650 al lla
23.70 1'r70
Acetroitilo* C2H3N 14.8950 3413.1 0 ?5n 5?? I Yt
-) 30.19 81.6
Benceno -' coHo 13.7819 2726.81 21'7.572 6-104 iv. I 1. 80.0
lso-Butano . CrH,^ 13.8254 2187.'79 248.870 -83 t.3v
-Butano CrH,n 13.6608 2154.'70 238.789
-719 ^)a / /
-11.9
1-Butanol
-73 - -0.5
CaHigO 75.3744 3212.43 182.739 J/-tJ 43.29 71'7.6
2- Butanolx CaH16O 15.1989 3026.03 186.500 25 40.75 99.s
lso-Butanol GaH16O 14.6047 2740.95 166.610 30
-120
128 41.82 107.8
tert-Butatol CaHlsO 14.8445 2658.29 -
- 10r
17'7.650 10 39.07 82.3
Tetacloruro de cabono CC], 14.0572 2914.23 232.148 -14 - 101 29.82 '7
6.6
Clorobenceno C6H5Cl 13.8635 3774.78 211.700 ,o_1<O 35.19 t7I./
1-Clorobutano CaHeCl 13,7965 . I J. / 5 218.265
-17 -79 30.39 78.5
CIooformo CHC13 13.7324 2548.74 218.s52 )Q )-
Ciclohexano
-23 - 84 61.1
Ca}ltz 13.6568 2723.44 220.618 o 1n<
29.97 80.7
Ciclopentano csHro 13.972'7 2653.90 234.s70 -35 z/.)u 49.2
n-Decano crcHzz 13.9148 344236 i93.858 65
-71 38.75 174.1
Diclorometano CH2C12 13.9891 2463.93 223.240 -203
ter dietlico CaH16O 14.0135 2511.29 237.200
-38 - 60
-43 - 55
28.06
26.52
39.7
34.4
1,4 Dioxeno CaH6O2 15.0967 3579.78 240.337 20 105 34.76 101.3
n-Eicosano CtnHn 14.4575 4680.46 132.100 208
- 379 57.49
Etao1 C2H6O 16.89s8 3795.77 izo.sft 3
- 38.s6 I .L
Etilbenceno cHro 13.9'.726 3259.93 21230A 33 -96
Etilenglicol* C2H6O2 15.756'7 4187.46 778.650 100
- 763 35.57
s0.73
136.2
197.3
n-Heptano ctHta 73.8622 2910.26 216.432 L -222
11a. J T. / I 98.4
,z-Hexano coHr+ 13.8 193 2696.04 224.377 -
-79 92 28.85 68.7
Metanol .- CHO 16.5785 307. I 239.500 - 83 35.27
Acetato de metilo
-11 - 64.7
C3H602 14.2456 2662.78 219.690
Metil etil cetona
-23 -78 3U-32 56.9
CaHsO 14.1334 2838.24 21.8.690 31.30
Nitometano*
-8 - 103 79.6
CH3NO2 14i7513 3331.70 227.600 56 146 33.99 101.2
n-Nonano Cs}lzo t3.9854 33t1.79 202.694 46
- 178 36.91 150.8
lso-Octano csHrs t3.6703 2896.31 220.767 -
) _1)< 34,'79 99.2
n-Octano CsHie 13.9346 ) t3.tJ 209.635 26 t52 34.4i t25.6
n-Pentano csHrz q 1?.7667 2451.88 232.014 -45
- 58 25.79 36.0
Fenoi C6H6O t4.4387 3507.80 175.400 80
-
1-P,ropanol C3HsO 16.1154 3483.67 205.807 20
- 208 46.18
41.44.
181.8

2-Propanol C3HsO 16.6796 3640.20 219.610 - 116

8-100 39.85
97.2
82.2
Tolueno czHs 13.9320 3056.96 217.625 13 136 33.1 8 1i0.6
Agua Hzo 16.38:72 3985.70 239.170
-
0-200 40.66 100.0
o.Xileno csHro t4.0415 3358.79 212.041 40 1 /
t'72 36.24 1+A.T
m-XtTeno caHro 14.1387 338 1.8 1 2t6.120 J) - t 35.66 139.1
p-Xileno caHro 14.0579 3331.45 214.627 35
- 166 35.67 i3 8.3
Basado principalmenfe en la informacin presentada por
-
B E. poling, i. u. nruurrr* y r. erc co*.tt,
The Propertiei of Gases and Liqttids,s" ;di.e A, McGraw-Hilr, Nueva york, 2001.
* Parimet,os de ".,
Antoine adaptados de Gmehling y colaboradores. vase pie de pgina 2, p.791.
i Parimetros A de Antoine ajustados paru r"prou.ir a '"
riril";;;'-
"",
 APNDICE B. Protiiades de es

