PHYSICAL CHEMISTRY

TARGET : JEE (Main) 2017

Course : ABHINAV (EA) NO. 20

This DPP is to be discussed in the week (24-08-2015 to 29-08-2015)

DPP No. # 20
Total Marks : 46 Max. Time : 30 min.
Single choice Objective ('1' negative marking) Q.1 to Q.10 (3 marks, 2 min.) [30, 20]
Multiple choice objective ('1' negative marking) Q.11 to Q.12 (4 marks, 2 min.) [8, 4]
Match the Columns (no negative marking) Q.13 (8 marks, 6 min.) [8, 6]

1. The Habers process involves an exothermic reversible reaction for which the yield would be high for :
(1) Low T, Low P (2) High T, Low P (3*) Low T, High P (4) High T, High P
gSoj&ize] "ek{ksih mRe.kh; vfHkf;k gS rc fdlds fy, yfCk mPp gksxhA
(1) fuEu T, fuEu P (2) mPp T, fuEu P(3*) fuEu T, mPp P (4) mPp T, mPp P
Sol. N2 + 3H2 2NH3 + Heat for the Habers process
(g) (g) (g)
Hence as per Le-Chatelier principle use high P & low T to maximize yield.

2. For the reaction A(s) B(s) + 2C(g) ; Kp = 16 (atm)2 at 1000 K. In a vessel of 20.5 litre 2 moles of B are
taken at 1000 K and then 2 moles of C are added. Assuming volume occupied by the solid to be negligible,
predict :
(1) Nothing can be predicted in the absence of sufficient data
(2) Nothing would happen
(3*) An equilibrium will be set up with the formation of 0.5 moles of A
(4) B and C would react completely to form A.
1000 K ij vfHkf;k A(s) B(s) + 2C(g) ds fy, Kp = 16 (atm)2 gSA ,d 20.5 yhVj ds ik=k esa 1000 K ij B ds
2 eksy fy, x;s rFkk fQj C ds 2 eksy feyk;s x,A ekuk Bksl }kjk ?ksjk x;k vk;ru ux.; gS] vuqeku yxkb, %
(1) i;kZIr vkdMksa dh vuqifLFkfr esa vuqeku ugha yxk;k tk ldrk gSA
(2) dqN ?kfVr ugha gksxkA
(3*) A ds 0.5 eksyksa ds fuekZ.k ds lkFk lkE;oLFkk LFkkfir gksxhA
(4) B rFkk C iw.kZr;k vfHkf;k dj A cuk;sxhA
Sol. kp = 16
pc2 = 16 or pc = 4 atm
4 20.5 = nc 0.082 1000 nc = 1.0
eq (Total moles)
It means one mole of c (out of 2 added) will react with 0.5 mol of B to produce 0.5 mole of A.

3. Which of the following is correct for the equilibrium of the reaction

C(s) + H2O(g) CO(g) + H2(g)
vfHkf;k C(s) + H2O(g) CO(g) + H2(g) ds lkE; ds fy, fuEu esa ls dkSu lk lgh gS \
pH2 2O
(1) pH2 pH2O (2*) pH2 pH2O (3) p H2 p H2O (4) pH2
2
pCO

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4. 1 mol of N2O4(g) at 300 K is kept in a closed container under 1 atm. It is heated to 600 K, upon which 20%
by mass of N2O4(g) decomposes to NO2(g). The resultant pressure is
300 K rFkk 1 atm ij ,d can ik=k esa N2O4(g) ds 1 eksy j[ks x;s gSA bls 600 K rd xeZ djus ij N2O4(g) dk 20%
O;eku fo?kfVr gksdj NO2(g) nsrk gSA ifj.kkeh nkc gS %
(1) 1.2 atm (2*) 2.4 atm (3) 2.0 atm (4) 1.0 atm

5. A sample of pure NO2 gas heated to 1000K decomposes : 2NO2 2NO(g) + O2(g). The equilibrium
constant KP is 100 atm. Analysis shows that the partial pressure of O2 is 0.25 atm. at equilibrium. The partial
pressure of NO2 at equilibrium is:
'kq) NO2 xSl ds izkn'kZ dks 1000K rd xeZ djus ij ;g fo?kfVr gks tkrk gS 2NO2 2NO(g) + O2(g). lkE; fu;rkad
KP = 100 atm gSA fo'ys"k.k ls Kkr gksrk gS fd lkE; ij O2 dk vkaf'kd nkc 0.25 atm gSA rc lkE; ij NO2 dk vkaf'kd
nkc gS %
(1) 0.03 (2) 0.25 (3*) 0.025 (4) 0.04

