Chapter 10

(a) What is Raoults law Give its three statements

(b) Define Molarity, Molality and mole fraction
Justify the following facts:
(d)Relative lowering of vapour pressure is independent of the temperature.
( e)Colligative properties are obeyed when solute is non-volatile and non electrolyte and also
when the
solution are dilute.
(f) Write down the measurement of boiling point elevation by Lands Bergers method
(g) Define Osmosis and gives its daily life applications
Sample problems10.2,10,7,10.9,10.10,(self check 10.8)
Exercise problems 27,30
Long Question
How will you explain that elevation in boiling point is a colligative property and derive the
expression for molecular mass of non-volatile and non electrolyte solute.
Chapter 11
(a) Define the followings:
(a)Enthalpy of reaction (b) Enthalpy of neutralization (c) Enthalpy of combustion
(b) Derive H=qp and Prove w= PV
(c) Sample problems (Self Check 11.3.11,4,11.5 ),11.6
(d) Exercise problems 16,17,19,23,28.
Long Question
(a) Explain Hesss Law with example
(b) Write note on Born-Haber Cycle
Chapter 12

(a) What is standard hydrogen electrode? Give its construction and working.
(b)Write the spontaneous reaction for the following set of half reactions.
Au3+ + 3e Au E0 =1.5 V NO3- +4H+ +3e
NO + H2O E0 =0.096V
Balance the following reactions by ion-electron method.
(a) IO3-1 + ClO3-1 I2 + ClO4- ( Acidic medium)
(b) MnO4-1 + NO2-1 Mn+2 + NO3-1 (acidic medium)
Calculate the mass of Cu and O2 produced by the electrolysis of CuSO4 solution on passing 5
amperes of current for 2 hours. What would the volume of O2 at STP. Following reactions occur
at the electrodes.
At Cathode Cu2+ + 2e Cu
At Anode 2H2O O2 + 4H+ +4e
How can you relate chemical change and electric current in term of Faradays Law
Define primary cell and secondary cell with examples
Sample problems 12.13,12,15,( Self Check 12.10)
Exercise problems 11,16
Long Question
(1) Explain the process of corrosion and how we prevent a metal from it.
(2) Explain the process of electroplating with the help of example
Chapter 7
(a) In the equilibrium N2 (g)+ O2(g) 2NO(g) H = 91.46 KJ/m
What is the effect on the position of equilibrium if
(a)Temperature is increased (b) Pressure is decreased (c) Any amount of nitrogen is added
(b) Discuss two applications of equilibrium constant (a) Extent of reaction and (b) Direction of
the reaction
(c) Write conditions for equilibrium
(d) Write an expression for the KSP of Mg(OH)2
(e) Sample problems 7.5,7.6,7.9,7.10
(f) Exercise problems 16,17,26
Long Question
(a) What is law of mass action? Derive an equation for Kc expression of a general reversible
reaction
(b) Write Note on Common Ion effect
Chapter 8.
(a) What is relationship between Ka and Kb
(b) Write expressions for the ionic product of water, Kw, and for pH.
(c) What are amphoteric oxide? Give example
(d) What is relationship between Ka and Kb
(e) Write expressions for the ionic product of water, Kw, and for pH.
(f) Sample problems 8.1,8.7,8.9
(g) Exercise problems 7
Long Question
(a) What is hydrolysis. Discuss in detail the behavior of each of the following salt in the aqueous
solution.
K2CO3 (ii) NH4Cl (iii) NaNO3 (iv) CH3COONH4
(b) What are Buffer solution Give the applications of buffer.

