FULL SYLLABUS TEST (FST)

PATTERN : AIPMT
TARGET : AIPMT/AIIMS-2016

DATE : 17-01-2016 COURSE : SANKALP(MP) / SAMBHAV(MF)

HINTS & SOLUTIONS

PART - A 1.68 500

Moles of solute = = 0.84 moles
CHEMISTRY 1000
= + Tb = 100 +
3. (1) CF4 is tetrahedral where is T-shaped.
Tb
= Tf = 0 Tf
(2) , O = C = O both linear = 100 + Tb (Tf)
104 = 100 + Tb + Tf = 100 + Kb +
according to VSEPR.
(3) BF3 is trigonal planar and PCl3 is tetrahedral. Kf
(4) PF5 is trigonal bipyramidal and IF5 is square = 100 + (0.52 + 1.86)
pyramidal.
104 100 4
(1) CF4 T- = = = 1.68 m
2.38 2.38
moles 1000
=
(2) , O = C = O VSEPR Wgm (solvent)
moles 1000
; 1.68 =
500
(3) BF3 PCl3
1.68 500
(4) PF5 IF5 = = 0.84 moles
1000

P Ps loss in wt. of solvent 9. Formula will be X 1 Y4 = X3Y4.

12
7. = 4
Ps loss in wt. of solution +
11. In A, NO has no unpaired e s. So, complex is
P Ps 0.05 5 18
= = diamagnetic but in B, NO is odd e molecule,
Ps 2.50 M 90
1 having one odd e . So, B is paramagnetic.
M = 50 gmole . +
A NO
8. Boiling point of solution = boiling point + Tb =
100 + Tb B, NO
Freezing point of solution = freezing point Tf B
= 0 Tf
Difference in temperature (given) = 100 + Tb
(Tf) 0.0591 [H ]2
104 = 100 + Tb + Tf = 100 + molality Kb + 12. Ecell = Ecell log
molality Kf 2 [Ni2 ][H2 ]
= 100 + molality (0.52 + 1.86) 0.0591
Ecell Ecell =
+
104 100 4 log [H ] = 0.0591 pH
Molality = = = 1.68 m T
2.38 2.38
pH = 1
moles 1000
H2 2H + 2e
+
and molality = ;
Wgm (solvent)
Ni + 2e Ni(s)
2+

moles 1000 H2 + Ni 2H + Ni(s).

2+ +
1.68 =
500
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13. Cu can not reduce ferrous sulphate (Electro 24. Only those ions will be coloured which have
chemical series) incompletely filled d-orbitals. Those with fully-
Cu filled or empty d-orbitals are mostly colourless.
3+ 1 3+ 2 3+ 3 2+ 9
Thus, Ti (3d ), V (3d ), Cr (3d ), Cu (3d ),
3+ 5 2+ 7
Fe (3d ) and Co (3d ) are all coloured due to
3+ 0
14. (4) Concentration is the method employed to d-d transition.Only Sc (3d ) is colourless.
remove gangue materials by mechanical d-
separation in calcination, volatile impurities are
d-
removed.
3+ 1 3+ 2 3+ 3 2+ 9
, Ti (3d ), V (3d ), Cr (3d ), Cu (3d ),
3+ 5 2+ 7
Fe (3d ) Co (3d )
3+ 0
1
d-d Sc (3d )
15. G = 439 (941) = + 502 KJ/mol so
reaction will non-spontaneous
kt st st
26. Ct = Coe (For I order) (I )

16. NO2 , Br & Cl can oxidise I into I2 which give NH4NO2 (aq) N2(g) + 2H2O () (Ist
2
blue black colour in starch but CO3 does not. st

NO2 , Br

Cl , I

I2 order) (I )
2
CO3

17. Pb(CH3COO)2 + H2S PbS (Black) +

2CH3COOH
Pb(CH3COO)2 + H2O + SO2 PbSO3
(white) + 2 CH3COOH
1
27. Unit of k for Ist order reaction is s
18. Catalyst are selective in nature. ( 1
k s
)
H
29. Not show stereisomerm.
21. Cl2O7 + H2O 2HClO4 ; Cl2O3 + H2O CH 3
2HClO2 Because chiral center is absent and the
conductions al geometrical isomerism are also
2ClO2 + H2O HClO2 + HClO3
absent.
Cl2O5 + 2H2O 2HClO3
O2 /
32. CH3CH=CHMgBr CH3CH=CH
22. K AgF4 + BF3 AgF3 + KBF4 ;
2AgF3 + Xe 2AgF2 + XeF2 H / H O
OMgBr
2
(CH3CH=CHOH)
(red solid) (brown solid)

