CHEMISTRY

DPPS: 14 ATOMIC STRUCTURE

1 Which of the following is/are correct statement(s)?

(a) The ration of wavelengths of mth an nth lines in Lyman series of a H like species is

m m 1
n 1 1
2 2


n n 12
m 1
2
1

(b) Kinetic energies of emitted electrons during photoelectric effect is lower than the energy of incident
radiation.
(c) Balmer lines are observed in visible region of electromagnetic spectrum for H-like species.
(d) The scattering of -particles involves a perfectly elastic collision.

2 A sample of the hydrogen atoms absorbs radiation of wavelength 0 and consequently emits radiations of six
different wavelengths of which two wavelengths are shorter than 0. Choose the correct alternatives.
(a) The highest orbit occupied by the electron is the fourth orbit.
(b) The initial orbit number of the electrons may be 2.
(c) The initial orbit number of the electrons may be 3.
(d) There are three transitions belonging to Lyman series.
An
3 Let An be the area enclosed by nth orbit in the H-atom. The graph In against In (n)
A1
(a) Will pass through origin
(b) Will be straight line with slop = 4
(c) Will be monotonically increasing non-linear curve
(d) Will be a circle

4 According to Bohrs model,

(a) Energy of an electron is discrete --- not continuous
(b) An electron revolves in a fixed orbit and does not loses energy during revolution
(c) Angular momentum of an electron is quantized
(d) When an electron jumps from a higher orbit to lower orbit, energy equal to the energy of higher orbit is
released in the form of photons

5 Which of the following is (are) true regarding a H-like species, on the basis of Bohrs model?
Ze 2
(a) Kinetic energy of an electron in nth Bohr orbit is .
8 0 r
Ze 2
th
(b) Potential energy of an electron in n Bohr orbit = .
4 0 r
(c) Emission spectrum of H-atom is continuous.
(d) Electrons when passed through electric and magnetic field, get deflected.

6 If the shortest wavelength of transition of H-atom in Lyman series is x, then the correct conclusion is (are)
x
+
(a) The longest wavelength in Balmer series of He is .
4
(b) The shortest wavelength in Balmer series of He+ is x.

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 CHEMISTRY
DPPS: 14 ATOMIC STRUCTURE

4
(c) The longest wavelength in Lyman series of H atom is x.
3
16 x
(d) The longest wavelength in Paschen series of Li2+ is .
7

Answer:

1 2 3 4 5 6
a,b,c a,b,d a,b a,b,c a,b b,c,d

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