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Solar Energy 86 (2012) 30843098


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Packed-bed thermal storage for concentrated solar power


Pilot-scale demonstration and industrial-scale design
G. Zanganeh a, A. Pedretti c, S. Zavattoni b, M. Barbato b, A. Steinfeld a,d,
a
Department of Mechanical and Process Engineering, ETH Zurich, 8092 Zurich, Switzerland
b
Department of Innovative Technologies, SUPSI, 6928 Manno, Switzerland
c
Airlight Energy Holding SA, 6710 Biasca, Switzerland
d
Solar Technology Laboratory, Paul Scherrer Institute, 5232 Villigen PSI, Switzerland

Received 29 March 2012; received in revised form 3 July 2012; accepted 26 July 2012
Available online 24 August 2012

Communicated by: Associated editor Yogi Goswami

Abstract

A thermal energy storage system, consisting of a packed bed of rocks as storing material and air as high-temperature heat transfer
uid, is analyzed for concentrated solar power (CSP) applications. A 6.5 MWhth pilot-scale thermal storage unit immersed in the ground
and of truncated conical shape is fabricated and experimentally demonstrated to generate thermoclines. A dynamic numerical heat trans-
fer model is formulated for separate uid and solid phases and variable thermo-physical properties in the range of 20650 C, and val-
idated with experimental results. The validated model is further applied to design and simulate an array of two industrial-scale thermal
storage units, each of 7.2 GWhth capacity, for a 26 MWel round-the-clock concentrated solar power plant during multiple 8 h-charging/16
h-discharging cycles, yielding 95% overall thermal eciency.
2012 Elsevier Ltd. All rights reserved.

Keywords: Packed bed; Solar thermal storage; Concentrated solar power; CSP; Sensible heat; Air

1. Introduction material; (2) applicability in a wide temperature range, with


limiting temperatures given by the rocks melting point; (3)
Thermal energy storage systems for concentrated solar direct heat transfer between working uid and storage
power (CSP) plants have featured the use of molten salt material; (4) no degradation or chemical instability; (5)
(DeLaquil et al., 1991; Herrmann and Kearney, 2002), no safety concerns, and (6) elimination of chemicals and
steam (Steinmann and Eck, 2006), and concrete (Tamme corrosive materials. The characteristics of packed beds
et al., 2004) for sensible heat, phase change materials for for thermal storage have been applied for food processing
latent heat (Watanabe et al., 1993), and reversible reactions (Laguerre et al., 2006), catalytic reactions (Beek, 1962),
for thermochemical storage (Gil et al., 2010; Lovegrove waste heat recovery (Jalalzadeh-Azar et al., 1996), and
et al., 2004; Medrano et al., 2010). Of special interest is low-temperature seasonal (Hahne, 2000) as well as high-
the use of a packed bed of rocks as sensible heat storing temperature hourly solar energy storage (Meier et al.,
material and air as heat transfer uid (Meier et al., 1991). 1991). Pertinent modeling studies (Beasley and Clark,
Such a storage concept can be incorporated in solar power 1984) are mostly based on the original analytic work by
plants using air as working uid (Bader et al., 2011). Its Schumann (1929) and include 1D and 2D heat transfer
main advantages are: (1) abundant and economical storing models with two separate phases (Ismail and Stuginsky,
1999), and several models developed for the temperature
Corresponding author. range 60200 C using air, water, or oil as working uid
E-mail address: aldo.steinfeld@ethz.ch (A. Steinfeld). (Gross et al., 1980; Mawire et al., 2009; Sanderson and

0038-092X/$ - see front matter 2012 Elsevier Ltd. All rights reserved.
http://dx.doi.org/10.1016/j.solener.2012.07.019
G. Zanganeh et al. / Solar Energy 86 (2012) 30843098 3085

Nomenclature

A surface area (m2) v interstitial uid velocity (m/s)


Bi Biot number; Bi hp d=k s () V volume (m3)
cp heat capacity of air at constant pressure (J/kg K) W function of c in Pfeers correlation ()
cs heat capacity of the solid (J/kg K) z axial coordinate (m)
C circumference of dodecagon (m)
d rock diameter (m) Greek letters
D diameter (m) a Convective heat transfer coecient (W/m2 K)
E energy (J) b Ratio of the average length between the centers of
f fraction of energy ow () two neighboring solids to the mean particle diam-
fcs compressive stress limit of concrete (N/m2) eter ()
fs safety factor () e void fraction ()
g gravitational constant; g 9:81 (m/s2)  emissivity ()
G mass ow rate per unit cross section (kg/m2s) c function of void fraction in Pfeers correlation/
hf specic enthalpy of uid (J/kg) ratio of the length of solid aected by thermal
hv volumetric convective heat transfer coecient conductivity to the mean particle diameter ()
(W/m3K) g Eciency ()
hp Particle convective heat transfer coecient j ratio of solid to uid thermal conductivity ()
(W/m2K) l dynamic viscosity (kg/ms)
hrv void to void radiative heat transfer coecient m Poisson ratio ()
(W/m2K) q density (kg/m3)
hrs solid to solid radiative heat transfer coecient r StefanBoltzmann constant (r 5:6704E  08
(W/m2K) W/m2K4)/stress (N/m2)/ capacity ratio of the
h thickness of concrete (m) storage unit ()
H height (m) /specic enthalpy of a control volume / relative humidity () / measure of the eective
(J m3/kg) thickness of the uid lm ()
k thermal conductivity (W/mK) w sphericity ()
L length of packed bed in Erguns equation (m) x specic humidity () / measure of the eective
m_ mass ow rate (kg/s) thickness of the uid lm ()
m bending moment per unit length (Nm/m0 )
M molecular weight (g/mol) Subscripts
Nu Nusselt number () 1 surrounding
p pressure (Pa) a air
Pe Peclet number; P e RePr () eff eective
Pr Prandtl number; Pr cp l=k () f uid
q Load on circular plate (N/m2) n spatial increment
q_ heat ux per surface area (W/m2) s solid
Q_ heat ux (W) sat saturation
r radius (m) w water
R specic gas constant (J/mol K)
Re Reynolds number; for packed bed Re Gd=l, for Superscripts
cover Re qDCover uwind =l () t time level
S section modulus per unit length (m3/m0 )
t time (s) Abbreviations
T temperature (K) or (C) CSP concentrated solar power
u specic internal energy (J/kg) RMS root mean square
U overall heat transfer coecient (W/m2 K)

