Conversion

171 MMSCFD 8518.916993

CO2/STEAM MIXED REFORMING

Option 1:

CO2 + CH4 = 2CO + 2H2

(kgmol/h) feed mass (kg) no of mol

CH4 2044.54
CO2 5963.24
H20
CO
H2

Option 2:

(kgmol/h) feed mass (kg) no of mol

CH4 2044.54
CO2 5963.24
H20
CO
H2
kgmole/hr

CO2 + CH4 = 2CO + 2H2 1

H2O + CH4 = CO + 3H2 2
Reforming conversion Reaction 1 Reaction 2
Consumption Production Total Consumption
1022.27 1022.27 1022.27
1022.27 4940.97
1022.27
2044.54 2044.54
2044.54 2044.54

CO2 + 2H2O + 3CH4 = 4CO + 8H2

Reforming conversion Reaction 1
Consumption Production Total
2044.54 0.00
681.51 5281.73
1363.03 0.00
2726.05 2726.05 H2/CO Ratio
5452.11 5452.11 2.00
 Reaction 2
Production Total
0.00
4940.97
0.00
1022.27 3066.81 H2/CO Ratio
3066.81 5111.35 1.67
 Conversion
171 MMSCFD 8518.916993 kgmole/hr

PRE-REFORMER

CnHm + nH2O = nCO + (n+m/2)H2 (1)

CO + 3H2 = CH4 + H2O (2)
CO + H2O = CO2 + H2 (3)
C3H8
(kgmol/h) Reaction 1 Reaction 2
Consumption Production Total Consumption Production
C3H8 42.59 42.59 0.00
C2H6 468.54 468.54
CH4 2044.54 2044.54 85.19
CO2 5963.24 5963.24
CO 0.00 127.78 127.78 85.19
H2 0.00 298.1620948 298.16 255.567509805
H2O 2000.00 127.7837549 1872.22 85.19

C2H6
(kgmol/h) Reaction 1 Reaction 2
Consumption Production Total Consumption Production
C3H8 0.00 0.00 0.00
C2H6 468.54 468.54 0.00
CH4 2129.73 2129.73 468.54
CO2 6005.84 6005.84
CO 0.00 937.08 937.08 468.54
H2 85.19 2342.702173 2427.89 1456.73480589
H2O 1914.81 937.08086928 977.73 468.54

DRY REFORMING

CH4 + CO2 = 2CO + 2H2

(kgmol/h) Reaction 1
Consumption Production Total
C3H8 0.00 0.00
C2H6 0.00 0.00
CH4 2598.27 2598.27 0.00
CO2 6474.38 2598.27 3876.11
CO 0.00 5196.54 5196.54
H2 1439.70 5196.539366 6636.24
H2O 977.73 977.73

FT SYNTHESIS

C8H18
(kgmol/h) Reaction 1 Reaction 2
Consumption Production Total Consumption Production
C3H8 0.00 0.00
C2H6 0.00 0.00
CH4 0.00 0.00
CO2 3876.11 3876.11
CO 5196.54 3122.93 2073.60
H2 6636.24 6636.24 0.00
H2O 977.73 3122.934747 4100.66
C8H18 390.3668434 390.37
 CO2 70%
CH4 24%
C2H6 5.5%
C3H8 0.5%

8
action 2 Reaction 2
Total Consumption Production Total
0.00 0.00
468.54 468.54
2129.73 2129.73
5963.24 42.59 6005.84
42.59 42.59 0.00
42.59 42.59 85.19
1957.41 42.59 1914.81

6
action 2 Reaction 2
Total Consumption Production Total
0.00 0.00
0.00 0.00
2598.27 2598.27
6005.84 468.54 6474.38
468.54 468.54 0.00
971.16 468.54 1439.70
1446.27 468.54 977.73
8
action 2 Reaction 2
Total Consumption Production Total
 Conversion
171 MMSCFD 8518.916993 kgmole/hr

CRYOGENIC DISTILLATION

(kgmol/h)
Inlet Vap Outlet Liq Outlet Total Outlet
C3H8 42.59 0.4088 42.09 42.50
C2H6 468.54 43.3328 425.41 468.74
CH4 2044.54 1758.86 285.55 2044.41
CO2 5963.24 241.40 5721.96 5963.35
CO 0.00 0.00 0.00 0.00
H2 0.00 0.00 0.00 0.00
H2O 0.00 0.00 0.00 0.00
Total 8518.92 2044 6475 8519.00

DRY REFORMING

CH4 + CO2 = 2CO + 2H2

(kgmol/h) HYSYS Output

Consumption Production Total
C3H8 42.50 42.50 42.8448127151
C2H6 468.74 468.74 468.7726567657
CH4 2044.41 2044.41 0.00 3.7804246513
CO2 5963.35 2044.41 3918.94 3921.560504986
CO 0.00 4088.82 4088.82 4082.858623443
H2 0.00 4088.819 4088.82 4082.858623443
H2O 0.00 0.00 0.000
TOTAL 12601.41550445

FT SYNTHESIS
2 (%)= ([2 ])/([ ][ ])
x 100

(%)= ([2 ][ ][2 ])/([ ][ ]) x

100

4 (%)= [4 ]/([ ][ ][2 ]) x 100

24 (%)= (24_(=2)^4 (_ _2 +_
_(2+2)))/([ ][ ][2 ]) x 100
24 (%)= (24_(=2)^4 (_ _2 +_
_(2+2)))/([ ][ ][2 ]) x 100

5+ (%)= ([ ][4 ]24_(=2)^4 (_ _2 +_ _(2+2)))/

([ ]) x 100

Selectivity In Out Mole Fraction

CH4 0.00 435.3001096 435.30010962 0.0206614319
CO2 0.01 3217.859756 0.32 0.0000152735
CO - 3217.859756 0
H2 - 0
H2O - 17415.08514 0.8266035038
C2H6 31.07 5.604426316
C2 - C4 C3H8 - 999.68904729 0.047450039
C4H10 -
C5H12 68.93 -
C6H14
C7H16
C8H18
C5+ 2217.8489227 0.1052697518
C9H20
C10H22
C11H24
C12H26
SUM 6876.778983 21068.245005 1
 CO2 70%
CH4 24%
C2H6 5.5%
C3H8 0.5%

ERROR (%)

0.8201%
0.0069%

0.0668%
-0.1458%
-0.1458%

[ ]) x

x 100
_2 +_ _(2+2)))/

Mole Fraction (average)

0.0206614319
0.0000152735

0.8266035038
0.0160826926
0.0158166797
0.0158166797
0.013158719
0.013158719
0.013158719
0.013158719
0.013158719
0.013158719
0.013158719
0.013158719
1.000266013
 kgmole/h
Selectivity In Out Mole fraction
CO - 4082.86 0.00 0
CO2 0.01 4082.86 0.41 2.78E-06
HC 99.99 0.00 4082.45
CH4 0.00 0.00 0.00 0
C2-C4 31.07 0.00 1268.42 0.008631 0.002877
C5+ 68.93 0.00 2814.03 0.019147 0.004787
H2O ### 0.97222
### 1