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ABC CLASSES FOR IIT-JEE

ALKYL HALIDE & ORGANOMETALLIC COMP.
D.P.P. - 2

1. Write down the missing products.

2. What are compound (A) to (C)?

3. Identify A, B, C, D and E, F in following series of reactions.

4. Explain the fact that a small amount of NaI catalyzes the general reaction.
RCl + R' O − Na + → ROR'+ NaCl .
5. Identify the product.

6. Arene B (C10H14) has 5 possible mono chloro derivatives (C10H13Cl) considering both ring and silde
chain halogenation vigorous oxidation of B yields an acidic compound C8H6O4 having only one
mononitro substitution product C8H5O4NO2. Identify B and also draw structure of 5 monochloro
derivatives.
7. When alkyl halides are treated with aqueous AgNO3, silver halide precipitate and an alcohol is
formed. From what you know about the SNI reaction, propose a mechanism for the following
conversion.

ABC CLASSES126,2nd Floor , Kingsway Camp ,Delhi-110009,Ph.No:011-

47041845.
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8. 0.3699 of a bromoderivative of a hydro carbon (A) when vaporized occupied 67.2 ml at NTP. (A)
on reaction with aq. NaOH gives (B). (B) when passed over alumina at 2500C gives an isomer of
(A). When (D) is treated with conc. H2SO4 and the product obtained. Identify (A) to (E).
9. Identify A, B and C;

10. C4H8Cl2 (A) on hydrolysis forms C4H8O (B) which forms an oxime, but does not reduce Fehling
soln. B also gives iodoform test. Identify A and B and explain the reactions.

ABC CLASSES126,2nd Floor , Kingsway Camp ,Delhi-110009,Ph.No:011-

47041845.