Cunningham, 1995; Waked, 1986). Fewer studies have Recently, a packed bed of 150  150  150 mm3 Al2O3
dealt with the high-temperature range, including experi- bricks with 9 MWh storage capacity was tested using a
mental tests and modeling of a lab-scale packed bed of gas burner for charging at 650 C and discharging at
crushed steatite up to 550 C (Hanchen et al., 2011; 120 C (Zunft et al., 2011) and simulated using a thermo-
Meier et al., 1991) and of ZrO2 pellets up to 1000 C mechanical model (Dreissigacker et al., 2010). Most previ-
(Jalalzadeh-Azar et al., 1996; Nsofor and Adebiyi, 2001). ous simulation models considered temperature-invariant
3086 G. Zanganeh et al. / Solar Energy 86 (2012) 30843098

properties of uid and solid, which introduces uncertainties mined and are presented later. The tank is lled to the
for wide-range temperature operation. height of 2.9 m with pebbles with an equivalent sphere
In this paper, we describe the design, fabrication, and diameter of 23 cm. A 400 mm Foamglas insulation is
testing of a pilot-scale packed bed of rocks and its simula- packed under the lid. The hot air enters through the inlet
tion by means of a dynamic two-phase heat transfer model. pipe from the top, ows through the packed bed, and is
As it will be shown in the analysis, the model incorporates collected at the bottom after owing across a metal grid
variable thermo-physical properties for both uid and solid perforated with 10 mm-dia. holes every 30 mm, which pre-
phases and, hence, enables good matching between experi- vents congestion of the outlet pipe by the rocks and debris
mental and numerical results. The storage tank geometry while ensuring low resistance to the ow. Charging from
and practical design aspects are discussed for operating the top allows the exploitation of the buoyancy eect to
conditions relevant to large-scale industrial implementa- create and maintain thermal stratication inside the packed
tion. The validated model is further applied to optimize bed, the hottest region being at the top. During discharg-
and scale-up the design of a thermal storage system for ing, the direction of the ow is reversed as cold air is circu-
an industrial-size round-the-clock CSP plant and identify lated through the tank from the bottom.
the major sources of irreversibility. As it will be shown in the analysis that follows, an addi-
tional advantage of the conical shape of the storage tank
2. Pilot-scale thermal storage design and experimental setup vis-a`-vis a cylindrical shape is the larger storing volume
on top of the tank, where the temperature is highest, lead-
The pilot-scale storage design and experimental setup ing to a higher volume-to-surface ratio and hence smaller
are shown schematically in Fig. 1. The tank is immersed losses from the lateral walls. The relatively smaller volume
in the ground and has a truncated cone shape for exploiting at the bottom, where most of the energy is already
the eect of lateral earth pressure at higher load bearing extracted from the air, results in lesser necessary storing
and for reducing the normal force on the walls during ther- material.
mal expansion of the rocks by guiding them upwards (Lang The temperature is recorded by K-type thermocouples,
and Huder, 1990). It has a dodecagon cross section, a total of which ve are located inside the packed bed at dierent
height of 4 m, and a radius of the inscribed circle that vertical positions (T1T5, T6 is not covered with rocks)
decreases from 2 m at the top to 1.25 m at the bottom at and at a distance of 10 cm from the lateral walls, as indi-
a wall inclination of 12. The tank is made of concrete cated in Fig. 1. Two thermocouples measure the tempera-
for avoiding deforming caused by thermal expansion of ture just above the packed bed on the tank axis (T8) and
the storing material. The 12 lateral wall segments consist in the outlet pipe (T7). The air ow is fed with ambient
of a 15-mm layer of ultra-high performance concrete on air aspirated through air lters by a fan coupled to an elec-
the packed bed side with high mechanical stability and tric motor and heated in a tubular 58 kW electric heater
thermal conductivity and a 235-mm layer of low density before entering the storage tank. Additional measurements
concrete with low thermal conductivity in order to reduce include: ambient air temperature and relative humidity,
the thermal losses (Martinola et al., 2010). The thermal ow velocity, and pressure drop in the air ow across the
properties of the concrete layers were experimentally deter- packed bed.

Fig. 1. Scheme of the pilot-scale thermal storage conguration and experimental setup.
G. Zanganeh et al. / Solar Energy 86 (2012) 30843098 3087

3. Heat transfer model ht1 t


f ;n  hf ;n htf ;n  htf ;n1
en An qtf ;n m_ t
Dt Dz
A quasi-one-dimensional, two-phase heat transfer
An htv;n T ts;n  T tf ;n U twall;n C n T 1  T tf ;n 5
model was formulated. The unsteady-state energy equation
accounts for the convective heat transfer between the uid where the subscript n and the superscript t denote the spa-
and the solid phase, and axial dispersion by conduction tial and temporal position respectively. Considering the so-
and radiation through the solid phase. The single rock tem- lid phase equation, the rocks density is not varying with
perature is considered uniform, as justied by Bi  1 for temperature (Somerton, 1992). Since the eective thermal
all relevant operating conditions in this study (Bimax calcu- conductivity and the cross sectional area vary with space,
lated in the respective sections). The uid ow is assumed the axial dispersion needs to be calculated using the chain
plug ow. The pressure and viscous terms are neglected. rule. With a rst-order forward dierence in time and back-
Temperature-dependent solid and uid properties are con- ward dierence in space for the rst derivatives and second-
sidered for the temperature range of 20650 C. Energy order central dierence in space for the second derivative,
conservation for the uid phase term, see Panton (Panton, Eq. (4) becomes:
ut1 t
s;n  us;n
2005), after the indicated simplications, yields: 1  en An qs
Dt !
@qf H f @qf vH f k teff ;n An T ts;n1  T ts;n  k teff ;n1 An1 T ts;n  T ts;n1
Q_ 1 An htv;n T tf ;n  T ts;n
@t @z Dz2