23. Fe2(C2O4)3 + K2Cr2O7 Fe + CO2 + Cr

+3 +3
CH3CH2CH=O
n=6 n=6
O
FeCl3 + Na2C2O4 Fe2(C2O4)3 ||
n=3 n=6 33. A = CH3 C CH3 ,B =
1 OH
meq. of Fe2(C2O4)3 reacted = 10 x =1
10 |
1 CH3 CH CH3
Fe2(C2O4)3 = 10 x =1 Step 1 is Markownikov addition of water and
10
meq. of FeCl3 required = 1 Step 2 is reduction of ketone formed in step-I to
FeCl3 =1 2-propanol.
1 1
millimole of FeCl3 required =
3 I 2
1 2-
FeCl3 =
3
37. -amino acids exist as Zwitter ion.
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39. It is E2 reaction (anti elimination). 9 109 92 0.144
47. 0.144 = 92 =
(0.05) 2
9 109 400

q 2 1.6 1019
49. i 1.6 1019 A
T 2
i 1.6 1019
B o o o 1019
2r 2 0.8
42. Esters of fatty acid gives glycerol and acid salt 50. If path difference = (SS1 + S1O) (SS2 + S2O)
on hydrolysis in basic medium. = n n = 0, 1, 2, 3, .... the central fringe at O is a
bright fringe and if the path difference
1
n , n = 1, 2, 3, ..... the central bright
2
43. fringe will be a dark fringe.
= (SS1 + S1O) (SS2 + S2O) = n
n = 0, 1, 2, 3, .... O
1
n , n = 1, 2, 3,
44. Because (1), (3), (4) have hemiacetal structure. 2
(1), (3), (4) .....

H O 51. Negative charge experiences force opposite to

45. CH3CN
3
CH3COOH
direction of electric field.
KMnO ,H ,
PhCH2CH3
4
PhCOOH
KMnO ,
CH3CH2CHO

4
CH3CH2COOH
H /

HO 52. (4) The magnetic induction at O due to the

HCOOCH3 3
HCOOH current in portion AB will be zero because O
Formic acid is strongest acid among all the lies on AB when extended.
above products. AB O
AB O, AB

PART -B 53. U = decrease in potential energy

PHYSICS
46. (1) The current in the circuit are assumed as
= Ui U f
shown in the fig.
2
1 1 V V2
=C(V12 + V22) (2C) 1
2 2 2
6 i1 B 3 i1 i2 C 1
A = C(V1 V2)2
4
15 V 3 30 V C3
55. q3 = .Q
i2 C2 C3
3 3
i1 D q3 = 80 = 80 = 48 C
Applying KVL along the loop ABDA, we get 32 5
ABDA 0 2i 2 i
6i1 3 i2 + 15 = 0 or 2i1 + i2 = 5 ..(i) 56. B . 12.56 107
Applying KVL along the loop BCDB, we get
4 r 5.2 1011
BCDB i 1.04 103 A
3(i1 i2) 30 + 3i2 = 0 or i1 + 2i2 = 10 ..(ii)
Solving equation (i) and (ii) for i2, we get i2 = 5 A.
(i) (ii) i2 = 5 A

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 57.

y
A B

C D

63. In the presence of medium force becomes

1
times .
K
1
K
0i
64. B =
2R
s
0 A 20 20 s
C1 = ;C= 2 =
d d d
2

s s
4 0 20
C' = 2 = 40 s ; C" = 2 = 0 s
d d d d 0 qf q
B0 = = 0
2 2R 2R. 2
q
C C' 4 0 s s 7 0 s B0 = 207
C2 = + C'' = + 0 = R
C C' 3 d d 3 d
66.
59. In the presence of an applied electric field ( E ) in
a metallic conductor. The electrons also move
randomly but slowly drift in a direction opposite
to E .

60. Due to wood moment of inertia of the system

becomes twice but there is no change in
magnetic moment of the system.
Hence by
I
using T 2 T I T' 2 T Perpencicular distance from side of "O" is a cos
MBH 30
O a cos 30
3a
r=
I 2
T 2 T I T' 2 T
MBH Bnet = 6.B,
i 6 0i 2 2 1
= 6 0 (sin 30 + sin 30) =
R 4 r 4. 3a 2
61. R = , R' =
a 4a 4
30i
=
62. Magnetic lines are tangential to the coil as a
shown in figure. Thus net magnetic flux passing
through the coil is always zero or the induced
current will be zero.
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 T 1 2QV e
67. The current takes sec to reach the peak 78. mv 2 QV v 2 V
4
value. 2 m m
2 1 v 2 1.6 1011 200 8 106 m / s .
In the given question 200 T sec
T 100
1 1 h h
Time to reach the peak value sec 80. mv 2 E mv 2mE;
400 2 mv 2mE
69. Potential at the centre O, O 1 q2
81. q CV and U CV 2
1 Q 2 2C
V 4 .
40 a / 2 T
(e1 sin t e2 cos t)2 dt
Where Q
10
109 C
82. Vrms2 = T
3 0
and a 8cm 8 102 m e12 e22
+q +q =
A B 2
2
where =
.
a T
O
2 E h pc
83. p
c c h
1 1
84. U CV 2 50 106 (10)2 2.5 103 J
D +q C 2 2
+q
Vrms 100
10
109 85. rms = =
Z 2
So V 5 9 10
9 3 1500 2 volt 1
R2 L
8 102 C
P.d. across resistance = R
2
70. Because power i2R, if R = 0, then P = 0. rms .
71. E 1 106 1.6 1019
86. E h
h 6.6 1034
2.4 10 Hz
20

