Escolar Documentos
Profissional Documentos
Cultura Documentos
MetallurgicalWastes
theExampleofBauxiteResidues
Prof.Ioannis Paspaliaris
Seeding
Filtration
Alumina
Calcination
Precipitation
Bauxite
Lime+CausticSoda
BauxiteResidue
Milling Digestion Thickening
(RedMud)
Washing
TheBayerProcessforAluminaProduction
Seeding
Filtration
Alumina
600kg Calcination
Precipitation
Bauxite(wt%)
Lime+CausticSoda
Al2O3 56 Bauxite
Fe2O3 25
SiO2 2
1000kg
TiO2 3 RedMud(wt%)
Al2O3 16
CaO 1 RedMud Fe2O3 48
Na2O
LOI 12
400kg SiO2 6
Milling Digestion Thickening TiO2 6
CaO 11
Washing Na2O 2
LOI 11
GlobalBauxiteResiduesProduction
Producedasaslurry
100120Mt/year
Usualhandlingpractice:
Disposedinsealedor
unsealedartificial
impoundments
BauxiteResiduesDamFailure
Hungary2010
AluminumandAluminaProductioninGreece
AluminiumofGreece(ALSA),aluminarefineryand
aluminiumproductionplant
Producing800,000tonsofalumina and165,000tonsof
aluminiumannually
Theonlyverticallyintegratedbauxite,aluminaandaluminium
productionplantinEurope.
ALSA:650,000tonsofbauxiteresidues(redmud) 6
BauxiteResidues:ThecaseofAluminium ofGreece
DewateringBRinFilter
Presses
Thefiltercakehasamoisture
contentto25%,whichmakes
iteasiertohandle
AoG wasoneofthefirst
WesternEuropeanplantsto
applythistechnology
AoG Produces650,000tBR
peryear
CanthisBRcakebeapotentialresource?
BriefHistoryinBRExploitation
Since1999AoG,NTUAareactivelyparticipatinginRTDprojectsforBRtreatment
Road Construction Mine Remediation Landfill BR clay
AoG BRusedin
BR Soil BR clay
CementIndustry(ironsourcein
clinker)
Brick/TileIndustry(substitution
ofclay)
Geopolymer bricks
SoilRemediation/Vegetation
cover
RoadBaseConstruction
BR Soil BR Geopolymers
Landfillbarrier/cover
BackfillingofAbandonedMines
NewApproachesinBauxiteResidueValorisation
Bauxite(wt%) 56 1 2 3 25 12
RedMud(wt%) 16 11 6 6 48 2 11
RedMudcontainsabout48%ironoxide.
IronisapotentialelementthatcouldberecoveredfromRedMud.
Is itfeasible??
ReductiveSmeltingofBauxiteResidue
FineRedMud PigIron
48%Fe2O3 95%Fe
CokeFines Slag
Reductive
Smelting
+
Innovative Electric Arc Furnace with a novel feeding system, capable to directly
treat finely sized material, without significant material loss in the offgases. The
material is directly fed to the EAF and prior agglomeration is not necessary.
ReductiveSmeltingofBauxiteResidue
RedMud
PigIron
ReductiveSmeltingofBauxiteResidue
Twotestcampaignshavebeencarriedout
ThefirstonewithNTUAa750kVA pilotElectricArcFurnace
ofa600kgbatchcapacity
Pilotplantinstallation PigIronProduction
ThesecondatAluminium ofGreecewith1MVAElectricArcFurnace
ofa1000kgbatchcapacity
CaseStudywithBauxiteResidues
Totalcharge:550kg
77kg 350kg 53kg 70kg Fluxes:351kg/tnRM
MolarratioC:Fe=2.43 [StoicheometircreductionratioC:Fe=1.5]
(%wtCaO+%wtMgO)/(%wtSiO2)=0.94 [NeutralSlag=1.0]
Experimental conditions
Preheatslag:200kg OpticalPyrometry
AroundElectrodes17002400C
FeedingRate:3kg/min
MeltsurfaceT=14001600C
Smeltingtime:3.5h CrustsurfaceT=9001100C
13
CaseStudywithBauxiteResidues
Pigiron Exp%wt
%Fe 87.09% Slag Exp%wt
%C 4.05% %Na2O 1.89%
%S 0.05% %MgO 4.65%
%P 0.20% %Al2O3 24.23%
%Si 1.70% %SiO2 32.62%
%Ti 0.45% % SO3 1.09%
%V 0.28% %CaO 29.65%
%Cr 4.43% %TiO2 6.79%
TOTAL 99.83% %Cr2O3 0.41%
PigIronPhase 120kg %Fe2O3 1.11%
%C 0.49%
Fe%Recovery 97%
TOTAL 102.43%
HighCrpresencedueto SlagPhase 280kg
initialrefractory Basicity 1.05
dissolution
14
Resultsfrom750kVA experiments
Questionsraised
Whatcanwedowiththeproducedslagfrom
thesmeltingprocess?
