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IP/Pure O Level Chemistry


Revision questions for Mole Calculation
Practice paper (IP)

*Q1) A supply of sodium metal was contaminated with sodium oxide and sodium chloride. A
sample of this metal weighing 1.00g was reacted with water, producing 470cm 3 of hydrogen
gas under room temperature and pressure.

2Na + 2H2O 2NaOH + H2


Na2O + H2O 2NaOH

The resulting solution was made up to a volume of 250cm 3 with water and a 25.0cm3 portion


of the final solution was exactly neutralized by 37.20cm3 of 0.056mol/dm3 of sulfuric acid.

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Calculate the percentage of Sodium Oxide and sodium Chloride in the sample.
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Q2) 0.12 g of rock salt (NaCl) was dissolved in water and titrated with 0.100 mol dm -3 silver
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nitrate until the first permanent white precipitate of silver chloride is seen. 19.7 cm3 of silver
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nitrate was required to remove all the chloride ion. What is the % purity of the rock salt?
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Q3) Magnesium hydroxide is only sparingly soluble. Assume that only 56% of it dissolves in
water.

a) Calculate the mass of Mg(OH)2 required to prepare a 250cm3 of solution containing


0.250 mol/dm3 of hydroxide ions.

b) How many (i) moles of sodium ions (ii) moles of Oxygen atoms and (iii) sulphate ions
(SO42-) are present in 250cm3 of 0.400 mol/dm3 of Na2SO4 solution?

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1 (GENIEius)
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Name:________________________ Date:_________________

Q4) Household bleach contains the active ingredient Hydrogen Peroxide (H 2O2). It
decomposes easily into oxygen gas and water.

a) Draw a dot and cross diagram of hydrogen peroxide and hence the structural formula.
b) 136g of bleach decomposes into 2.40dm3 of oxygen gas. Calculate the percentage
purity of hydrogen peroxide in the household bleach.

Q5) A sample containing ammonium sulphate was warmed with 250cm 3 of 0.800 mol/dm3
sodium hydroxide solution. After the evolution of ammonia has ceased, the excess sodium


hydroxide solution was neutralised by 85.0cm3 of 0.500 mol/dm3 hydrochloric acid.

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Assuming that the mass of the sample containing ammonium sulphate was weighed and
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found to be 10.85g, what is the percentage purity of the sample?
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Q6) 4.30g of an impure sample of ammonium chloride was warmed with 100cm 3 of 1.00
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mol/dm3 sodium hydroxide solution. The mixture was boiled until all the ammonia was
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driven off. The excess sodium hydroxide in the mixture required 50.0cm3 of 0.250 mol/dm3
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sulphuric acid to be neutralised. Calculate the percentage purity of the ammonium chloride
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sample.

Q7) A chloride of an unknown transition metal Z has the formula ZCl3 . 32.5g of ZCl3 solid
was added to the water to form an aqueous solution of ZCl3. It was found that 300cm3 of 2.00
mol/dm3 aqueous silver nitrate was required to precipitate all the chloride ions.

a. Determine the relative atomic mass of metal Z.


b. Identify metal Z

Written by Eugene Chew


2 (GENIEius)
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Name:________________________ Date:_________________

Q8) 6.45g of Sodium Thiosulfate Pentahydrate (Na2S2O3. 5H2O) is dissolved in water and
made up to 250cm3 in a volumetric flask.

a. Determine the concentration in g/dm 3 of thiosulphate ions in the solution.


b. 40cm3 of the solution is removed and transferred into a beaker and further made up
to 250cm3. What is the concentration in g/dm3 of thiosulphate ions in the new
solution?

*Q9) 3.00g of impure sodium metal is slowly added to a beaker containing 150cm3 of water.


The resulting sodium hydroxide solution is added to 50.0cm3 of 1.50 mol/dm3 dilute

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sulphuric acid solution. The mixture is then made up to 250cm3 in a volumetric flask by
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adding distilled water. 25.0cm3 of this solution requires 40.0cm3 of 0.100 mol/dm3
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potassium hydroxide solution for complete neutralisation.