E
88. % = 2 2 100
E11
89. Let the energy in A, B and C state be EA. EB and
EC, then from the figure
A, B C
in ABC 90 + 3 = 180 = 30 EA EB EC
72. This is because, when frequency is increased,
1 C
the capacitive reactance XC decreases 1
2C B
and hence the current through the bulb
increases. 2 3
1
XC A
2C hc hc hc
(EC EB ) (EB EA ) (EC EA ) or
1 2 3
E 3 104 12
75. eE evB v 1.5 107 m / s 3
B 2 103 1 2
76. Usystem 1 (q)( 2q) 1 ( 2q)(q) 1 (q)(q)

40 a 40 a 40 2a 1
90. Conductivity .....(i)
7q2
Usystem 1
80 a and conductance G
R
GR 1 .....(ii)
From equation (i) and (ii) (i) (ii)
77. For TIR medium at refraction must be rarer.
GR

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 FULL SYLLABUS TEST (FST)
PATTERN : AIPMT
TARGET : AIPMT/AIIMS-2016

DATE : 17-01-2016 COURSE : SANKALP(MP) / SAMBHAV(MF)

ANSWER KEY
CODE-4
PART -A
CHEMISTRY
1. (2) 2. (3) 3. (2) 4. (3) 5. (2) 6. (2) 7. (3)
8. (4) 9. (2) 10. (4) 11. (3) 12. (4) 13. (4) 14. (4)
15. (3) 16. (4) 17. (3) 18. (2) 19. (2) 20. (3) 21. (3)
22. (1) 23. (3) 24. (2) 25. (4) 26. (4) 27. (4) 28. (3)
29. (4) 30. (4) 31. (4) 32. (3) 33. (2) 34. (3) 35. (2)
36. (2) 37. (1) 38. (2) 39. (2) 40. (4) 41. (2) 42. (2)
43. (3) 44. (2) 45. (4)

PART - B
PHYSICS
46. (1) 47. (1) 48. (1) 49. (2) 50. (3) 51. (4) 52. (4)
53. (3) 54. (2) 55. (3) 56. (4) 57. (4) 58. (2) 59. (4)
60. (4) 61. (2) 62. (4) 63. (4) 64. (4) 65. (2) 66. (4)
67. (4) 68. (3) 69. (2) 70. (2) 71. (2) 72. (2) 73. (3)
74. (4) 75. (3) 76. (3) 77. (4) 78. (1) 79. (2) 80. (1)
81. (1) 82. (4) 83. (2) 84. (1) 85. (2) 86. (2) 87. (3)
88. (3) 89. (2) 90. (1)
PART - C
BIOLOGY
91. (2) 92. (4) 93. (1) 94. (4) 95. (2) 96. (4) 97. (2)
98. (1) 99. (2) 100. (4) 101. (1) 102. (3) 103. (4) 104. (2)
105. (4) 106. (2) 107. (3) 108. (3) 109. (4) 110. (4) 111. (3)
112. (3) 113. (4) 114. (3) 115. (2) 116. (4) 117. (1) 118. (3)
119. (3) 120. (3) 121. (3) 122. (3) 123. (2) 124. (1) 125. (2)
126. (1) 127. (2) 128. (4) 129. (1) 130. (4) 131. (1) 132. (4)
133. (1) 134. (3) 135. (2) 136. (3) 137. (1) 138. (4) 139. (4)
140. (1) 141. (4) 142. (4) 143. (2) 144. (4) 145. (2) 146. (1)
147. (4) 148. (1) 149. (4) 150. (4) 151. (2) 152. (1) 153. (2)
154. (2) 155. (2) 156. (4) 157. (4) 158. (4) 159. (1) 160. (4)
161. (4) 162. (4) 163. (4) 164. (2) 165. (4) 166. (4) 167. (4)
168. (4) 169. (2) 170. (1) 171. (4) 172. (3) 173. (3) 174. (2)
175. (4) 176. (4) 177. (3) 178. (3) 179. (4) 180. (1)

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