1.

In the above process product A is 4

a) Fluorobenzene
b) Benzene
c) 1,4Difluorobenzene
d) 1,3Difluorobenzene
Ans: 1
Exp: Fluorobenzene

2. Chlorobenzene on reacting with sodium metal in dry ether produce 4

a) Benzene
b) Sodium phenoxide
c) Methylbenzene
d) Diphenyl
Ans: 4

Exp:

3. Major acetylation product of chlorobenzene is : 4

a) 2-Chloroacetophenone
b) 3-Chloroacetophenone
c) 4-Chloroacetophenone
d) m-Chloroacetophenone
Ans: 3
Exp:

4. Peroxide effect is not observed in 4

a) 2- Methylprop -1 ene
b) 2- Methylbut-2-ene
c) 2,3-Diethylpent-1-ene
d) 2,3-Dimethylbut-2-ene
Ans: 4
2,3 - Dimethyl but - 2 - ene

Exp:

As this is a symmetrical alkene, peroxide effect is not observed.

5. The correct increasing order of the reactivity of halides for SN1 reaction is 4
a)
b)

c)

d)

Ans: 1

Exp:
As per carbocation stability

Identify product Z in the following sequence of reactions.

6. 4

a) Butane
b) Ethanol
c) Methyl iodide + ethanol
d) Ethyl methyl ether
Ans: 4

Exp:
Hence

Analyse the following reaction and identify the nature of A and B.

7. 4

a)Both A and B are

b)Both A and B are

c)A is and B is

d)A is and B is

Ans: 3

Exp: A is and B is

8. Indicate which of the following is correct 4

a) Increasing the concentration of nucleophile favours SN1reaction over SN2 reaction.
b) Ethyl iodide is more reactive than ethyl chloride in SN2 reaction.
c) In SN2 reaction, a greater yield of the product with retained configuration is obtained.
d) SN2 reaction is two step reaction.
Ans: 2
Exp: Ethyl iodide is more reactive than ethyl chloride in SN2 reaction.

9. Trichloracetaldehyde, CCl3CHO reacts with chlorobenzene in presence of sulphuric acid and produces 4

a)
b)

c)

d)

Ans: 4
Trichloracetaldehyde when reacts with chlorobenzene in presence of sulphuric acid,p,p'-dichlorodiphenyl-trich
loromethane (DDT) is produced.

Exp:

10.Among the following the most reactive towards alcoholic KOH is 4

a)
b)
c)
d)
Ans: 2
Exp: Elimination of become easier due to the presence of carbonyl group.
 Order of hydrolysis of the following in increasing order is

11. 4

a)
b)
c)
d)
Ans: 4

II: CH3Br (10 alkyl halide)

Exp:

IV: (CH3)2CHBr (20 alkyl halide)

B (C - Br)

Thus, hydrolysis order is .

12. Which of the following is least reactive in a nucleophilic substitution reaction? 4

a) (CH3)3C-Cl
b) CH2 = CHCl
c) CH3CH2Cl
d) CH2 = CHCH2Cl
Ans: 2

Exp:
Due to resonance, C-Cl bond has some double bond character and hence vinyl halides are much less reactive th
an alkyl halides towards nucleophilic substitution reactions.

13. Which one of the following when heated with metallic sodium will not give the corresponding alkane? 4

a)

b)
c)

d)

Ans: 3

Exp: in wurtz reactn, 30 R-X won't be taken due to high reactivity

14.Allylic bromination is carried out with 4

a) HBr/H2O2
b) HOBr
c) Br2/CS2
d) NBS
Ans: 4
NBS is a specific regent for allylic
Exp:
bromination

15.2 Chloro 2 methyl butane, on reaction with alc. KOH gives X as the major product, X is 4
a) 2 Methyl 1 butanol
b) 2 Methyl 1 butene
c) 2 Methyl 2 butene
d) 2 Methyl 2 butanol
Ans: 3
Exp: 2 Methyl 2 butene

16.In wurtz reaction 2, 3 - Dimethylbutane is obtained from 4

a) 2-chloropropane
b) n-butyl chloride
c) 1-chloropropane
d) tert-butyl chloride
Ans: 1
Exp: 2-chloropropane

17.Aryl fluoride may be prepared from diazonium chloride using 4

a) HBF4 /NaNO2, Cu,
b) HBF4/
c) CuF/ HF
 d) Cu/ HF
Ans: 2
Exp: HBF4/

18. When neo-pentyl bromide is subjected to Wurtz reaction, the product formed is 4
a) 2,2,4,4-Tetramethylhexane
b) 2,2,4,4-Tetramethylpentane
c) 2,2,5,5-Tetramethylhexane
d) 2,2,3,3-Tetramethylpentane
Ans: 3
In Wurtz reaction, an alkane with double the number of carbon atoms, as parent alkyl halide has, is obtained.

Exp:

The following reaction is known as

19. 4

a) Kharasch effect
b) Darzen's procedure
c) Williamson's synthesis
d) Hunsdiecker synthesis reaction
Ans: 2
Exp: Darzen's method uses phenol & thionyl chloride in presence of pyridine to prepare chlorobenzene.

