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Examples 12.2 Molar analysis of combustion products with 200% theorical air
Dew point temperature for a given ambient pressure
Gas data
Rev. cjc. 30.11.2016
% theorical air
1.- Air fuel molar ratio for a stoichiometric perfect combustion of octane.
2.- Air fuel mass ratio for a stoichiometric perfect combustion of octane.
NF = 1 kmolF
NN2 = 47 kmolNO2/kmolC8H18
8 CO2 + 9 H2O + 47
15.0
2
Examples 12.2 [4] , page 508 Octane
1 C8H18 + 25 O2 + 94 N2 ---->
O2
Example 12.2 [4] , page 508
Table 1
Mol
percentage
%
CO2 6.47
H2O 7.29 3
N2 10.12
O2 76.12
tDP = 40.0 C 4
Example 12.3 [4] , page 508 Coal gas
Given the volume fraction of a coal gas and an excess air factor (EAF)
determine: 1.- Stoichiometric air fuel volume ratio
2.- Air fuel volume ratio for combustion with excess air
3.- Air fuel mass ratio for combustion with excess air
1
Total products of stoichiometric combusti
Nprod_st = 2.028
0.974 Air
0 S + 0.045 CO2 + 0.259 O2 + 0.974 N2 ----> 0.200 H2O 0.345 CO2 1.483 N2 + 0
1
etric combustion
N2 SO2
0 0
0 0
1 0.509 0
0 0
0 0
0 1 0
0 0
1 0.974 0
N2 = 1.483 SO2 = 0
of stoichiometric combustion
kmolprod / kmolF
roducts (st)
roducts (st)
SO2
SO2
molprod / kmolF
Example 12.3 [4] , page 508
1.- Stoichiometric air fuel volume ratio
2.- Air fuel volume ratio for combustion with excess air
3.- Air fuel mass ratio for combustion with excess air
1
1.233
2
1.48
3
1.73
Example 12.4, [4] page 511 Methane
Orsat analysis of combustion For 100 mols of dry products the equation of combustion is
products of methane
[4], Example 12.4, page 511 a CH4 + b O2 + c N2
Dividing by 10.53
CH4 + 2.20 O2 + 8.27 N2
+ 0.265 + d/2
N2
Page 2 of 3
N2
N2
N2
Page 3 of 3
Example 12.4 [4] , page 511
Percentage of theotical ai
PTA =
Mass air fuel ratio
1
18.97 kgair / kgF 1
110 % 2
Gas data
Ref [2]
Gas MW MW
kg/kmol kg/kmol General gas Conststant
CH4 16.042 16 R= 8314 J/(kmol*K)
C2H6 30.068 30 Standard ambient pressure
C3H8 44.094 44 P= 101325 Pa
C4H10 58.12 58
C5+ 60 60 ratio_N2_O2_a = 3.76
C2H18 114.224 114
H2 2.016 2 Molecular mass of air
CO 28.010 28.01 MMAir = 28.97 kgAir / kmolAir
CO2 44.01 44.01
S 32.06 32
SH2 34.08 34
SO2 64.06 64 Dew point temperature 0 C < tDP <
H2O 18.016 18 [3], page 6.9, equation (35)
N2 28.016 28.016
Ar 39.944 40 tDP = -35.957 - 1.8726*LN(pw) + 1.1689 * (LN(pw))^
O2 32 32 pw = 5000 Pa tDP =
C 12 12 tDP = 32.9 C
70 C
[2] Termodinamica
Virgil Moring Faires