6. The value of Kc for the reaction 2SO3(g) 2SO2(g) + O2(g) is 10 mol/l. at a certain temp. TK. The no. of
molecules of O2 present at equilibrium in a 10 lit. vessel such that the active masses of SO3 and SO2 is same
at equilibrium :
(1) 10 (2) 10 NA (3) 100 (4*) 100 NA.
(Where NA = Avogadro Number)
vfHkf;k 2SO3(g) 2SO2(g) + O2(g) ds fy, fdlh fuf'pr rki TK ij Kc dk eku 10 mol/l gSA lkE; ij 10 yhVj
ik=k esa O2 ds v.kqvksa dh la[;k bl izdkj mifLFkr gS fd lkE; ij SO3 rFkk SO2 ls lf; O;eku leku gS %
(1) 10 (2) 10 NA (3) 100 (4*) 100 NA.
(tgk NA =vkoksxkks la[;k)

7. For N2 + 3H2 2NH3, at equilibrium; mixture contains a mol N2 ,b mol H2 , c mol NH3 and d mole of an
inert gas. Given p1v = (a + b + c) RT and p2 v = (a + b + c + d) RT then expression of kp is
(1) (1/p22) (c2/ab3) (a + b + c)2 (2*) (1/p12) (c2/ab3) (a + b + c)2
2 2 3 2
(3) (1/p2 ) {(2c) / (1) (3b) } (a + b + c + d) (4) None of these
lkE; ij N2 + 3H2 2NH3 ds fy,; ,d feJ.k esa N2 ds a eksy, H2 ds b eksy] NH3 ds c eksy rFkk ,d vh; xSl
ds d eksy mifLFkr gSA fn;k gS p1v = (a + b + c) RT rFkk p2 v = (a + b + c + d) RT rc kp ds fy, O;atd gS %
(1) (1/p22) (c2/ab3) (a + b + c)2 (2*) (1/p12) (c2/ab3) (a + b + c)2
(3) (1/p22) {(2c)2 / (1) (3b)3} (a + b + c + d)2 (4) fuEu esa ls dksbZ ugh

8. A vessel contain SO3, SO2, O2, He in molar ratio of 1 : 2 : 3 : 4 at equilibrium. Which of the following is correct
(1*) Kp for 2SO3 2SO2(g) + O2(g) is 1.2 p where p is the total pressure of the vessel
(2) Kp for SO2 + 1/2 O2 SO2 is (1/ 3p 0 ) where p0 is the pressure due to inert gas
(3) both
(4) None of these.
lkE; ij ,d ik=k esa SO3, SO2, O2, He dk eksyj vuqikr 1 : 2 : 3 : 4 gSA fuEu esa ls dkSulk lgh gS \
(1*) 2SO3 2SO2(g) + O2(g) ds fy, Kp = 1.2 p gS tgk p ik=k dk dqy nkc gSA
(2) SO2 + 1/2 O2 SO2 ds fy, Kp = (1/ 3p 0 ) gS tgka p0 vf; xSl ds dkj.k mRiUu nkc gSA
(3) nksuks
(4) fuEu esa ls dksbZ ugha

9. 1 mole Cl2 and 1 mole H2 gas is placed in a container, the gases combined spontaneously in the presence
of sunlight. If before reaction the pressure is p1 and after the reaction pressure is p2 then (assume the ideal
beheviour)
(1) p1 > p2 (2) p1 < p2 (3*) p1 = p2 (4) none
,d ik=k esa 1 eksy Cl2 rFkk 1 eksy H2 xSl j[kh x;h gSA lw;Z izdk'k dh mifLFkfr esa xSls Lor% la;qDr gks tkrh gSA ;fn
vfHkf;k ls iwoZ nkc p1 rFkk vfHkf;k ds i'pkr~ nkc p2 gS rc (ekuk vkn'kZ O;ogkj gS)
(1) p1 > p2 (2) p1 < p2 (3*) p1 = p2 (4) dksbZ ugha