20. Ethyl cyanide may be prepared by heating 4

a) Propyl alcohol with AgCN
b) Ethyl alcohol with AgCN
c) Ethyl chloride with AgCN
d) Ethyl chloride with KCN
Ans: 4
Ethyl chloride with KCN
Exp:
C2H5 Cl + KCN C2H5 CN + KCl
 In the chemical reactions,

21. 4

the compounds A' and B' respectively are :

a) Benzenediazonium chloride and fluorobenzene
b) Nitrobenzene and chlorobenzene
c) Nitrobenzene and fluorobenzene
d) Phenol and benzene
Ans: 1

Exp:

Identify Z in the reaction

22. 4

a) CH3CH2CN
b) CN CH2 CH2 CN
c) BrCH2CH2CN
d) BrCH = CHCN
Ans: 2

Exp:

In the following sequence of reactions

23. 4

The product (C) is

a) Propan-2-ol
b) Propan -1-ol
c) Propyne
d) propene
Ans: 2

Exp:

24. Which of the following compound undergoes replacement of Cl by OH by merely warming with aqNaOH 4

a)

b)

c)

d)
Ans: 4

In alkaline hydrolysis of a tertiary alkyl halide by aqueous alkali if concentration of alkali is double, then the r
25. 4
eaction
a) Will be doubled
b) Will be halved
c) Will remain constant
d) Can't say
Ans: 3
Exp: Conceptual.

26. 4
a) C6H6 + KCl
b) C6H5CH2CN + KCl
c) C6H5CH3 + KCl
d) None of these
Ans: 2
Exp:

Given reaction,

27. 4

Y' in the reaction is

a) Hexane
b) Cyclohexane
c) Cyclohexylcyclohexane
d) Cyclohexylether
Ans: 2

Exp:

28. 4

a) Chlorination
b) Sandmeyer's reaction
c) Perkin reaction
d) Substitution reaction
Ans: 2
Exp: Factual.

29. 2,6-Dimethylheptane on monochlorination produces derivatives 4

a) 5
b) 6
c) 3
d) 4
Ans: 4

Because

there is four methyl groups on the corner so it can produce 4 derivatives.

Exp: from CH3 - 1st derivative
from CH - 2nd derivative
from CH2 - (3rd carbon) - 3rd derivative
from CH2 - (4th carbon) - 4th derivative
This structure is symmetrical from left hand side and right hand side the dvt. obtained will so be the same. (sho
wn with the circle).

30. Which of the following statements is incorrect 4

a) C2H5Br reacts with alco. KOH to form C2H5OH
b) C2H5Br when treated with metallic sodium gives ethane
c) C2H5Br when treated with sodium ethoxide forms diethyl ether
d) Both 1 and 2
Ans: 4

Exp:

Out of

31. 4

which undergo SN reactions easily ?

a) All except III
b) All except II, IV
c) All except I, III
d) All except IV
Ans: 2
Exp:

Yes as NO2 is EWG making (C Cl) bond weak

Thus, I and III undergo SN reaction.

32. Which of the following is Swarts reaction ? 4

a)

b)

c)

d)

Ans: 4
Exp: Swarts reaction exchange of halogen (Cl, Br, I) with F using Hg2F2 is called as swarts reaction.

When chlorobenzene is treated with NH3 in the presence of Cu2O at 202C and 60 mm atm. pressure, then pr
33. 4
oduct formed would be
a) Benzene diazonium salt
b) Benzyl amine
c) Aniline
d) Diphenyl
Ans: 3

Exp:

Identify the product in the following reaction

34. 4

a)

b)

c)

d)

Ans: 3
Exp: It's a wurtz' - fittig reaction.

Following reaction is called

35. 4

a) Fittig
b) Ullmann
c) Wurtz
d) Wurtz fitting
Ans: 2
Exp: Cu is used in Ullman reaction to prepare biphenyl

Chlorobenzene on heating with aq NaOH at 623K under pressure and the product formed on acidification giv
36. 4
en phenol. This process is called
a) Dow's process
b) Raschig process
 c) Sandmeyer's reaction
d) Gattermann reaction
Ans: 1
Exp: Conceptual

Predict the order of reactivity of the following compounds in SN1 reactions

37. 4

a) (i) (ii) (iii) (iv)

b) (iv) (ii) (iii) (i)
c) (ii) (iii) (i) (iv)
d) (iii) (iv) (ii) (i)
Ans: 2
Order of reactivity of SN1 reaction is depends on X atom & type of R-X
Exp:
i.e.

38. 4

How many structures of A' is possible

a) 2
b) 3
c) 4
d) 5
Ans: 2
Exp: But -1 ene (minor), cis But 2 ene (minor) Trans - But - 2 - ene acc.to Saytzeff's rule. Trans is major

Following compound is reacted with PI3 gives

39. 4

a)
b)

c)

d)

Ans: 2
Exp: OH replaces with I

40. Major monochlorination product of 2-Methyl propane is 4

a) sec-propyl chloride
b) sec-butyl chloride
c) tertiary butyl chloride
d) isobutyl chloride
Ans: 3
Because this is free radical substitution & 30 free radical more stable than

Exp:
10

41. Treatment of ammonia with excess of ethyl chloride will yield. 4

a) Diethyl amine
b) Ethane
c) Tetraethyl ammonium chloride
d) Methyl amine
Ans: 3
Exp: Excess of RX gives till Quaternary ammonium salt.

Arrange the following compounds in the order of increasing boiling point.

42. 4
(i) 1-Bromobutane (ii) 2-Bromobutane (iii) tert-Butyl bromide
a) i > ii > iii
b) iii > ii > i
c) ii > I > iii
 d) None of the above
Ans: 1
Exp: Order of boiling point is 10 > 20 > 30

The major product of given reaction is

43. 4

a)

b)

c)

d)

Ans: 1
Exp: -halogenation (bromination) alkene takes place in the presence of NBS

The major product of

44. 4

is

a)

b)

c)

d)

Ans: 1
Exp: is most stable free radical that can be formed

The IUPAC name of the compound shown below is

45. 4

a) 2-bromo-6-chlorocyclohexene -1-ene
b) 6-bromo-2-chlorocyclohexene
c) 3-bromo-1-chlorocyclohexene
d) 1-bromo-3-chlorocyclohexene
Ans: 3
Exp: 3-bromo-1-chlorocyclohexene