Tabla 8.1: Propiedades caractersticas de especies puras

Masa vc
molar (D TrK i
cm- mot
._l
' lnlK
Metano \6.4$ 0.072 190.6 45.99 0.286 OCA 111/
Etano 30.070 0.100 . 305.3 49.1) n .)70 145.5 184.6
Propano- 44.097 0-152 369.8 42.48 0.276 200.0 231.1
r-Butano 58.t23 0.200 475.1 37.96 0.274 ,55 )1)'7
/z-Pentano '72.150 0.252 469.7 33.70 0.2'70 111 ?no,
n-Hexano 86.\77 0.301 507.6 34.25 0.266 371. 341.9
z-Heptano 700.204 0.350 540.2 2'1.40' 0.267 428. 3'71.6
z-Octano 114.231 0.400 568.7 ?4 QO O
'<A
486. 398.8
n-Nonano 128.258 0.444 594.6 22.90 0.252 544 .)A Cl

n-Decano 742.285 0.492 61'7.7 21.10 0.247 600. 447.3

Isobutano 58.123 0.181 408.1 36.48 0.282 N2.1 261.4
Isooctano 114.231 0.302 544.0 25.68 0.266 468. 372.4
Ciclopentano 70.734 0.196 51 1.8 45.02 0.273 ?5R ?)) L
Ciclohexano 84.161 0.210 553.6 40;t3 0.273 308. 353.9
Metilciclopentano 84.161 0.230 532.8 3'.7.85 0.272 319. 345.0
Melciclohexano 98.188 0.235 572.2 34.71 0.269 368. 3i1.1
Etileno 28.054 0.087 282.3 50.40 0.281 131. 169 .4
Propileno 42.081 0.140 365.6 46.6s 0.289 1RR4 ??S i
1-Buteno 56.108 0.191 420.0 40.43 0.2'77 239.3 266.9
cls-2-Buteno 56.108 0.205 435.6 42.43 0.273 233.8 276.9
trans-2-Buteto 56.108 0.218 428.6 41.00 0.275 )?'7 '7 )1A
1-Hexeno 84.161 0.280 504.0 31.40 0.265 354. 336.3^
Isobutileno 56.108 0.194 417.9 40.00 0.2"75 238.9 266.3
1,3-Butadieno 54.092 0.190 425.2 42:77 0.267 220.4 268j
Ciclohexeno 82.745 0.212 560.4 43.50 0.272 297. 356.r
Acetileno 26.038 0:187 308.3 6r.39 0.271 113. 789.4
Benceno 78,174 0.2i0 562.2 48.98 0.2'71 259. 353.2
Tolueno 92.741
,_ts 0.262 591.8 41.06
-alb6- 0.264 -- 316. 38}8
Etilbenceno 106.167 0.303 617.2 0:263 37a:*--qh
Cumeno 120.794 0.326 631.1 32.09 A.261 4)'7 42\ 6
o-Xileno 106.167 0.310 630.3 37.34 0.263 369. 417.6
m-XiTeno 106.t67 0.326 617.1 35.36 0.259 376. 412.3
p-Xileno 106.767 0.322 616.2 35.11 0.260 379. 411.5
Estieno 104.152 0.297 636.0 38.40 0.256 352. 418.3
Naftaleno t28.174 0.302 748.4 40.51 0.269 413. 491.2
Bifenilo 154.211 0.365 7 89.3 38.50 0.295 502. 528.2
Formaldehdo 30.026 0.282 408.0 65.90 0.223 1 15. 254.1
Acetaldehdo 44.053 0.291 466.0 55.50 0.221 154. 294.0
Acetato de metilo 74.079 0.331 506.6 47.50 0.257 228. 330.1
Acetato de etilo 88.106 0.366 523.3 38.80 0.255 286. 350.2
Acetona 5e.o8o o.3o't 508.2 47.01 0.233 209. 1)O t
Metil etil cetona '72:10'7 0.323 535.5 41.50 0.249 267. 352.8
ter dietflico 74.123 0.281 466.7 36.40 0.263 280. 30'7.6
ter metil r-butlico 88.150 0.266 497.1 34.30 0.213 329. ).+
/

68i
Tabla B.1: (Conrina)

