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C. Grefaldia1, C. Hernia2
1 College of Home Economics, University of the Philippines, Diliman, Quezon City 1101
2 National Institute of Geological Sciences, College of Science, University of the Philippines, Diliman, Quezon City 1101
3. Write the Ksp of Ca(OH)2 in terms of its (a) molar 5. What are the possible sources of errors and their
solubility s, (b) [OH-] and (c) [Ca2+]. effect on the calculated parameters? Rationalize.
The Ksp of Ca(OH)2 written in terms of its (a) molar solubility Possible sources of error could be errors in standardization
is which can cause a large error on all calculations
subsequently. Improper measurements of reagents can also
Ksp = 4s3 be possible source of error which could lead to a different
calculation of the solubility which in effect causes errors in
In terms of [OH-], the data result and the conclusion based on the data
obtained. Lastly, titration error can also be huge source of
4([OH-]/2)3 error. For example improper measurement of titrant,
spillage of the analyte, over titration and contaminated
in terms of [Ca2+], glassware are among the possible errors during titration
which could lead to inaccuracy in the data making the
4[Ca2+]3 [2] experiment and the data result useless and unreliable.
Theoretically the presence of another common ion in the [2] Brown, Theodore L., H. Eugene LeMay, and Bruce
solution can reduces the solubility of a sparingly soluble Edward. Bursten. C hemistry: The Central Science. Upper
salt when a soluble compound with the same ions as the Saddle River, NJ: Prentice Hall, 2000. Print.
salt is added to the solution, shifting the equilibrium of it
[3] UPD Chem 26.1 Analytical Chemistry Laboratory
back to the reactant side [3]. In general, the solubility of a
Manual, Institute of Chemistry, University of the
Philippines, 2017 edition. Print.