The rst and second terms on the l.h.s. describe the 6


change in specic enthalpy of the uid over time and over The specic enthalpy of the uid phase is dened as
space respectively. Q_ accounts for the net ux in or out of RT
hf T ref cp;f dT and the internal energy of the solid phase
the uid phase. With the specic enthalpy of a control vol- RT
ume given by H f eAhf dz and the mass ow rate given by as us T ref cs dT . The temperature dependent heat capacity
m_ veAqf and invariant in space, Eq. (1) becomes: for the uid, cp;f , is a sixth order polynomial t on literature
@eAqf hf dz @hf dz values between 0 and 650 C (Incropera et al., 2007), and for
m_ Q_ 2 the solid, cs , is a correlation according to Kelley (Kelley,
@t @z
1960) to extrapolate the experimentally measured value at
The net ux is: ambient temperature as it will be introduced in the follow-
Q_ Ahv dZ T s  T f U wall CdZ T 1  T f 3 ing section. Due to the large variation of the solid heat
capacity with temperature and the large density of the rocks,
The rst term on the r.h.s. considers the convective heat it is important to implement the internal energy with respect
transfer between the uid and the solid phases and the sec- to variable properties. Further, the axial dispersion term has
ond term the losses through the lateral walls. Additional to be calculated using the chain rule due to varying cross
terms have to be added to the r.h.s. of Eq. (3) for the lid sectional area and eective conductivity. The packed bed
and the bottom (e.g. rst and last layers): U cover;conductive is divided in 100 equal layers. Temperature dependent coef-
Acover T surface  T 8 and U bottom;conductive Abottom T 1  T f ;bottom cients are calculated at every time step and for every layer.
respectively, which are explained in detail in the following Eqs. (5) and (6) can now be solved explicitly for ht1 f ;n and
section. t1
us;n . Using the known correlations for cp;f and cs , the tem-
Energy conservation for the solid phase yields:
perature is calculated at every time step and position using
@1  eAqs us dz @ @T s a NewtonRaphson subroutine. The following initial and
Ahv dzT f  T s k eff A dz 4
@t @z @z boundary conditions have to be fullled: (1) The initial solid
The l.h.s. comprises the change in internal energy with and uid temperature distributions of the packed bed
time. The rst term on the r.h.s. accounts for convective should be specied, but do not need to be uniform. (2)
heat transfer which is the coupling term between the solid The inlet temperature and mass ow rate should be specied
and uid phases. The second term accounts for axial dis- at all times, but they can be temporally variable. (3) Adia-
persion by conduction and radiation. batic conditions for the uid phase at the outlet, i.e.
@T f zH
@z
0. (4) Adiabatic conditions for the solid phase at
z0
3.1. Numerical method the inlet and outlet, i.e. @T s@z @T s zH
@z

0. Numerical sta-
bility is ensured by the more restrictive CourantFried-
Eqs. (2) and (4) are solved for hf and us at the next time richsLewy condition (Courant et al., 1928) of the uid
step. For the uid phase time derivative, the void fraction and solid phases. According to the von Neumann stability
and area are independent of time and are hence taken analysis (Anderson, 1995) on the simplied linear and peri-
out of the derivative. Using a rst-order forward dierence odic Eqs. (5) and (6), with the source terms neglected, the
in time and a rst-order backward dierence in space, and criteria are: CFL vDt < 1 for the uid phase and
Dz
using the lagging coecient method for the uid density,
Dt < 12 Dz2 1eq s cs
for the solid phase.
this becomes: k eff
3088 G. Zanganeh et al. / Solar Energy 86 (2012) 30843098

3.2. Physical correlations method at four dierent temperatures with an average


absolute deviation of 0.040.15 W/mK, depending on the
The thermo-physical properties of air are calculated measured specimen. The results are shown in Table 2.
using tabulated data given in literature (Incropera et al., The data is extrapolated to 650 C using the Tikhomirovs
2007). The mass ow rate is calculated using the air veloc- correlation (Somerton, 1992):
ity measured by the velocity meter, the pipe cross sectional h i
area, and the density of moist air (Moran and Shapiro, kT k 20  AT  Bk 20  C k 20 DT Ek20 F k G20
2006): qair;moist qair;dry 1R1x
w =Ra x
, with Rw and Ra the specic for k 20 > 2 W=mK 7
gas constant of water and air respectively. The density of
dry air is calculated using the ideal gas law, kT k 20  AT  Bk 20  C for k 20 > 2 W=mK 8
qair;dry p=Ra T , and the specic humidity using the par-
pw with k20 the thermal conductivity at ambient temperature,
tial pressure of water vapor: x M w
, with M w and
M a ppw and T in Kelvin. Tikhomirovs correlation is also used
M a the molecular weight of water and air respectively, for concrete (Toman and Cerny, 2001; Vodak et al.,
the atmospheric pressure, and pw the partial pressure of 1997). The values of the coecients AG are given in
water vapor: P w /P w;sat . The relative humidity, /, is Table 1 for the dierent rock and concrete types. For most
recorded during the experimental runs. The water vapor types of rocks the thermal conductivity decreases with tem-
saturation pressure, P w;sat is given by the extended Antoine perature (Vosteen, 2003). Typically, the higher k20, the
equation (Yaws, 1999): log 10(pw,sat/133.32) = stronger the decrease with temperature (Seipold, 1998). In
A  B/T  C log 10T + DT + ET2, with the coecients A contrast, for very small k20, the thermal conductivity stays
to E given in Table 1 and T in Kelvin. constant or even increases with temperature, which is the
Thermal properties of the rocks and the two concrete case for Gabbro and the low density concrete. The heat
types were experimentally measured. The ve dierent capacities, measured using a calorimeter, are shown in
types of rocks used in the packed bed, excavated from Table 2. Due to close values for the dierent rock types,
the Rafzerfeld area in Zurich, Switzerland, are identied the average is used to extrapolate the results up to 650 C
as Helvetic Siliceous Limestone, Quartzite, Limestone, (Kelley, 1960): cs(T) = A(B + CT + D/T2), with coecients
Calcareous Sandstone and Gabbro. The thermal conduc- AD given in Table 1. Heat capacities and thermal conduc-
tivity of the solid material is measured using the hot-wire tivities are plotted in Fig. 2 and 3 as a function of

