Escolar Documentos
Profissional Documentos
Cultura Documentos
Higheralkanes
FromWikipedia,thefreeencyclopedia
Higheralkanesarealkaneshavingnineormorecarbonatoms.Nonaneisthelightestalkanetohaveaflashpointabove25C,andis
notclassifiedasdangerouslyflammable.
Thetermhigheralkanesissometimesusedliterallyas"alkaneswithahighernumberofcarbonatoms".Onedefinitiondistinguishesthe
higheralkanesasthenalkanesthataresolidundernaturalconditions.
Contents
1 Uses
2 Properties
2.1 Nonanetohexadecane
2.2 HeptadecanetoTetracosane
2.3 PentacosanetoTriacontane
2.4 Hentriacontanetohexatriacontane
2.5 HeptatriacontanetoDotetracontane
2.6 TritetracontanetoOctatetracontane
2.7 NonatetracontanetoTetrapentacontane
3 Seealso
4 References
5 Externallinks
Uses
Alkanesfromnonanetohexadecane(analkanewithsixteencarbonatoms)areliquidsofhigherviscosity,whicharelesssuitableforuse
ingasoline.Theyforminsteadthemajorpartofdieselandaviationfuel.Dieselfuelsarecharacterisedbytheircetanenumber,cetane
beinganoldnameforhexadecane.Howeverthehighermeltingpointsofthesealkanescancauseproblemsatlowtemperaturesandin
polarregions,wherethefuelbecomestoothicktoflowcorrectly.Mixturesofthenormalalkanesareusedasboilingpointstandardsfor
simulateddistillationbygaschromatography.[1]
Alkanesfromhexadecaneupwardsformthemostimportantcomponentsoffueloilandlubricatingoil.Inlatterfunctiontheyworkat
thesametimeasanticorrosiveagents,astheirhydrophobicnaturemeansthatwatercannotreachthemetalsurface.Manysolidalkanes
finduseasparaffinwax,usedlubrication,electricalinsulation,andcandles.Paraffinwaxshouldnotbeconfusedwithbeeswax,which
consistsprimarilyofesters.
Alkaneswithachainlengthofapproximately35ormorecarbonatomsarefoundinbitumen(asphalt),used(forexample)inroad
surfacing.However,thehigheralkaneshavelittlevalueandareusuallysplitintoloweralkanesbycracking.
Properties
Thepropertieslistedhererefertothestraightchainalkanes(or:nalkanes).
Nonanetohexadecane
Thisgroupofnalkanesisgenerallyliquidunderstandardconditions.[2]
https://en.wikipedia.org/wiki/Higher_alkanes#cite_ref2 1/3
4/2/2017 HigheralkanesWikipedia
HeptadecanetoTetracosane
Fromthisgroupon,thenalkanesaregenerallysolidatstandardconditions.
PentacosanetoTriacontane
Hentriacontanetohexatriacontane
HeptatriacontanetoDotetracontane
TritetracontanetoOctatetracontane
NonatetracontanetoTetrapentacontane
Seealso
Alkene
Alkyne
Cycloalkane
Hydrocarbon
Paraffinwax,composedmostlyofhigherlinearalkanes
Polyethylene,alinearalkaneofpolymericlength
References
1.ASTMD539909,StandardTestMethodforBoilingPointDistributionofHydrocarbonSolventsbyGasChromatography
2.KarlGriesbaum,ArnoBehr,DieterBiedenkapp,HeinzWernerVoges,DorotheaGarbe,ChristianPaetz,GerdCollin,DieterMayerHartmut
Hke"Hydrocarbons"inUllmann'sEncyclopediaofIndustrialChemistry,2005,WileyVCH,Weinheim.doi:10.1002/14356007.a13_227(http
s://dx.doi.org/10.1002%2F14356007.a13_227)
3.Weast,RobertC.,ed.(1982).CRCHandbookofChemistryandPhysics(63rded.).BocaRaton,Fl:CRCPress.p.C561.
Externallinks
InternationalChemicalSafetyCard1245(http://www.inchem.org/documents/icsc/icsc/eics
Lookuphigheralkanesin
1245.htm)(nonane) Wiktionary,thefree
NIOSHPocketGuidetoChemicalHazards(http://www.cdc.gov/niosh/npg/npgd0466.htm dictionary.
l)(nonane)
InternationalChemicalSafetyCard0428(http://www.inchem.org/documents/icsc/icsc/eics
WikimediaCommonshas
0428.htm)(decane) mediarelatedtoHigher
Alkanes.
Retrievedfrom"https://en.wikipedia.org/w/index.php?title=Higher_alkanes&oldid=746816373"
Categories: Alkanes
Thispagewaslastmodifiedon29October2016,at19:05.
TextisavailableundertheCreativeCommonsAttributionShareAlikeLicenseadditionaltermsmayapply.Byusingthissite,
youagreetotheTermsofUseandPrivacyPolicy.WikipediaisaregisteredtrademarkoftheWikimediaFoundation,Inc.,a
nonprofitorganization.
https://en.wikipedia.org/wiki/Higher_alkanes#cite_ref2 3/3