CHEMISTRY

Daily Practice Problems

Q.1 Find the species / molecule is having maximum number of lone pair on the central atom. [3]
(A) ClOF4 (B) ClOF2+ (C) BH4 (D) XeOF2

Q.2 If y-axis is the approaching axis between two atoms, then which of the set of orbitals can not form the
bond between two atoms in general. [3]
(A) pz pz (B) px px (C) px py (D) None of these

Q.3 The maximum number of bond and -bond can be formed between two atoms are respectively.[3]
(A) 4, 3 (B) 3, 2 (C) 2, 3 (D) 3, 1

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Q.4 Which of the following set of overlap can not provide -bond formation. [3]
(A) 3d and 2p (B) 2p and 3p (C) 2p and 2p (D) 3p and 1s

Q.5 The ratio of number of -bond to -bond in N2 and CO molecules are [3]

(A) 2.0 , 2.0 (B) 2,

1
2
yP (C)
1 1
,
2 2
(D)
1
2
,2

Q.6 Which of the following overlapping is involved in formation of only -bond. [5]
(A) s p overlapping (B) p d overlapping
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(C) s s overlapping (D) p p overlapping

Paragraph for question nos. 7 to 9

Different types of bonds are formed in the chemical compounds. These bond have different strength and
bond energies associated with them. These bonds are formed with atoms in different environments.
S

Q.7 Which of the following bond has highest bond energy? [9]
(A) -bond (B) -bond (C) Hydrogen bond (D) Metallic bond
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Q.8 Shape of the molecule is decided by

(A) -bond (B) -bond
(C) both and -bond (D) Never Nor -bond

Q.9 Which of the following hydrides is thermally least stable?

Ac

(A) H2O (B) H2Te (C) H2S (D) H2Se

Q.10 Match the column : [4]

Column I Column II
(Orders) (Sequences)
(A) Increasing order of ionic (P) Si, Mg, Al, Na
mobility in water
(B) Decreasing order of size (Q) Li+, Na+, K+, Rb+, Cs+
(C) Decreasing order of ionisation (R) O, O+, O2, O
energy
(S) Se, S, O, F
 CHEMISTRY
Daily Practice Problems

Q.1 Explain type of hybridisation, shape, bond angle and geometry of the following compounds.
[18]
(1) XeF2 (11) IF7

(2) XeF4 (12) OF 2

(3) XeF5 (13) NO 3

(4) XeOF4

t
(14) ClO 4

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(5) PCl3
(15) SF4
(6) PCl5
(16) I3
(7)

(8)
SF2

SF6
yP (17) ClO3

(18) OCl2
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(9) IF3

(10) IF5

Q.2 What is hybridisation of central atom of anionic part of PBr5 in crystalline state. [3]
S

(A) sp2 (B) sp3 (C) sp (D) not applicable

Q.3 What is the difference between bond angles in cationic species of PCl5 and PBr5 in solid state. [3]
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(A) 60 (B) 10928 (C) 0 (D) 90

Q.4 All possible bond angles in anionic part of PCl5 are. [3]
(A) 109 28 only (B) 90, 180 (C) 90, 120, 180 (D) 72, 90, 180
Ac

Q.5 The hybridisation and shape of XeO3F2 molecule is [3]

(A) sp3 and tetrahedral (B) sp3d and see-saw
(C) sp3d and TBP (D) sp3d2 and octahedral

Q.6 TeF5 , XeF2 , I3+ , XeF4 , PCl3

Which of the following shape does not describe to any of the above species ? [3]
(A) Square pyramidal (B) Square planar
(C) Trigonal planar (D) Linear

Q.7 Which of the following species does not exist? [3]

(A) XeF3 (B) XeF4 (C) XeF5 (D) XeF6
Q.8 Which of following pair of species is having different hybridisation but same shape. [3]
(A) BeCl2 and CO2 (B) CO2 and SO2 (C) SO2 and I3 (D) ICl 2 and BeH2

Q.9 Statement-1 : CH4 and CH2F2 are having regular tetrahedron geometry. [3]
Statement-2 : Both are having same hybridization.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.

Paragraph for question nos. 10 to 12

Hybridisation is the mixing of atomic orbital of comparable energy and the number of hybrid orbitals
formed is equal to the number of pure atomic orbitals mixed up and hybrid orbitals are occupied by
-bond pair and lone pair. [9]
Q.10 Which of the following geometry is most likely to not form from sp3d hybridisation of the central atom.
(A) Linear (B) Tetrahedral (C) T-Shaped (D) See-Saw

Q.11 The orbital is not participated in sp3d2 hybridisation.

(A) px (B) dxy (C) d x 2 y 2 (D) pz

Q.12 "The hybrid orbitals are at angle of X to one another" this statement is not valid for which of the
following hybridisation.
(A) sp3 (B) sp2 (C) sp3d2 (D) sp