Table 1
Values for the coecients of the correlations of Antoine, Tikhomirov and Kelley used in the paper.
k20 A B C D E F G
Antoine equation 29.8605 3152.2 7.3037 2.4247E09 1.808E06
Tikhmirov correlation
Helvetic siliceous limestone (Eq. (7)) 3.6 1.00E03 293 1.38 1.80E03 0.28 1.4 0.6
Quartzite (Eq. (7)) 5.39 1.10E03 293 1.38 1.70E03 0.25 1.28 0.65
Limestone (Eq. (7)) 2.82 1.00E03 293 1.3 1.70E03 0.5 1.4 0.5
Calcareous sandstone (Eq. (7)) 4.36 1.00E03 293 1.3 1.65E03 0.28 1.2 0.6
Gabbro (Eq. (8)) 2.05 2.00E03 293 2
Ultra-high performance concrete (Eq. (7)) 2.22 9.00E04 280 1.4 0.0025 0.3 1.15 0.75
Low density concrete (Eq. (8)) 0.35 2.00E03 250 0.6
Kelley correlation 705 1 6.14E04 1.93E+04

Table 2
Thermal properties of the dierent rock and concrete types as experimentally measured.
Quartzite Calcareous sandstone Helvetic siliceous limestone Limestone Gabbro
cp (J/kg K) 623 12 652 31 669 15 683 15 643 24
q (kg/m3) 2618 1.68 2661 1.71 2776 2.95 2697 1.66 2911 2.69
k (W/mK)
298 K 5.39 0.07 4.36 0.15 3.60 0.21 2.82 0.06 2.05 0.08
348 K 4.05 0.17 3.26 0.24 3.32 0.24 2.41 0.07 1.99 0.09
396 K 3.76 0.13 3.16 0.18 2.83 0.16 2.20 0.05 2.18 0.06
446 K 3.37 0.11 2.98 0.09 2.72 0.15 2.05 0.03 2.05 0.04
k (W/mK) Ultra high performance concrete Low density concrete
296 K 2.22 0.09 0.35 0.06
353 K 2.1 0.04 0.41 0.06
391 K 2.07 0.12 0.43 0.05
449 K 1.94 0.03 0.41 0.04
G. Zanganeh et al. / Solar Energy 86 (2012) 30843098 3089

" #
temperature. The densities of the rocks, measured using 5=3 1=3
1  1  e
Archimedes principle (Pratten, 1981), are given in Table 2. hp 1:26 cp G1=3 k=d2=3 9
W
Their average was used in the model and considered invari-
ant with temperature (Somerton, 1992). where W 2  3c 3c5  2c6 with c 1  e1=3 . The par-
Various rock-to-uid convective heat transfer correla- ticle and volumetric convective heat transfer coecients are
tions have been investigated and showed to deliver negligi- related by: hv hp 61e
d
. The eective thermal conductivity
ble dierences in the obtained temperature proles (Alanis in a packed bed has been extensively studied (Antwerpen
et al., 1976; Coutier and Farber, 1982; Lof and Hawley, et al., 2010). Because of the high temperature of charging
1948; Pfeer, 1964). Due to similar ow conditions small and temperature gradient in the axial direction, the correla-
Reynolds number and Pe  1 the correlation by Pfeer tion of Kunii and Smith is applied, which considers the
was chosen: thermal conductivity of the solid and the uid, as well as
the radiative transfer (Kunii and Smith, 1960; Yagi and
Kunii, 1957):
2 3
6  7
6 hrv d b1  e 7
6  7
k eff k f 6e 1 b 7 10
6 kf 1 kf 7
4 c 5
1 hrs d ks
/ kf
The void to void radiative heat transfer coecient, hrv , is
represented by:
  
e 1  s
hrv 0:1952 1 T f =1003 11
21  e s
The solid surface to solid surface radiative heat transfer
coecient, hrs , is:
 