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10. For the gaseous equilibrium, A2 (g) + B2(g) 2AB(g), the equilibrium constant at a certain temperature
is 49. If an equimolar mixture of A2 and B2 is heated in a closed container to this temperature, the mole
fraction of B2 in the equilibrium mixture is
A2 (g) + B2(g) 2AB(g) xSlh; lkE; ds fy, fdlh fuf'pr rki ij lkE; fu;rkad 49 gSA ;fn bl rki ij ,d
can ik=k esa A2 rFkk B2 ds leeksyj feJ.k dks xeZ fd;k x;k rc lkE; feJ.k esa B2 dk eksy izHkkt gS %
2 1 3 1
(1) (2*) (3) (4)
9 9 8 8
Sol. A2 + B2 2AB ; K = 49
1 1 0
1x 1x 2x
2x
=7
1 x
2x = 7 7x
9x = 7
7
x=
9

2/9 1
XB 2 = =
2 9

11. Which of the following reactions nearly go to completion.

fuEu esa ls dkSu lh vfHkf;k,sa lekfIr dh vksj vxzlj gS \
(1*) A2 + B2 2AB ; Kc = 1 1024 (2) C2 + D2 2CD ; KC = 1 1024
(3) E2 + F2 2EF ; Kc = 3.4 100 (4*) G2 + F2 2GF ; Kc = 3.4 1034
Sol. If the value of KC is very large the reaciton is almost complete.

12. For the equilibrium N2O4 2NO2 , the value of equilibrium constant is 2 104 at a particular temperature
if equilibrium is established by taking 2 moles of N2O4 in 1 litre container then
(1) Concentration of NO2 at equilibrium is approximately 0.02 M
(2*) Concentration of NO2 at equilibrium is approximately 0.01 M
(3*) Concentration of N2O4 at equilibrium is approximately 2 M
(4) Concentration of N2O4 at equilibrium is approximately 1 M
lkE; N2O4 2NO2 ds fy, ,d fuf'pr rki ij lkE; fu;rkad dk eku 2 104 gSA ;fn 1 yhVj ds ik=k esa N2O4
ds 3 eksy ysus ij lkE; LFkkfir gks tkrk gS rc %
(1) lkE; ij NO2 dh lkUrk yxHkx 0.02 M gSA
(2*) lkE; ij NO2 dh lkUrk yxHkx 0.01 M gSA
(3*) lkE; ij N2O4 dh lkUrk yxHkx 2 M gSA
(4) lkE; ij N2O4 dh lkUrk yxHkx 1 M gSA

Sol. N2O4 2NO2

2x 2x 2x~2

4x 2
= 2 104 x = 0.01
2

13. Match the following :

Column I Column II
(a) For the equilibrium
NH4(s) NH3(g) + H(g), if pressure is increased at equilibrium (P) Forward shift
(b) For the equilibrium
N2 + 3H2 2NH3 at equilibrium volume is increased at equilibrium (Q) No change

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 (c) For the equilibrium
H2O(g) + CO(g) H2(g) + CO2 (g) inert gas is (R) Backward shift
added at constant pressure at equilibrium
(d) For the equilibrium
PCl5 PCl3 + Cl2, Cl2 is removed at equilibrium (S) Final pressure is
more than initial pressure
Pf > Pi
fuEu dks lqesfyr fdft, %
dkWye I dkWye II
(a) fuEu lkE; NH4(s) NH3(g) + H(g), (P) vxz fn'kk
ds fy,] ;fn lkE; ij nkc dks c<+k;k tkrk gks
(b) fuEu lkE; N2 + 3H2 2NH3 , (Q) dksbZ ifjorZu ugha
ds fy,] lkE; ij vk;ru dks c<k;k+ tkrk gks
(c) fuEu lkE; H2O(g) + CO(g) H2(g) + CO2 (g) (R) i'p fn'kk
fu;r nkc ij vf; xSl dks feyk;k tkrk gksa
(d) fuEu lkE; PCl5 PCl3 + Cl2 (S) vfUre nkc] izkjafHkd nkc ls vf/kd gksxk Pf > Pi
ds fy,] lkE; ij Cl2 dks gVk;k tkrk gS
Ans. (a R, S ; b R ; c Q ; d P, S)

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