PART TEST-3 (PT-3)

PATTERN : AIPMT
TARGET : AIPMT/AIIMS-2016
DATE : 27-12-2015 COURSE : SAFAL (MRQH1)

HINTS & SOLUTIONS

PART -A 17. (i) Cu + 2e Cu , E1 = 0.337 V, G1

2+
=
CHEMISTRY n1 FE1 & n1 = 2
(ii) Cu + e Cu+ , E2 = 0.153 V, G2
2+
=
13. Ecell = 0.76 volt n2 FE2 & n2 = 1
Applying nernst equation
target reaction (iii) Cu + e Cu ,
+
E3 =
? G3 = ?
0.0591 [Zn2 ][PH2 ] so target equation = (i) (ii)
Ecell = Ecell log so G3 = G1 G2
2 [H ]2 1
0.0591 (0.1)(1) so E3 = { 2 0.337 + 0.153} V = 0.521 V
0.169 = 0.76 log 1
2 [H ]2 (i) Cu + 2e
2+
Cu , E1 = 0.337 V, G1 =
2 0.591
0.1 n1 FE1 & n1 = 2
log =
2
(ii) Cu + e Cu+ , E2 = 0.153 V, G2
0.0591 2+
[H ] =
or
+ 2
log 0.1 log [H ] = 20 n2 FE2 & n2 = 1
(iii) Cu + e Cu ,
+
or 2pH = 20 log 0.1
21 E3 = ? G3 = ?
pH = = 10.5 = (i) (ii)
2
G3 = G1 G2
0 0.0591 [ H ]anode 0.0591
14. Ecell = Ecell log10 = 1
1
[ H ]cathode 1 E3 = { 2 0.337 + 0.153} V = 0.521 V
1
10 2
log10 = ve (non spontaneous). ( ) 1 1 106 1 106 1 =
K1C1 K 2C2 =
+
10 3 18. H =

E0Zn2 / Zn 2 106
0
15. Ecell = EPb 2
/Pb

= 0.126 (0.763) = +0.637 V 6 1/2 1 6

P = log (2 10 )
H
= log (2 10 )
0.0591 [Zn2 ] 2
Ecell = E0cell log
n [Pb2 ] =3
log2
= 3 0.1505 = 2.849
0.0591 2
= 0.637 log 0.1
2 K a1
= 0.637 + 0.02955 = 0.667 V
19. Relative strengths of weak acids =
Ka
16. We know that, 2
standard Gibbs energy, G = nEFcell Assume C1 and C2 are same (Although not
For the cell reaction, given).
2Ag + Cu Cu2+ + 2Ag
+
K a1 1.8 10 4
G = 2 96500 0.46 Relative strength = =
5
Ka
= 88780 J = 88.7 kJ = 89.0 kJ 2 1.8 10
, G = nEF Relative strength for HCOOH to CH3COOH =
, 10 : 1
2Ag + Cu Cu2+ + 2Ag
+
K a1
G = 2 96500 0.46 =
= 88780 J Ka
2
= 88.7 kJ 89.0 kJ
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 C1 C2 ( ) 26. (1) Ca salt imparts brick red colour to the flame.
(2) Sr salt imparts bright crimson colour to the
K a1 1.8 10 4 flame.
= =
Ka 5
2 1.8 10 (3) Ba salt imparts apple green colour to the
flame.
HCOOH CH3COOH =
(4) Mg salt does not impart any colour to the
10 : 1 flame because of high ionization energy.
(1) Ca
20. Sodium acetate and acetic acid solution and
ammonia and ammonium chloride solution are the (2) Sr
examples of acidic buffer. (3) Ba
(4) Mg

27. Plaster of Paris is hemihydrate of calcium

21. KCl can make precipitate with AgNO3, Pb(NO3)2 sulphate.
so can't be used along these electrolyte.
AgNO3, Pb(NO3)2 KCl
KMnO / H
28. CH3 CH2 C CH
4
CH3CH2COOH + CO2 + H2O
29. Baeyers reagent is dilute alkaline KMnO4
Zn2C1 + 2e

22. Zn
solution.
Zn2C2 + 2e

Zn KMnO4

Zn2C2 Zn2C1
30. > CH3 Cl > CH3 CH2
0.0591 C
E=0 log 1
2 C2
Cl >
E +ve When C1 < C2
23. Thermal stability of alkali metal oxy-acid salts
increases with increasing metallic character so 31. According to carboction stability (
Li2CO3 has lowest stability. )
-
32. SN2 mechanism is a single step concerted
Li2CO3
process and proceed through transition state.
SN2

24. Mg + 3N2 Mg3N2 ; Mg3N2 + 6H2O

3Mg(OH)2 + 2NH3 .