s 3
hrs 0:1952 T s =100 12
2  s
Fig. 2. Thermal conductivity and average heat capacity of the rocks as a The emissivity of the rocks, s , is 0.85. The factor b in
function of temperature. Extrapolations obtained using Tikhomirovs Eq. (10) is dened as the ratio of the average length
correlation for thermal conductivity (Somerton, 1992) and Kelleys
between the centers of two neighboring solids to the mean
correlation for heat capacity (Kelley, 1960). Markers indicate experimen-
tally measured values, dashed and solid lines extrapolations: j Quartzite, particle diameter and ranges from 0.82 (close packing) to
 Calcareous Sandstone, N Helvetic Siliceous Limestone, x Limestone, 1.0 (loose packing). Due to the random packing of the
and d Gabbro. rocks, an average value of 0.9 is taken in the model. The
factor c is dened as the ratio of the length of solid aected
by the thermal conductivity to the mean particle diameter;
it has a value of 2/3. The factor / is a measure of the eec-
tive thickness of the uid lm adjacent to the contact sur-
face of two solid particles:
e  e2
/ /2 /1  /2 13
e1  e2
where /1 and /2 represent the two extreme cases of the
void fraction e1 0:476 and e2 0:26 and are calcu-
lated as:
j1 2
1 j
sin hi 21
/i  14
2 lnj  j  1  j1
j
1  cos h i 3j
With j k s =k f and sin2 hi 1=ni . n is the number of the
contact points on a semispherical p surface of one solid par-
ticle with n1 = 1.5 and n2 4 3.
For the lateral walls, the overall heat transfer coecient
Fig. 3. Thermal conductivity of the two concrete types as a function of is calculated as:
temperature. Extrapolations obtained using Tikhomirovs correlation
(Somerton, 1992). Markers indicate experimentally measured values, 1 1 Xn
1 rj1
dashed lines extrapolations: d ultra high performance concrete and x low rinside ln 15
U wall U inside k
j1 j
rj
density concrete.
3090 G. Zanganeh et al. / Solar Energy 86 (2012) 30843098

The second term on the r.h.s. considers conduction T sky T ambient 0:711 0:56T dewpoint  273=100
through three layers: ultra-high performance concrete,
0:73T dewpoint  273=1002 1=4 25
low density concrete and ground. T 1 is assumed after
20 cm of depth in the ground, as justied by thermal with T ambient and T dewpoint in Kelvin. The incoming solar
images. The wall-lm heat transfer coecient, U inside , is radiation is considered during daytime and is calculated
given as: as:
U inside aconvective aradiativeconductive 16 Q_ solar q_ solar Acover 26
Where aconvective accounts for convective heat transfer
with q_ solar 1000 W=m2 . The only unknown, T surface , is
between the uid and the lateral walls (Beek, 1962):
obtained at every time step by solving Eq. (18) using
kf the NewtonRaphson method, which in turn is used to
aconvective 3:22Re1=3 Pr1=3 0:117Re0:8 Pr0:4 17
d calculate the cover losses. Conductive heat transfer
The second term in Eq. (16) accounts for radiation and through the bottom concrete layer and 10 cm of ground
conduction heat transfer between the packed bed and the is considered, after which ambient temperature is
walls and is obtained using correlations given by Ofuchi assumed.
and Kunii (Ofuchi and Kunii, 1964) that are similar to The pressure drop in the packed bed is calculated using
the Eqs. (10)(14) introduced above. The heat loss through the equation given by Ergun (Ergun, 1952) which has been
the lid is calculated by applying an energy balance on the modied with a buoyancy term (Anderson, 2003):
!
lid: LG2 1  e2 l 1e DT
Dp A B 3 qgL 27
Q_ coverloss Q_ conductive Q_ convective Q_ radiative  Q_ solar 18 qd 2
e w Gd
3 ew T
which states that the energy conducted from the storage to The rst and second terms in the brackets represent vis-
the lid surface must be equal to the energy loss by convec- cous and kinetic energy losses respectively. The second
tion and radiation to the surrounding under consideration term considers the pressure dierence over the layer due
of incoming solar radiation during day time. The conduc- to temperature dierence. It has an augmenting eect on
tive term is: the pressure drop during charging and a reducing eect
Q_ conductive U cover;conductive Acover T surface  T 8 19 during discharging. A and B are study dependent constants
and w considers the sphericity of the rocks (Ozahi et al.,
where U cover;conductive considers conduction through three 2008) with unity for a perfect sphere. Published data by
layers: Foamglas insulation, concrete lid, and 200 mm Macdonald (Macdonald et al., 1979) for randomly shaped
ground that was put on top of the lid to reduce thermal gravel with similar particle size and void fraction as in this
losses. The convective term in Eq. (18) is calculated as: study have been taken: A = 217, B = 1.83 and w = 0.6. Eq.
(27) is solved for every layer after every time step consider-
Q_ convective aoutside Acover T surface  T ambient 20 ing the local ow conditions separately from Eqs. (5) and
aoutside is the convective heat transfer at the lid outer (6) in order to calculate the pressure drop across the
surface under consideration of the wind speed and packed bed.
temperature of the ambient, both recorded during the The void fraction of the packed bed was measured in an
experimental runs: experimental setup built for this purpose. A cylindrical iron
tank with 2 m inner diameter and 1.5 m height was lled
NuD k a with the rocks that were previously used in the thermal
aoutside 21
Dcover storage. A steel tube with 40 mm outer diameter and same
height as the tank was welded coaxially to the bottom of
where (Incropera et al., 2007): the tank to measure the water level that is lled in the
packed bed during the measurements. A hole was bored
Nux 0:332Re1=2 Pr1=3 for Re < 105 22
at the bottom of the tube in order to assure equal water
4=5 1=3 5
NuD 0:037Re  APr for Re > 10 level as in the packed bed. The tank is lled in ve steps
4 1 and the water level in the tube is measured after the end
withA 0:037Rex;critical  0:664Re2x;critical 871 Rex;critical 105
5
of every step using a Bosch DLR130K digital distance mea-
23 surer (accuracy 1.5 mm). With the lled water volume
The radiation loss from the cover is calculated as (Siegel known, the void fraction is calculated as:
and Howell, 2002): V eff
e 28
Aeff DH w
Q_ radiative ground rAcover T 4surface  T 4sky 24
where V eff is the eective water volume lled in the tank
with ground 0:95. The sky temperature, T sky , is calculated and Aeff the eective surface area of the tank, and DH w
as (Berdahl and Martin, 1984; Martin and Berdahl, 1984): is the dierence in the water height between two
G. Zanganeh et al. / Solar Energy 86 (2012) 30843098 3091

in contrast to previous studies (Gross et al., 1980;


Hanchen et al., 2011), no bypass fraction of the mass
ow is assumed.