Chapter 9
(a) What is the effect of catalyst in the following:
(i) The rate of reaction (ii) The energy of activation (iii) The equilibrium position of a reversible
reaction
(b) Differentiate between instantaneous and average rate of reaction
(c) Differentiate between Homogeneous and Heterogeneous Catalysis
(d) Self check Exercise 9.3,9.4,9.5
(e) Exercise problems 14,16
Long Question
Explain in detail the various factors which can affect the rate of reactions
Chapter 4
(a) Write three applications of Daltons Law of partial pressure
(b) Give the postulates of Kinetic Molecular Theory of Gases
(c) Derivation of critical form of Charless law
(d) Derive the relationship between Kinetic energy and temperature
(e) Derive Grahams law of diffusion on the basis of kinetic theory of gases
(f) Sample problems 4.8,4.15,4.16,4.20
(g) Exercise problems 11,12,17,19 (b)
Long Questions
(a) Derive Vander Waals equation for real gases
(b) Deviation from ideal gas behavior

Chapter 5
(a) Specify the predominant intermolecular force involved for each substance given below
(1) CH3OH (2) CH4 (3) CH3F (4) HCl(g) (6) I2 (7) CH3COCH3
(b) Why is the boiling point of water much higher than the rest of the hydrides in group 6?
(c) Why does the boiling point of the group 4 hydrides increase form CH4 to GeH4?
(d) What are the factors affecting viscosity
(e) What are the factors affecting evaporation
(f) What is surface tension? Give its units.
(g) Give three applications of hydrogen bonding
(h) Define Vapour pressure and what are the factors affecting Vapour Pressure

Chapter 6
(a) What type of crystal will each of the following substances form in its solid state?
(a) CO2 (b)SiO2 (c) C(diamond) (d) NaNO3(e) Al (f) SO2
(b) Explain the allotropes of oxygen and also draw a diagram how ozone protects earth from
ultraviolet
(c) Electrical conductivity of metal decreases with increase in temperature. Why?
(d) Why a compound like CaCl2 fluctuate in mass from day to day because of humidity
(e) How will you get sodium chloride salt from saline solution
(f) Exercise problems 6,9,10,15
Long Question
(a) Write note on covalent solids and ionic solids
Section B ( Chapter 1 to chapter 6)
(b) Chapter 1
(c) (a) Define mole, Avogadro number, limiting reactant, theoretical yield
(d) (b) Actual yield is always less than theoretical yield
(e) (c) Sample problems ( 1.3,1.5,1.7,1.8,1.9and 1.10)
(f) (d) Exercise problems 5(b), 6(b)
(g) Chapter 2
(h) (a) Write down the important points of Planks quantum theory.
(i) (b) What is spectrum?. Differentiate between continuous and line spectrum.
(j) (c) The e/m ratio of positive rays for different gases are different but those for cathode rays
the e/m values is the same
(k) (d) Whichever gas is used in the discharge tube ,the nature of the cathode rays remains the
same
(l) (e) Describe how J.J Thomson discover the charge to mass ratio of an electron
(m) (f) Rules for distribution of electron
(n) (g) Sample problems(2.1,2.6)
(o) (h) Exercise problems 2(xvii ,xiv (b)
(p) Long Questions ( section-D)
(q) (a) Derive the equation for the energy difference between energy levels frequency of the
photon and wave number of photon which is emitted or absorbed when the electron jumps
between energy levels in hydrogen atom
(r) (b) Explain Quantum numbers
(s) Chapter 3
(t) (a) Predict the geometries of molecules on the basis of V.S.E.P.R.theory (a) PH3 (b)
SO3 (c) PbCl2
(u) (b) Calculate the bond energy of H-I. The bond energy of H-H is 436 Kj/mole and that f
I-I is 151Kj/mole
(v) (c) If the bond length and dipole moment of a diatomic molecule are 1.25 A and 1.0 D
respectively, what is the percent ionic character of the bond?
(w) (d) M.O Theory is superior to V.B Theory.Justify with one example
(x) (e) Define bond length. Write different methods to measure bond length
(y) Long Questions ( section-D)
(z) Explain the geometries of following molecules on the basis of hybridization.
(aa) (i) CH4 (ii) BF3 (iii) H2O (iv) C2H4 (v) C2H2