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2Na + 2H2O 2NaOH + H2


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Determine the percentage purity of the sodium metal.


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Q10. A student can recall only the chemical formula of a mineral as K4Al6(SO4)a(OH)b , but
remembers that its empirical formula is K2Al3SO7H3.

a. What are the values of a and b?


b. What is the percentage of the number of carbon atoms and the percentage by mass of
carbon atoms in one molecule of glucose (C6H12O6)?
c. 6.00dm3 of as gas G2 has a mass of 8.00g at room temperature and pressure. What is
the relative atomic mass of G?

Written by Eugene Chew


3 (GENIEius)
Website: http://genieius.weebly.com
Name:________________________ Date:_________________

Q11) Aspirin has the molecular formulae C9H8O4.


a. How many moles of aspirin are there in 2.00g of this substance?
b. How many aspirin molecules are there in 1.74g of this substance?
c. What is the mass in grams of 1.00 x 1023 molecules of aspirin?
d. How many carbon atoms are there in one mole of aspirin?

Q12) 8.00g of a mixture of anhydrous sodium carbonate and sodium chloride was made up
to 500cm3 of aqueous solution. 25.0cm3 of this solution neutralized 10.0cm3 of 0.200
mol/dm3 hydrochloric acid.
Calculate the mass of sodium carbonate and sodium chloride present in the mixture.


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y.
Q13) Dilute acids react with most metals to produce a metal salt and hydrogen gas. When
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0.006 mole of metal W was added to an excess of a dilute acid, 144cm 3 of hydrogen gas was
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evolved. Which of the following shows the correct equation for the reaction?
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A. 2W + 2H+ 2W+ + H2
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B. 2W + 6H+ 2W3+ + 3H2


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C. W + 4H+ W4+ + 2H2


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D. W + 2H+ W2+ + H2
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Q14) Aqueous sodium hydroxide reacts with the solution of a certain metal chloride MClx to
form a precipitate of the metal hydroxide. Assume that 10.0cm3 of 6.00 mol/dm3 NaOH
solution was used to react exactly with 10.0cm3 of 3.00 mol/dm3 MClx solution. What is the
formula of the metal chloride?

Q15) A solution of dibasic acid with a concentration of 14.4g/dm 3 is titrated with a solution
of sodium hydroxide of concentration 0.200mol/dm3. It is found that exactly 30.0cm3 of
sodium hydroxide solution neutralises 25.0cm3 of the acid. What is the relative molecular
mass of the acid?
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4 (GENIEius)
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Q16) 37.5g of hydrated copper (II) sulfate, CuSO4 . 5H2O is dissolved in water and the
solution made up to 265cm3. From which 15cm3 of this solution was taken out. What is the
concentration of the 15cm3 solution with respect to the sulfate ion?

Q17) A 1.97g of an unknown metal carbonate, MCO3, reacts completely with 50.0cm3 of
0.400mol/dm3 hydrochloric acid. What is the relative atomic mass of M?

Q18) A compound contains 52% carbon, 13% hydrogen and 35% oxygen by mass. What is a
possible formula of the compound?


A. CH3COOH

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B. CH3OH
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C. HCOOH
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D. C2H5OH
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Q19. In an experiment conducted at room temperature and pressure, 5.00cm3 of gaseous


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hydrocarbon reacted with excess oxygen to form 30.0cm 3 of carbon dioxide and 15.0cm3 of
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water vapour. What is the formula of the hydrocarbon?


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Q20. What is the total number of ions and atoms in 500cm3 of 0.500mol/dm3 of
(NH4)2Cu(SO4)2, assuming that this compound is only 50% soluble in water.

Q21. 40.0 cm3 of aqueous 1.00mol/dm3 of the hydroxide solution of metal X neutralizes
exactly 80.0cm3 of 0.250mol/dm3 aqueous sulfuric acid. What is the formula of the sulfate of
X?