3.3. Comparison of cylindrical and truncated conical tank

The model is used to compare the performance of a ther-


mal storage unit with truncated conical shape vs. the more
commonly used cylindrical shape. Fig. 5 shows the temper-
ature distribution and the energy stored per unit height
after 8h charging, as well as the pressure drop as a function
of charging time for two tanks with equal volume. Dimen-
sions and operating conditions are shown in Table 3. A
smaller height and hence volume of the storing material
is needed to extract the energy from the air ow through
Fig. 4. Experimentally measured axial void fraction distribution in the the conical-shaped storage tank as compared to the cylin-
packed bed (height = 0 at top). drical tank under the same operating conditions since more
energy can be stored in the top of the tank because of the
consecutive measurements. The axial void fraction distri- larger diameter. In addition, due to the larger volume to
bution showed a second order monotonic decrease with surface ratio in the high temperature region, the wall losses
packed bed depth from 0.366 to 0.327 which corresponds are smaller for the conical tank, as explained in Section 2
to an 11% decrease in void fraction after which it ap- (EWallLoss;Conical 51:9 kW h vs. EWallLoss;Cylindrical 68:5 kW h).
proaches asymptotically a value of 0.325. The results of However, due to the larger cover area, the cover losses
the measurement are shown in Fig. 4. The reason for are larger for the conical tank (ECoverLoss;Conical 11:1 kW h
the decrease is mainly the non-homogeneous and random vs. ECoverLoss;Cylindrical 6:3 kW h). The pressure drop increases
distribution of size and shape of the rocks and the own- for both cases with time as the overall temperature inside
weight eect of the rocks (DuToit, 2008). Layers close to the packed bed increases, causing the density to decrease
the bottom and top of the packed bed were omitted in and the dynamic viscosity to increase, which in turn
order to exclude the eects of the bottom and the distur- increases the pressure drop according to Eq. (27). At the
bance of the bed near the open area, hence, the results beginning of the charging phase, when the temperature is
are shown from around 510 rock diameters from both low in the whole packed bed, the pressure drop is larger
ends. The average bulk void fraction was 0.342. In a pre- for the conical tank because of the reciprocal dependence
vious study, the inuence of axially variable void fraction of the kinetic and viscous terms on the radius and because
on the heat transfer and pressure drop in the packed bed that the cone-to-cylinder radius at the top is smaller than
was investigated via CFD simulations (Zavattoni et al., the cylinder-to-cone radius at the bottom. As the tank is
2011). Non-uniform radial distribution or the wall charged, the pressure drop in the cylindrical tank exceeds
eect can be neglected due to the large tank to rock that of the conical tank because of the larger average tem-
diameter ratio (DTank/d > 80) (Meier et al., 1991). Hence, perature in the cylindrical tank.

Fig. 5. Temperature and energy distribution after 8 h charging (left), and pressure drop as a function of charging time (right) for a cylindrical storage tank
vs. a conical storage tank of equal volume. Dimensions and operating conditions given in Table 3.
3092 G. Zanganeh et al. / Solar Energy 86 (2012) 30843098

Table 3
Dimensions and operating conditions of the storage units of Fig. 5.
Cylindrical Conical
rtop (m) 1.5 2
rbottom (m) 1.5 0.94
Height (m) 3 3
Packed bed volume (m3) 21 21
tcharging (h) 8
m_ (kg/s) 0.4
d (m) 0.03
Tch (C) 650

3.4. Importance of radiative heat transfer


Fig. 7. Heat transfer coecient between the packed bed and the wall,
Radiation exchange between the particles as well as Uinside, and the contributions of its composing terms for case #1
investigated above.
between the particles and the walls is signicant at the high
temperatures involved. The former aects the eective ther-
mal conductivity in the packed bed and the latter the ther- on the convective heat transfer between the uid and the
mal losses to the surrounding. The eect of radiation has wall, which in turn is dependent on the ow and therefore
been considered by employing Eqs. (10)(14). Fig. 6a operating conditions. For case #1 investigated above, the
shows the eective thermal conductivity of the packed heat transfer coecient between the packed bed and the
bed and the contribution of conduction and radiation to wall (U inside , Eq. (16)) and the contributions of its compos-
the eective thermal conductivity as a function of temper- ing terms (radiation, conduction and convection) are
ature. While conduction is superior at below 150 C, radi- shown in Fig. 7 for the last time step as a function of tank
ation becomes predominant at higher temperatures. Fig. 6b height. Again, in the high temperature region (top), the
shows the temperature prole in the packed bed after 8 h of contribution of radiation is predominant and decreases
charging for a conical tank according to Table 3 for three towards the low temperature region (bottom).
dierent cases: #1 k eff according to Eq. (10), #2 k eff
according to Eq. (10) with radiation neglected (hrv 0 3.5. Comparison of temperature-dependent and constant
and hrs 0) and #3 k eff 0, hence without axial conduc- properties
tion. As expected, the thermocline attens with increasing
eective thermal conductivity (from case #3 to #1). The Fig. 8 shows a comparison of simulation results for con-
eect of axial conduction when radiation is neglected is stant and temperature dependent solid and uid properties.
small (case #2 vs. #3), while considering radiation aects All of the uid and solid properties are evaluated at the
the temperature prole to a larger extent, especially in average temperature of 335 C for the case with constant
the high temperature region. properties. The most important parameter is the solid heat
The contribution of the radiative heat transfer to the capacity, which aects the amount of energy that can be
thermal losses is not straightforward since the overall wall stored. Its value is under-predicted in the hot region and
heat transfer coecient, U wall (Eq. (14)), is also dependent over-predicted in the cold region when constant properties

Fig. 6. (a) eective thermal conductivity of the packed bed and the contribution of conduction and radiation to the eective thermal conductivity as a
function of temperature and (b) the temperature prole in a conical tank according to Table 3 for three cases: #1 ke according to Eq. (10), #2 ke
according to Eq. (10) with radiation neglected and #3 without axial conduction (ke = 0).
G. Zanganeh et al. / Solar Energy 86 (2012) 30843098 3093

Fig. 8. Temperature prole inside the packed bed for constant and temperature dependent solid and uid properties at four dierent times for 20 h of
charging. All properties evaluated at 335 C for the constant properties case. Dimensions of the packed bed same as the conical tank in Table 3.

are considered. Therefore, the temperature prole is


slightly over-predicted for constant properties in the hot
region, while the opposite eect is more pronounced in
the cold region.

