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Safety Data Sheet in accordance with Regulation (EC) No

1907/2006
Appretan N94151 liq Page 1

Substance key: 000000188876 Revision Date: 09.06.2009


Version : 2 - / EU Date of printing : 30.10.2009

1. Identification of the substance/preparation and of the company/undertaking

Trade name
Appretan N94151 liq
Material number: 202892
Use of the substance/preparation.
Industry sector : Textile processing industry
Type of use : Textile finishing
Identification of the company
Clariant Production (France)

Usine de Lamotte
60350 Trosly Breuil
Telephone no. : +33 3 44 85 40 00
Information about the substance/preparation
Product Safety Dpt.
tel.: +33 1 46 96 97 82
e-mail: France.ProductSafety@clariant.com
Emergency telephone number : +33 1 45 42 59 59 (24 h)

2. Hazards identification
Does not require a hazard warning label, but the normal safety precautions for handling
chemicals must be observed.

3. Composition/information on ingredients
Chemical characterization
Aqueous dispersion of a vinyl acetate copolymer.

4. First aid measures


General information
Remove soiled or soaked clothing immediately
After contact with skin
In case of contact with skin wash off immediately with plenty of water
After contact with eyes
In case of contact with eyes rinse thoroughly with plenty of water and seek medical advice
After ingestion
Call in a physician immediately and show him the Safety Data Sheet.

5. Fire-fighting measures
Safety Data Sheet in accordance with Regulation (EC) No
1907/2006
Appretan N94151 liq Page 2

Substance key: 000000188876 Revision Date: 09.06.2009


Version : 2 - / EU Date of printing : 30.10.2009

Suitable extinguishing media


extinguishing measures to suit surroundings
Special hazards from the substance itself, its combustion products or from its vapours
In the event of fire the following can be released:
Carbon dioxide (CO2)
Carbon monoxide (CO)
Special protective equipment for firefighting
Use self-contained breathing apparatus
Wear full protective suit.

6. Accidental release measures


Personal precautions
Ensure adequate ventilation.
Environmental precautions
Do not allow to enter drains or waterways
Methods for cleaning up/taking up
Cover with absorbent material (eg sand, peat, earth) and then pick it up.
Dispose of contaminated material as prescribed

7. Handling and storage


Advice on safe handling
Use only in well ventilated areas.
It cannot be ruled out, that traces of following substances are present.
Vinyl acetate
Formaldehyde
Advice on protection against fire and explosion
Observe the general rules of industrial fire protection
Requirements for storage rooms and vessels
Keep only in the original container
Further information on storage conditions
Protect against frost. The product after freezing is no longer usuable
Protect from heat
Recommended storage temp 5-30 C
Storage stability
Storage period up to 12 months

8. Exposure controls / personal protection


Occupational exposure controls
General protective measures
Avoid contact with eyes and skin
Safety Data Sheet in accordance with Regulation (EC) No
1907/2006
Appretan N94151 liq Page 3

Substance key: 000000188876 Revision Date: 09.06.2009


Version : 2 - / EU Date of printing : 30.10.2009

Hygiene measures
Observe the usual precautions when handling chemicals.
Hand protection : Nitrile rubber gloves.
Observe the information of the glove manufacturers on
permeability and breakthrough times and other workplace
requirements
Eye protection : safety glasses

9. Physical and chemical properties


Form : Liquid
Colour : milky white
Odour : acrylic-like
Melting point : not determined
Boiling point : >= 100 C
Flash point : > 100 C
Method : NFT 60103 (closed cup)
Ignition temperature : not tested.
Self-ignition temperature : Not applicable
Flammability
Lower explosion limit : not tested.
Upper explosion limit : not tested.
Vapour pressure : not tested.

Density : approx. 1,05 g/cm3 (20 C)

Bulk density : Not applicable


Solubility in water : miscible in all proportions
Miscibility with water :
pH value : 3,5 - 4,5 (20 C)
Determined in the undiluted form
Octanol/water partition Not determined
coefficient (log Pow) :
Viscosity (dynamic) : approx. 100 mPa.s (20 C)
Method : Brookf-Visc.RVT Sp.1

10. Stability and reactivity


Thermal decomposition : No decomposition if used as prescribed.
Safety Data Sheet in accordance with Regulation (EC) No
1907/2006
Appretan N94151 liq Page 4

Substance key: 000000188876 Revision Date: 09.06.2009


Version : 2 - / EU Date of printing : 30.10.2009

Hazardous reactions
No hazardous reactions when stored and handled according to prescribed instructions.
Hazardous decomposition products
Carbon monoxide and carbon dioxide

11. Toxicological information


Acute oral toxicity : LD50 > 2.000 mg/kg (rat)
Test result of a similar preparation

Irritant effect on skin : non-irritant (rabbit)


Test result of a similar preparation
Irritant effect on eyes : non-irritant (rabbit eye)
test result of related preparation
Remarks
The toxicological data given are determined by analogy

12. Ecological information


Biodegradability : not tested.

Fish toxicity : LC50 100 - 1.000 mg/l (Brachydanio rerio)


Test conducted with a similar formulation.

Daphnia toxicity : not tested.

Algae toxicity : not tested.

Bacteria toxicity : EC50 100 - 1.000 mg/l (Pseudomonas putida)


Test conducted with a similar formulation.

Remarks
Ecological data are determined by analogy
Product does not contain any organic bound Halogens which could lead to AOX-values.
Do not dispose of in the environment.

13. Disposal considerations


Product
Incineration in suitable incineration plant, observing local authority regulations
Uncleaned packaging
Packaging that cannot be cleaned should be disposed of as product waste

14. Transport information


Safety Data Sheet in accordance with Regulation (EC) No
1907/2006
Appretan N94151 liq Page 5

Substance key: 000000188876 Revision Date: 09.06.2009


Version : 2 - / EU Date of printing : 30.10.2009

ADR not restricted


ADNR not restricted
RID not restricted
IATA not restricted
IMDG not restricted

15. Regulatory information


Labelling in accordance with EC-Directives
hazard warning labelling not compulsory
Chemical Safety Assessment
No Chemical Safety Assessment (CSA) is yet available for the substance, or for the
component substances, contained in this product.

16. Other information


See product leaflet

Decimal notation: "Thousands" places are identified with a dot (example: 2.000 mg/kg
means "two thousand mg/kg"). Decimal places are identified with a comma (example: 1,35
g/cm3).

The data are based on the current state of our knowledge, and are intended to describe the
product with regard to the requirements of safety. The data should not be taken to imply
any guarantee of a particular or general specification. It is the responsibility of the user of
the product to ensure to his satisfaction that the product is suitable for the intended purpose
and method of use. We do not accept responsibility for any harm caused by the use of this
information. In all cases, our general conditions of sale apply.