33.
25. M + (x + y) NH3 [M(NH3)x] + [e(NH3)y] ;
+

solution contains unpaired solvated electrons

which are responsible for their strongly reducing
+
and highly conducting nature.

M + (x + y) NH3 [M(NH3)x] + [e(NH3)y] ;

+
36. SN1 reactions occur through the intermediate
formation of carbocations.
SN1

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 but torque is not zero. Hence angular
PCl5 momentum of the system is not constant.
38.
(4) Potential energy may also change.
Sol. (1)

Product is R - 2- Chlorobutane
(2)
R-2-
(3)
SOCl
39. 2

pyridine,

It is SN2 reaction. SN2

(4)
40. According to stability of carbocation and leaving
ability of leaving group. d
67. = 1.5 + 4t
dt
= 9.5 rad/s

41. -Hydrogen is absent. (- ) 68. P1 p i

42. Rate of E2 stability of product (E2 P2 p i
) as there is no external force so momentum will
remain conserved
43. It is E2 reaction (anti elimination).
E2
P1 P' 2 P1 P2
CH3 CH CH2 CH3
Alc. KOH

P1 P2 0
|
Cl Now from option
CH3CH=CHCH3
(1) P1 P2 = (a1 a2 ) i (b1 b2 ) j c1k
45.
(2) P1 P2 = (c1 c 2 ) k

(3) P1 P2 = (a1 a2 ) i (b1 b2 ) j

(4) P1 P2 = (a1 a2 ) i 2 b1 j
and it is given that a1 b1 c1 , a2, b2, c2, 0
in case of A and D it is not possible to get

P1 P2 = 0
Hence Ans. (1)
a1 b1 c1 , a2, b2, c2, 0

A D P1 P2 = 0
PART - B Ans. (1)
PHYSICS

57. mg x As mg 69.
mg
produces extension x, hence k =
x
M m M m x m1y1 m2y2 m3 y3 m4 y 4 m5 y5
T = 2 2p
k mg ycm =
m1 m2 m3 m4 m5
ycm
66. (1) Since there in no resultant external force, 6m(0) m(a) m(0) m(a) m(a) a
linear momentum of the system remains = = .
m m m m 6m 10
constant.
(2) Kinetic energy of the system may change.
(3) Angular momentum of the system may
change as in case of couple, net force is zero

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70. Since masses of particles are equal, collisons Hindi.
are elastic, so particles will exchange
velocities after each collision. The first collision
will be at a point P and second at point Q
again and before third collision the particles
will reach at A.

P
Q
A

g 1 5g 2
=
1
2 = 5

v sin
2h 73. e= 2gh cos
71. R= u g apply conservation of momentum
25 25
20 = V1 and 100 = V2 m
10 10 2gh = m vcos ......(i)
V1 = 20 m/s , V2 = 100 m/sec. e 2gh cos m = mv cos ......(ii)
Applying momentum conservation just before
and just after the collision
(0.01) (V) = (0.2)(20) + (0.01)(100)
V = 500 m/s
2h
Sol. R= u g

25 25 tan
20 = V1 and 100 = V2 e
= cot.
10 10
V1 = 20 m/s , V2 = 100 m/sec. e = tan2on solving

74. Centre of mass is a point which can lie within

(0.01) (V) = (0.2)(20) + (0.01)(100)
V = 500 m/s or outside the body.

72.

75. Centre of mass is nearer to heavier mass

76.