3.6. Experimental validation with pilot-scale storage unit

An experimental run consisting of a charging time of


110 h was carried out in order to validate the numerical
model. Real time inlet temperature and mass ow rates
are considered. The average equivalent sphere diameter
of the particles is 2.5 cm. The maximum Biot number
(Bi hp d=k s ) reached is 0.18 (for hp 15 W=m2 K and
k s 2 W=mK). The assumption of homogeneous intrapar-
Fig. 9. Comparison of numerically calculated (curves) and experimentally
ticle temperature distribution is hence satised. The aver-
measured (markers) temperatures for the 6.5 MWhth pilot-scale thermal
age of uid and solid temperatures numerically modeled storage unit.
(curves) and the experimentally measured temperatures
(markers) are plotted in Fig. 9. The agreement is reason-
able good. The root mean square deviations of the simu- grid in the vicinity of the thermocouple. The thermal
lated and measured temperature proles are shown in capacity of the storage, dened as the energy stored in
Table 4. Slight over-prediction of the temperature proles the packed bed when charged from ambient temperature
by the model at the beginning of the charging phase is to be isothermally at the inlet temperature of 650 C, is
due to radial temperature distribution in the tank vs. the 6.5 MWh. A total 3.1 MWhth was fed to the storage, of
average temperature obtained by the 1D model as well as which 86% is stored in the packed bed while 10.2% is lost
the assumption of plug-ow in the model. This eect through the lateral walls and 3.1% through the cover.
becomes less pronounced towards the end of the charging The energy lost through the bottom and the energy owing
phase and tank bottom due to more homogeneous temper- out of the storage from the bottom sums up to 0.7% of the
ature as well as ow distribution in the tank. The discrep- input energy. The high losses are correlated to poor
ancy between the modeled and measured temperature T1 is insulation on the lateral walls and the relatively small vol-
due to near wall eects and the presence of the perforated ume-to-surface ratio of the tank. In order to investigate the
3094 G. Zanganeh et al. / Solar Energy 86 (2012) 30843098

Table 4
The root mean square deviation of the simulated temperature from the measured temperature for the thermocouples in the packed bed and in the outlet,
and the reference case vs. measurement deviations considered.
Thermocouple RMS deviations RMS deviations of reference RMS deviations of reference RMS deviations of RMS deviations of
of reference case case vs. deviations of case vs. deviations of thermal reference case vs. reference case vs.
vs. experimental thermal conductivity of conductivity of concrete deviations of heat deviations of density of
values (K) rocks considered (K) considered (K) capacity of rocks rocks considered (K)
considered (K)
T1 16 0.15 0.21 3.68 0.64
T2 4.4 0.19 0.47 6.06 1.04
T3 8.3 0.16 0.68 6.66 1.12
T4 7 0.17 0.72 5.78 0.97
T5 15.9 0.22 0.58 3.86 0.65
Toutlet 3.3 0.07 0.07 1.29 0.23

sensitivity of the simulations on the measurement uncer- respect to the nest grid. The normalized results are plotted
tainties of the thermal properties of the rocks and concrete in Fig. 10. As a compromise between calculation time and
types, the simulation was repeated with the mean standard accuracy, 100 grid points were chosen.
deviation of the measurements, as indicated in Table 2,
added to the reference values. The percentage mean devia- 4. Industrial-scale thermal storage system
tions are 3.2% for the thermal conductivity of the rocks,
3.7% and 11.7% for the thermal conductivity of the ultra The validated model is applied in the design of an indus-
high performance concrete and low density concrete trial thermal storage system for a round-the-clock 26 MWel
respectively, 0.5% for the rocks density and 3% for the CSP plant located in Ait Baha, Morocco. Simulations are
rocks heat capacity. The root mean square deviations of performed for the month of May, which has the highest
the temperature proles obtained with respect to the tem- monthly DNI for 8 h of charging followed by 16 h of dis-
perature proles obtained using the reference values are charging. Thus, 1/3 of the air mass ow rate coming from
shown in Table 4. For the heat capacity the results are the solar eld is directly fed to the heat exchanger for the
slightly aected, while the eect for the other properties steam-based Rankine cycle for electricity production and
is negligible. After several charging and discharging tests, 2/3 of it is directed to the two thermal storage units, each
neither the rocks nor the concrete wall segments showed with a thermal capacity of 7.2 GWhth. Construction limita-
any visible damage or signs of deterioration. No carry over tions determine the lid size to a maximal 20 m in radius, as
from the rock material was observed during the tests. calculated in Appendix A. The mass ow rate through
every storage unit is chosen so that the total pumping
energy required for a cycle stays below 2% of the input
3.7. Sensitivity analysis on number of grid points
energy of the storage unit per cycle. The charging temper-
ature coming from the solar eld is 650 C and the
In order to justify the number of grid points chosen,
discharging temperature coming from the power block
simulations are carried out for 25, 50, 100 and 200 grid
is 150 C (Kiameh, 2002). The Biot number arrives at a
points. For every case, the average root mean square of
maximum value of 0.15 (for hp 7:3 W=m2 K and
the deviations in the temperature prole is calculated with
k s 1:45 W=mK). The dimensions and operating
conditions of the storage unit are listed in Table 5.
The charging eciency is dened as the fraction of the
stored energy in the rocks at the end of the cycle to the
net input and pumping energy:
EStored
gCharging 29
ENetInput EPump;Charging
Ptcharging
where ENetInput EInput  Eoutflow and EPump;charging i0
Dpi mDt=qg
_ fan gRankine , considering Rankine cycle eciency
to produce the required electricity. The discharging e-
ciency is dened as the fraction of the recovered energy
during the discharging phase to the stored and pumping
energy:
Fig. 10. Normalized average RMS deviation of the temperature prole ERecovered
obtained with the indicated number of grid points with respect to the nest gDischarging 30
case (200 grid points). EStored EPump;Discharging
G. Zanganeh et al. / Solar Energy 86 (2012) 30843098 3095

