11/11/2014 sodium carbonate

Standard Reference Data Chemistry

Data Program Gateway WebBook

sodium carbonate
Formula: CNa2O3
Molecular weight: 105.9884
CAS Registry Number: 497-19-8
Information on this page:
Condensed phase thermochemistry data
References
Notes / Error Report
Other data available:
Reaction thermochemistry data
IR Spectrum
Data at other public NIST sites:
X-ray Photoelectron Spectroscopy Database, version 4.1
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Condensed phase thermochemistry data

Go To: Top, References, Notes / Error Report

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment

fHliquid -1108.51 kJ/mol Review Chase, 1998 Data last reviewed in March, 1966
Quantity Value Units Method Reference Comment
Sliquid,1 bar 156.41 J/mol*K Review Chase, 1998 Data last reviewed in March, 1966
Quantity Value Units Method Reference Comment
fHsolid -1130.77 kJ/mol Review Chase, 1998 Data last reviewed in March, 1966
Quantity Value Units Method Reference Comment
Ssolid 138.79 J/mol*K Review Chase, 1998 Data last reviewed in March, 1966
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11/11/2014 sodium carbonate

Liquid Phase Heat Capacity (Shomate Equation)

Cp = A + B*t + C*t2 + D*t3 + E/t2

H H298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 E/t + F H
S = A*ln(t) + B*t + C*t2/2 + D*t3/3 E/(2*t2) + G
Cp = heat capacity (J/mol*K)
H = standard enthalpy (kJ/mol)
S = standard entropy (J/mol*K)
t = temperature (K) / 1000.

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Temperature
1123.15 - 2500.
(K)
A 189.5350
B -0.000007
C 0.000002
D -5.20510010-9
E -0.000003
F -1183.060
G 342.9690
H -1108.510
Reference Chase, 1998
Data last
Comment reviewed in
March, 1966

Solid Phase Heat Capacity (Shomate Equation)

Cp = A + B*t + C*t2 + D*t3 + E/t2

H H298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 E/t + F H
S = A*ln(t) + B*t + C*t2/2 + D*t3/3 E/(2*t2) + G
Cp = heat capacity (J/mol*K)
H = standard enthalpy (kJ/mol)
S = standard entropy (J/mol*K)
t = temperature (K) / 1000.

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View table.

Temperature
298. - 723. 723. - 1123.
(K)
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A 175.2010 -1067.000
B -348.0580 2469.340
C 743.0720 -1829.060
D -305.5510 505.7480
E -1.634221 100.1820
F -1178.980 -607.1240
G 415.0610 -1356.440
H -1130.770 -1130.770
Reference Chase, 1998 Chase, 1998
Data last Data last
Comment reviewed in reviewed in
March, 1966 March, 1966

References
Go To: Top, Condensed phase thermochemistry data, Notes / Error Report

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data,
Monograph 9, 1998, 1-1951. [all data]

Notes / Error Report

Go To: Top, Condensed phase thermochemistry data, References

Symbols used in this document:

Sliquid,1 bar Entropy of liquid at standard conditions (1 bar)

Ssolid Entropy of solid at standard conditions
fHliquid Enthalpy of formation of liquid at standard conditions
fHsolid Enthalpy of formation of solid at standard conditions

Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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11/11/2014 sodium carbonate

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