Masa
vc
mola P/bx zc cm3 mol-l T"K
y::T"
Etanor___
0 561 s72.6 80.s7
:i?:?
_. .-___!6.069:--..0,645. 513,9
0.224 i18.
l-propanor -o.,szz _61:48 o.is )!__
60.0e6 536.8 ii.zi '.rri- ,*. -;1Jr.:^
l-Butanol 74.123 0.594 563.1 44 )? 370.4
l-Hexanoi toz.lil 0.57s 61r.; ;;;; X:2i ^.<A 27s' 3e0.8
2-propanol 60.0e6 0.668 5sj i;; E;Xr ,ri:
Fenor s4.113 0 444 6s4.3 6i ;; i.;;; 2zs. :1i:_
Eienglicot 62..068 0.487 719.7 77.00 0.246 45s.0
Acido acco 19i.C
60.053 0.467 592.0 57.86 O.zt; t:/9.j 470.5
88 106 0.681 ar,.t ;;.; 391.1
?:lf I:":*."
Acrdo benzoico 122.123 0.603 751.0 ,:;;; lot 1 ^ I
44.j0 0.246 a;;., Tii
Acetonitrilo 41.0s3 0.338 s4s.5 or.
qzo.t ;;;; itz. 3s4.8
fr:ffiJ' :!21r. 9.281 74.60 0.321 266.8 ts4.
Nihome,ano B .ja.; iii I;;:
Z??B B:3,i1
153.822 0.193 556-4 45.60 0.2i72
Tetracloruro de carbono {:Ll ?y,;
Cloroformo ;)z
1tg.37:, 0.222 SZ.q 54.72 0.293 23g. ;,1!;
Dicloromerao 94.932 0.199 ii.0 60.80 0.265 i85. 334.3
Cloruro de metilo 50.488 0.i53 qi3 66.80 0.2j6 1$. 312.9
Cloruo de erilo 64.574 0.190 q.i sz.1o 0.275 2oO. 249.1
Clorobenceno 12.558 0.250 AZZ + 45.20 28s.4
1
Tetrafluoroetano 102.030 0.327 zli.z 0.265 308. 404.9
40.60 0.258
Argn 39.948 0.000 f SO"S 48.98 0.291 198.0 24-r .1
Kriptn 83.800 0.000 iog..q ;;.; .;; 74.6 87.3
30 x.2
;n:i 131 o
11e.8
ooo 2*s.t ;;o ;# ,ir o 165 0
Hidrgeno--
oxgeno .iiii _8;i?Z
tl?9:.
,,1,3 ,tr,1t 383 Zir;i 1,1
o.ozz tsi.Z . 0.288 - 73.4._ 50.43
Nirrgeo 28.014 o.On n|.i 34.00 O.2gg
so.2
Airet 28.851 8g.z j7.3
0.035 132.2 3.7.45 O.2Bg
Cloro 7O.gO5 0.069 qtl.2 Tj.to 0.265
84.8
Monxido de cabono 28.010 O.OqA : tiZ.g
124. 239.1
Dixido de carbono
34.gg 0.299 %.4
44.010 0.224 zoi.z 73.g3 0.274 g4.0
81.7
Disjfuro de carbono 76.143 0.111 iiz. T.oo 0.275 160. ^,, 319.4
311:""i:ffi:"* 2ixz?
rrloxloo oe azutue
Trixido de azufe
64,065 0.245 430.g ::9
x:ii ::2: eTai l2Z,
7g.g4 0.269
2tzl
ZSZ..I
80.064 0.424 qgo. 82.10 0.255
Oxido ntrico O{O) 30.006 0.583 IAO.Z 64.80 0.251 127. 317.9
oxido nitroso (N2O) 44.013 0.141 ZOS. 72.45 0.2j4 58.0 tZt.4
Cloruro de hidrgeno 36.461
A.Bz zzq.i 83.10 0.249 gl. 97.4 784.7
188.2
Cianuo de hidrgeno 27.026
0.410 qSA.l 53.90 0.197
Agua 18.015 0.345 Aql.t 220.55 0.229 13g.
55.9
298.9
373.2
fl:*u:o. 17.031 0.2s3 coi.i 112.80 0.242 iz.5
Acido rutrico 63.013 0.714 SZO.O 6g.90 0.231 115. 23s.7
Acido sulfrico 9g.0g0 al 356.2
_seudoparmetros 924!
e)t ^ L-
^^ 0.147
64.00
y,
_177 610.0
= 0.7 9 y ysr= 0.21. Vea las ecuaciones (6.97)_(6.g9)
' para