Table 5 EBottomLoss;Cycle
Dimension and operating conditions of the 7.2 GWh packed bed thermal fBottomLoss 34
ENetInput
energy storage.
Dimensions The fraction of the pumping energy is dened as:
rtop (m) 20 EPump;Charging
rbottom (m) 16 fPump;Charging 35
Height (m) 25 ENetInput
Insulation Microtherm/Foamglas EPump;Discharging
Lid (m)/(m) 0.6/0.5
fPump;Discharging 36
ERecovered
Lateral walls (m)/(m) 0.3/0.5
Bottom (m)/(m) 0/0.4 The capacity ratio indicates to which extent the maximal
Number of storage units 2 theoretical capacity of the storage unit is being exploited
and is dened as follows:
d (m) 0.03
Estored
m_ total solar field (kg/s) 396 r 37
m_ perstorage;charging (kg/s) 132 Emax
stored
m_ perstorage;discharging (kg/s) 66
The cyclic energy ows and the nal outow tempera-
Operating conditions ture (top) at the end of discharging as a function of cycle
tcharging (h) 8
number are plotted in Fig. 11. Due to the small amount
tdischarging (h) 16
Tcharging (C) 650 of thermal and pumping losses, the charging eciency
Tdischarging (C) 150 approaches 100% and hence the discharging and overall
gfan 0.95 eciency are almost equal throughout the cyclic operation.
gRankine 0.35 The cover and bottom losses remain constant throughout
the cycles since the temperature at the top and bottom is
not varying signicantly with time, while the lateral wall
The overall cycle eciency is hence: losses increase due to the increase of average tank temper-
gOverall gCharging gDischarging 31 ature (Fig. 12). The sum of the thermal losses remains
below 0.5% of the input energy. The pumping energy dur-
ing charging is larger than during discharging due to the
The fractions of the cyclic thermal losses are dened as: larger mass ow rate and increases with cycle number for
both cases due to the increase in average tank temperature
EWallLoss;Cycle
fWallLoss 32 and the consequent increase in air viscosity. Although the
ENetInput
outlet temperature at the end of the discharging phase
drops below 400 C for the rst cycle, it increases signi-
ECoverLoss;Cycle cantly with every cycle and remains above 590 C as the
fCoverLoss 33
ENetInput storage approaches steady cyclic behavior, which is crucial

Fig. 11. Cyclic energy ows and nal outow temperature (top) at the end of discharging as a function of cycle number for a 26 MWel CSP plant thermal
storage system. Dimensions and operating conditions are given in Table 5.
3096 G. Zanganeh et al. / Solar Energy 86 (2012) 30843098

Fig. 12. Temperature prole of the packed bed at end of the charging and discharging phases for cycles 1, 10, 20 and 30.

for the operation of the power block. During the cyclic Appendix A
operation, the discharging eciency increases from 73%
to 95%. As shown in Fig. 12, the thermocline inside the Since the low tensile stress limit of concrete can be over-
packed bed attens and the temperature front moves come by armoring, the size of the concrete lid for a given
downwards during the cyclic operation. thickness and concrete type is limited by the compressive
stress limit, fcs . For a circular plate supported on its edge
5. Summary and unconstrained rotational degrees of freedom, the max-
imum bending moment in the plate center is calculated as
A pilot-scale thermal storage system based on a (Girkmann, 1963):
packed-bed of rocks with air as working uid was built, qr2
tested, and modeled. The tank is immersed in the ground mmax 3 m A1
16
and has a truncated cone shape for exploiting the eect of
lateral earth pressure at higher load bearing and for With m the poisson ratio, r the lid radius, and q the load on
reducing the normal force on the walls during thermal the lid, calculated as q = hqg, with h and q the thickness
expansion of the rocks by guiding them upwards. A and density of the concrete, respectively, and g the gravita-
dynamic numerical heat transfer model that solves the tional constant. Further, the elastic section modulus is cal-
unsteady energy equations for the uid and solid phases culated as:
was developed and experimentally validated. The model h2
was further applied in the scale-up design of an industrial S A2
6
thermal storage system, consisting of two 7.2 GWhth
The maximal stress is then rmax mmax =S which has to
thermal storage units, for round-the-clock electricity
be smaller than the compressive stress limit under consider-
production by a 26 MWel CSP plant. The compressive
ation of a safety factor, hence rmax < fcs =fs . For a standard
stress of the concrete lid limits the size of each tank.
concrete with fcs 40N =m2 , a thickness of 50 cm, a density
The overall thermal losses remains below 0.5% of the
of 2500 kg/m3 and a safety factor of fs 1:5, the maximal
input energy, the outow temperature during the dis-
radius for the concrete lid will be 20 m.
charging remains above 590 C, and the overall thermal
eciency reached 95% as the storage system operation
approaches steady cyclic behavior. References

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