NewApproachesinBauxiteResidueValorisation
RedMud
PigIron
MineralWool
Fiberisation
CaseStudywithBauxiteResidues
Slagfiberization
AoG PilotPlant
1MVAAMRTEAF(AC,3electrode,dust
treating,batchcapacity1t)
MeltFiberizing Line
StaticBedElectricDryer
Duringatwoyearlongexperimental
campaignstreatedmorethan25tofBR
Morethan5tofPigIronproducedand
testedinsecondarysteelproduction
HighQualitymineralwoolproduct
producedfromtheslag 18
TheENEXALBauxiteResidueTreatmentProcess
AoGs 1stPilotPlant
RedMudEAFCarbothemic Smelting
Openbathoperation
Continuousfeeding6.65kg/min
MeltTemperatureapp1600oC
EnergyConsumption:1508kWh/tofBR
Dustinfilters4%wt offeed
Feed Batch
Dry BR (kg) 700
Silica (kg) 126
Lime (kg) 105
Coke (kg) 140
Total Feed (kg) 1071
ENEXALBRTreatment
PigIronProduction
Producedmetalwithinspecificationforusein
secondarysteelindustry,asanupto20%
steelscrapsubstitute
Morethan5tpigironproducedintotal
MineralWoolProduction
Slagmeltwithinempiricalindexes
Fibrewithgoodquality:
=0,034W/(mk)[UNIEN12667]
Averagefiberdiameter7micron
Brightcolor(lowMn content)
HighMechanicalresistanceduetohighTiO2
BR
Mineral
Wool
Commercial
Mineral
Wool
TheENEXALBauxiteResidueTreatmentProcess
AoGs 2ndPilotPlant
Smeltingenergy14.5%in
excessofthermodynamic
requirement
Overallplantconsumption
2MWh/tBR
BRTreatmentresults
Upscalingwillbringhigherenergy
efficiency,especiallyinBRdrying
Initialstudiesshowtheprocessto
beprofitable
Breakevenpointisachievedwitha
fairlylowmineralwoolprice
but
Pigironrevenuesaccountsonlyfor
25%oftheoperatingcosts
TreatingtheAoG annualBR
productioncanproduce0.5Mtof
MineralWoolproducts
OnGoingResearch
TheAoG BRalsocontainsapproximately
0.1%wtREE
(mainlyasSc,CeandNd)
Whatcouldbeapossibletechnologyfor
theirrecovery?
SelectiveleachingofREEfromRedMud
OngoingRTDeffortfortheselective
leachingofREEfromredmudusing
IonicLiquids
100
90
REEinRedMud~1200ppm 80
600 70
%recovery
500 60
400 50
40
ppm
300
30
200 20
100 10
0 0
Ce La Sc Nd Y Pr Sm Dy Gd Yb Er Dy La Nd Y Ce Sc Si Al Fe Ca Na Ti Cr V
Directleachingofredmudwith
HbetTf2Ninwaterat60Cwith
10%pulpdensity
IonicLiquidNTUAPilotPlant
REEconcentrate IntheframeworkofEURAREaILpilotplantisbeing
/RedMud setupinNTUA
Thepilotwilldemonstratethefullprocessingchain
fromconcentratetoREEmetalusingIL
ILLeachingstage
2X1.0lt reactors
0.1kgbatch
220C ILSeparation
MixerSettlers
Units
S/Lseparation 20 stages
12lt/hour Upto100C ILelectrowinning
95C Flowrate1lt/h
100mlvolume
PrecipitationUnit
REEMetal
2X1.0lt reactors
95C
AlSc Alloy
RedMud Steel
Industry
REEandTh
Removaland
Separation
REE Holistic
industry Approach PigIronProduction
Safe
disposal
SlagValorization
ThecaseofLateritesandthe
FerroNickelIndustry
CaseStudywithFeNislag
30
ProposedSolution
Bothbyproductsarechemicallysimilar
OriginatingfromlateriticweatheringdepositsinGreece
Containinghighamountofironoxides(4050%wt)
Containingatleast30%wtaluminosilicates
EAF
Carbothermic ProduceMineralWool ProducePigIron =ZeroWasteProcess
Smelting
31
BauxiteResidueGeopolymeric Tiles/Bricks
Bendingstrength:600N(goodfortiles)
WaterAbsorption1.28%
Negligiblewaterpermeability
LowresistancetoFreezingThawingCycles
Suitablebuildingmaterialformoderate
climates(e.g.Mediterranean)
CombinedGeopolymers forBricksandTiles
ExcellentMechanicalproperties
Comp.Strength:>40MPa
BendingStrength:4MPa
Density:2350kg/m3
Waterabsorption:0.57%
Suitablebuildingmaterial
Waterpermeability:Negligible
foralmostanyclimate
HighresistancetoFreezing
ThawingCycles
33
ResearchProjects
20102014AoG /NTUACoordinatedtheFP7
ENEXALProject,demonstratingthecomplete
conversionofBauxiteResiduestopigironand
mineralwoolproducts.
20132017NTUACoordinatestheFP7
EURAREProject,researchingtechnologies
forREEextractionfromBR.
From2015AoG andNTUAwillundertake4PhDstudies
undertherecentlyapprovedMarrie Currieprojecton
EuropeanTrainingNetworkforZeroWasteValorisation
ofBauxiteResidue(RedMud)
TheENEXALBauxiteResidueTreatment
PreliminaryEconomicEvaluation
PigIronrevenues(fixedmarketprice400EUR/t)amountto
38%ofoperationalcosts
Mineralwoolrevenuesdependonmarketprice(dependson
productqualityandmarketdemand)