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1. A first order reaction is 87.5% complete in an hour. The rate constant of the
reaction is (ln2 = 0.693)
2. The half -life a first order reaction is 24 hours. If we start with 10M initial concentration of
the reactant then conc. after 96 hours will be
3. During the particular reaction 10% of the reactant decompose in one hour 20% in two
hours 30% in three hours and so on. The unit of the rate constant is
4. For a given reaction of first order, it takes 20 min, for the concentration to drop from
1 M L1 to 0.6 ML1. The time required for the concentration to drop from 0.6 ML 1 to 0.36
ML1 will be
(A) will increase by 2.828 times (B) will increase by 11.313 times
(C) will not change (D) will increase by 4 times
8. For a first order reaction A P, the temperature (T) dependent rate constant (k) was
found to follow the equation:
log k = 2000/T + 6
The pre-exponential factor A and the activation energy Ea, respectively, are
(A) 1.0 106 s-1 and 9.2 kJ mol-1 (B) 6.0 s-1 and 16.6 kJ mol-1
(C) 1.0 10 s and 16.6 kJ mol
6 -1 -1
(D) 1.0 106 s-1 and 38.3 kJ mol-1
Ea
-
10. In Arrheniuss equation, k = A exp RT . A may be termed as the rate constant at
(A) very low temperature
(B) very high temperature
(C) zero activation energy
(D) the boiling temperature of the reaction mixture
11. For the first order reaction 2N2O5 (g) 4NO2 (g) + O2 (g)
(A) The concentration of reactant decreases exponentially with time.
(B) The half life of the reaction depends on the initial concentration of reactant
(C) The half life of the reaction decreases with increasing temperature
(D) The reaction proceeds to 99.6% completion in eight half-life duration.
Column I Column II
t63/64 6t1/2
t15/16 2t3/4
t31/32 5
3 t7/8
t255/256 2t15/16
Section-IV (integer type)
17. The reaction A(g) + 2B(g) C(g) + D(g) is an elementary process. In an experiment,
the initial partial pressure of A & B are PA = 0.60 and PB = 0.80 atm. If rate of reaction
is r when PC = 0.2 atm and the initial rate of reaction is R. Then R/r is
18. For a hypothetical reaction A + B C+D, the rate = k[A]1/2 [B]3/2. On doubling the
concentrations of A and B the rate will become n times the previous rate. n' is
20. Under the same reaction conditions, initial concentration of 1.386 mol dm -3 of a
substance becomes half in 40 s and 20 s through first order and zero order kinetics
respectively. Ratio of (k0/k1) of the rate constants for zero order (k0) and first order (k1) is