To complete the vertical circle

g 1 5g 2 let distance moved by m = x,
=
1 and Let distnce moved by 5m = x2
M x1 = 5m. x2
2 = 5
x1 = 5x2 .........(1)

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 12 R (x1 x2) = 3 R :
x1 + x2 = 9 R V 0

6x2 = 9R
9 3
6
x = R = 2 R and 81. T sin = m Lsin2
2

3 15
x = 2 R5 = 2 R = 7.5 R

79. From energy conservation

v = u 2gL
2 2
...(1)
Now, since the two velocity vectors shown in
figure are mutually perpendicular, hence the
magnitude of change of velocity will be given
by
324 = 0.5 0.5 2
324
2 =
| v | u2 v 2 0.5 0.5
324
=
0.5 0.5
18
= = 36 rad/sec.
0.5

83. Fx
Substituting value of v 2
from v 2

= Px (Pfx Pix ) mV sin60 (mV sin60 ) 250 3 N

t t 3
2 10
Equation (1) (1)
= N towards left
| v | u2 u2 2gL
300 (0) 500(40) 400 70
| v | 2(u2 gL) 87. Xcm =
300 500 400
80. (1) Since the block rises to the same heights 500 40 400 70
in all the four cases, from conservation of Xcm =
1200
energy, speed of the block at highest point will
50 70 120
be same in all four cases. Say it is V . 0 Xcm = = 40 cm
3 3
1
88. V = .r V = 30 2 = 30
V 0
2
Equation of motion will be 89. Force is perpendicular to
mV02 v2 mv 2
N + mg = R= R= Ans.
R a F
mV02
or N= mg 90. Normal reaction at highest point.
R
V0
mv 2
mg N =
r
N+mg
R (the radius of curvature) in first case is mv 2
N = mg
minimum. Therefore, normal reaction N will be r
maximum in first case. R A > RB N A > NB
R ( Ans.
N

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 PART TEST-3 (PT-3)
PATTERN : AIPMT
TARGET : AIPMT/AIIMS-2016
DATE : 27-12-2015 COURSE : SAFAL (MRQH1)
ANSWER KEY
CODE-4
PART A
CHEMISTRY
1. (4) 2. (3) 3. (2) 4. (2) 5. (4) 6. (1) 7. (3)
8. (2) 9. (1) 10. (4) 11. (4) 12. (1) 13. (4) 14. (2)
15. (3) 16. (1) 17. (3) 18. (2) 19. (4) 20. (1) 21. (3)
22. (3) 23. (1) 24. (1) 25. (4) 26. (2) 27. (3) 28. (3)
29. (1) 30. (3) 31. (4) 32. (2) 33. (2) 34. (3) 35. (1)
36. (1) 37. (2) 38. (2) 39. (1) 40. (4) 41. (3) 42. (1)
43. (1) 44. (2) 45. (1)

PART - B
PHYSICS
46. (3) 47. (2) 48. (3) 49. (2) 50. (3) 51. (1) 52. (1)
53. (2) 54. (3) 55. (1) 56. (2) 57. (2) 58. (4) 59. (3)
60. (1) 61. (1) 62. (4) 63. (1) 64. (1) 65. (4) 66. (1)
67. (3) 68. (1) 69. (1) 70. (3) 71. (4) 72. (4) 73. (1)
74. (4) 75. (2) 76. (4) 77. (3) 78. (1) 79. (4) 80. (1)
81. (4) 82. (1) 83. (3) 84. (3) 85. (3) 86. (1) 87. (1)
88. (1) 89. (1) 90. (2)

PART - C
BIOLOGY
91. (3) 92. (2) 93. (4) 94. (3) 95. (1) 96. (4) 97. (1)
98. (3) 99. (4) 100. (3) 101. (3) 102. (4) 103. (3) 104. (3)
105. (2) 106. (2) 107. (2) 108. (2) 109. (2) 110. (4) 111. (4)
112. (3) 113. (3) 114. (2) 115. (3) 116. (4) 117. (3) 118. (1)
119. (4) 120. (1) 121. (1) 122. (4) 123. (3) 124. (2) 125. (4)
126. (2) 127. (2) 128. (1) 129. (3) 130. (2) 131. (3) 132. (2)
133. (3) 134. (4) 135. (2) 136. (2) 137. (3) 138. (1) 139. (2)
140. (4) 141. (3) 142. (3) 143. (4) 144. (4) 145. (3) 146. (2)
147. (3) 148. (4) 149. (3) 150. (2) 151. (2) 152. (4) 153. (3)
154. (1) 155. (4) 156. (2) 157. (1) 158. (3) 159. (4) 160. (3)
161. (4) 162. (2) 163. (2) 164. (3) 165. (3) 166. (1) 167. (4)
168. (3) 169. (3) 170. (4) 171. (1) 172. (3) 173. (4) 174. (1)
175. (2) 176. (2) 177. (1) 178. (3 179. (2) 180. (4)

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