Written by Eugene Chew


5 (GENIEius)
Website: http://genieius.weebly.com
Name:________________________ Date:_________________

Q22. U3O8 is a catalyst, prepared by heating a uranium nitrate salt, UO2(NO3)2. This salt
decomposes quantitatively to give U3O8, NO2 and O2 only. How many moles of U3O8 are
produced from six moles of the salt?

Q23. A complex mixture of calcium compounds, proteins and other substance is known to
be present in human bone. When a bone is strongly heated in a generous supply of air, the
only residue left is calcium oxide. When a bone sample weighing 100g is strongly heated in
air, 28.0g of calcium oxide is obtained. What is the percentage by mass of calcium in the
sample of bone?

Q24. A solution is made by mixing 40.0cm3 of 0.200mol/dm3 NaOH with 60.0cm3 of 0.100


mol/dm3 HCl and 10cm3 of 0.15 mol/dm3 NH4Cl. What is the concentration of each of the

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compounds (NaOH, HCl & NaCl) in the resulting solution?
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Q25. Hydrated Iron (II) Sulfate crystals have the formula (FeSO4. xH2O). When 8.34g of
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iron(II)sulfate crystals were heated to dryness, its mass decreased until a constant mass of
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4.56g. What is the percentage by mass of water in the crystal?


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Q26. On analysis, 2g of a compound was found to contain 0.772g of potassium, 0.276g of


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nitrogen and 0.952g of oxygen. What is the empirical formula of the compound?
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Q27. 3.9g of an element X reacts with oxygen gas to form 4.7g of an oxide X2O. The relative
atomic mass of X is?

Q28. 150cm3 of gaseous hydrogen contains n atoms. How many atoms are there in 150cm 3
of gaseous carbon dioxide under the same conditions of temperature and pressure?

Q29. A sample of an oxide of Manganese is analysed and is found that 5.g of manganese has
combined with 5.6g of oxygen. What is the empirical formula of the oxide?

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6 (GENIEius)
Website: http://genieius.weebly.com
Name:________________________ Date:_________________

Q30. A solution of pure Na2CO3 contains 21.2g/dm3 of Na2CO3. We have 100cm3 of this
solution in a 1000cm3 flask. How much water must we add to dilute the solution to
0.04moles/dm3?

Q31 Blue hydrated copper (II) sulphate crystals have the formula CuSO4.xH2O, where x is the
number of molecules of 'water of crystallization'. If 3.33g of copper sulphate crystals where
heated at 150oC until the residue of anhydrous copper sulphate remained constant at 2.12g.

Calculate the value of x in the formula of the blue crystals.


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Q32. If 0.352g of hydrated sodium carbonate crystals, Na2CO3.xH2O, was titrated with 0.100
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mol dm-3 (0.100M) standard hydrochloric solution such that the titration value was 24.65
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cm3, deduce x, the number of molecules of water of crystallisation in washing soda crystals.
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Q33 On reaction with dilute hydrochloric acid, 0.428 g of a group 2 metal (M) formed 75.0
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cm3 of hydrogen gas. Deduce the atomic mass of the metal and identify it from the periodic
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table.
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Q34. 4.90g of pure sulphuric acid was dissolved in water, the resulting total volume was 200
cm3. 20.7 cm3 of this solution was found on titration, to completely neutralise 10.0 cm 3 of a
sodium hydroxide solution. Calculate the concentration of the sodium hydroxide in mol dm -3 .

Q35. A chloride of an unknown transition metal Z was added to a solution of 0.05M Silver Nitrate.
If 40cm3 of Silver Nitrate solution was completely neutralized by 44.44cm 3 of the metal chloride
of 0.015M, deduce the formula of the metal chloride. (ZCl 3)

Written by Eugene Chew


7 (GENIEius)
Website: http://genieius.weebly.com
Name:________________________ Date:_________________

*Q36. Methane gas can be partially oxidized by steam to form carbon monoxide and hydrogen
gas, according to this equation: CH4 (g) + H2O (g) CO (g) + 3H2 (g). If 70cm3 of methane was
ignited with 30cm3 of steam in a reaction vessel, and the reaction was allowed to complete.
Calculate the total volume of gas in the reaction vessel at the end of the reaction.
(Think of a quick way to solve this type of questions)

*Q37. Carbon Monoxide (CO) combust with oxygen gas, in a free radical reaction, to form
Carbon Dioxide. Draw the dot and cross diagram for carbon dioxide and describe a method to
test for this gas. State the pH value of this gas. If 40cm 3 of Carbon Monoxide were to be ignited
with 40cm3 of oxygen gas, calculate the volumes of oxygen gas, carbon monoxide and carbon
dioxide gas remaining after the reaction is completed.
(Think of a quick way to solve this type of questions)


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*Q38. Ozone reacts with nitric oxide in the lower atmosphere to form nitrogen dioxide
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according to this equation NO + O3 NO2 + O2. Explain why this reaction is considered a
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redox reaction in terms of the oxidation states. If 34.0cm3 of Nitric Oxide is combusted with
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16.0cm3 of Ozone, calculate the volume of nitrogen dioxide produced. Draw the dot and
cross diagram of nitrogen dioxide, hence state the structural formula of nitrogen dioxide.
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(Think of a quick way to solve this type of questions)


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Q39. 7.8g of element R reacts with oxygen to form 9.4g of an oxide, R2O. Calculate the relative
atomic mass of R.
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Q40. A mixture of Barium Chloride and Barium Nitrate with a total mass of 2.00g is dissolved in
water and treated with an excess of silver nitrate solution. The precipitate is dried and was found
to weigh 0.688g. What is the mass of the Barium Chloride in the original mixture?

Q41. What is the concentration of sodium ions when 35.0cm3 of 0.284 mol/dm3 of aqueous
sodium Sulphate and 45.0cm3 of 0.196 mol/dm3 of aqueous sodium nitrate are mixed?

Q42. If 30cm3 of gas X and 40cm3 of gas Y was mixed together in a flask, what would be the total
volume of gases remaining at the end of the experiment? Given the following equation:
2X (g) + 4Y (g) 3Z (g)

Written by Eugene Chew


8 (GENIEius)
Website: http://genieius.weebly.com
Name:________________________ Date:_________________

Answer Key

Q1) -
Q2) 96%
Q3) (3.24g, 0.200, 0.400, 6.02 x 1022)
Q4) 5%
Q5) 95.9g
Q6) 93.3%
Q7) a. 56 b. Iron
Q8) 1.87g/dm3
Q9) 84.3%


Q10) a. (a=2, b=6) b. (25%, 40%) c. (Ar=16)

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Q11) a. 0.011mol b. (5.8 X 1021 molecules) c. 30g d. (5.4 X 1024 atoms)
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Q12) (2.12g, 5.88g)
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Q13) D
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Q14) MCl2
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Q15) -
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Q16) 0.566mol
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Q17) -
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Q18) D
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Q19) C6H6
Q20) (3.76 X 1023, 1.58 X 1024)
Q21) (X2SO4)
Q22) 2
Q23) 20%
Q24) (NaOH 0.00455mol/dm3, NaCl 0.0682mol/dm3, HCl- 0)
Q25) 45.3%
Q26) KNO3
Q27) 39
Q28) 1.5n
Q29) Mn2O7
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Q30) 400cm3
Q31) x=5
Q32) 10
Q33) Barium
Q34) 1.035 mol/dm3
Q35) ZCl3
Q36) 160cm3
Q37) 60cm3
Q38) 16cm3
Q39) 39g
Q40) 0.499g


Q41) 0.359 mol/dm3

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Q42) 40cm3
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Written by Eugene Chew


10 (GENIEius)
Website: http://genieius.weebly.com

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