Escolar Documentos
Profissional Documentos
Cultura Documentos
14 (2013), 7753-7757
http://dx.doi.org/10.14233/ajchem.2013.14595
ISSAM A. LATIF1,*, HILAL M. ABDULLAH1, SUNDUS H. MARZA1, AMMAR H. AL-DUJAILI1 and EMAD T. BAKIR2
1
Department of Chemistry, College of Education, Ibn Al-Haitham, University of Baghdad, Baghdad, Iraq
2
Department of Chemistry, College of Science, University of Tekrit, Tekrit, Iraq
Poly 4-methyl benzylidene vinyl alcohol [poly(vinyl acetal)] was prepared and characterized with IR spectroscopy and the melting point
measured, ZnO nanoparticles were prepared and with AFM and XRD characterized, studied and the nanoparticles size measured. Poly
(vinyl acetal)/PVA composite were prepared by ultrasonically mixing with different ZnO nanoparticles per cent. Each mixture was
fabricated in film and casted in 5 cm 5 cm glass caste. The real and imaginary dielectric permittivity and electric modulus were for the
prepared films studied.
Key Words: ZnO nanocomposite, Polymer nanocomposite dielectric constant, ZnO nanoparticles.
Recently, the polymer inorganic nanocomposites with 6000) with copper radiation (CuK, 1.5406 ), the prepared
high dielectric permittivity have been considered to be potential nanoparticles size and morphology were also observed with
candidates for integration into electronic devices. Owing to atomic force microscopy (AFM) and scanning electron
the continuous development towards the miniaturization of microscope (SEM).
electronics, newer dielectric materials were sought which Synthesis of poly 4-methyl benzyledene vinyl alcohol
would enable to achieve high energy density for capacitor (poly(vinyl acetal)) compound: All chemicals used in the
applications. Ceramics possessing high dielectric permittivity preparation are from Sigma-Aldrich. The preparation proce-
are being used as voltage capacitors due to their high breakdown dure of poly(vinyl acetal) compound was based on the work
voltages. However, they are brittle, suffer from poor mechanical of Sakurada25. PVA (Mw = 12000 g, 0.5 g) and 4-methyl benzal-
strength and hence cannot be exposed to high fields. Polymer dehyde (10 mmol, 12 g) was dissolved in mixture of benzene
films such as polyester, polycarbonate, polypropylene, poly- (24 mL) and ethanol (6 mL) with 2 drops of HCl. the reaction
styrene, polyethylene sulphide and polyvinyl acetal11 are mixture was left stirring vigorously at (40-50 C) for 24 h the
being used in the fabrication of low leakage capacitors. Though solution was poured into excess of methanol (100 mL) conta-
polymers possess relatively low dielectric permittivity, they ining equimolar amount of NaOH, the product was separated
can withstand high fields, are flexible and easy to process. By by filtration and then washed with methanol and dried in
combining the advantages of both, one can fabricate new vacuum. The yield of the product was 80 %.
hybrid materials with high dielectric permittivity and high
breakdown voltages to achieve high volume efficiency and HC
O
energy storage density for applications in capacitors as electric
H
H2 H C CH3
C C + H 3C CH H2C O
energy storage devices12-15. This study aims the achievement
CH
OH O
n
of ZnO nanostructures in the reaction temperature of 70 C by
the solochemical method using zinc nitrate hexahydrate and Poly 4-methyl benzyledene vinyl alcohol
sodium hydroxide. The product obtained was characterized
by X-ray diffraction (XRD) technique method. The morphology Poly 4-methyl benzyledene vinyl alcohol -PVA with
and size of the ZnO was investigated with AFM and SEM. ZnO nanocomposites film fabrication: Four polymer compo-
Among the nanomaterials with industrial relevance stands out site films were prepared and the composition percentage are
zinc oxide, an n type semiconductor that displays a hexagonal shown in Table-1, each portion dissolved in 20 mL DMF and
crystalline Wurtzite-type structure, with space group P63 mc mixed completely under constant stirring for 1 h while the
and lattice parameters of a = b = 0.3250 nm and c = 0.5207 mixture was heated up till 50 C then the mixture was let to
nm16. The importance of ZnO is due to its unusual physical cool down to room temperature (24 C) with stirring of the
properties such as high conductance, chemical and thermal mixture was carried out to ensure a homogenous composition.
stability17, wide and direct band gap of 3.37 eV18 and a high
excitation binding energy of 60 M eV19. Moreover, it has good TABLE-1
radiation resistance20 and is harmless to the environment21. The COMPOSITIONS OF THE PREPARED FILMS
ZnO nanostructures has great potentiality for being used in Film Poly(vinyl PVA ZnO g
No. acetal) (g/film) (g/film) (%/film)
preparing solar cell, acoustic, electrical and optical devices,
1 0.166 0.0 0.00
chemical sensors22, catalysts, pigments, cosmetics, varistors 2 0.166 0.2 1.71
and gas sensors23. 3 0.166 0.2 2.81
EXPERIMENTAL 4 0.166 0.2 3.79
10.00 nm
500 nm
5.00 nm
0 nm 0 nm
0 nm
500 nm
1000 nm
1500 nm
2000 nm
2500 nm
Fig. 2. (a) Represent the AFM 2-D image with maximum high (40 nm) of
the ZnO nanoparticles
4000 3000 2000 1800 1600 1400 1200 1000 800 600
Wavelength (cm1)
Fig. 1. IR spectrum of poly-4-methyl benzyledene vinyl alcohol
18000 5
Film No. 1
Film No. 2
16000
4 Film No. 3
Film No. 4
14000
3
(101)
12000
Intensity
10000 2
(100)
8000 0
(002)
(103)
(112)
4000 concentration of ZnO nano particles
(102)
(213)
(200)
2000
exists in heterogeneous dielectric materials and is produced
0
by the traveling of charge carriers28. In order to study the
20 30 40 50 60 70 80 frequency and the different concentrations of fillers depen-
2 ()
dence of relaxation processes, effective permittivity was used
Fig. 3. XRD pattern of ZnO nanoparticles powder
Figs. 4 and 5 shows the real and imaginary part of permittivity,
respectively obtained through eqns. 1-3.
1
= M + M
M* = (5)
* 4
where M' and M" are the real and imaginary part of dielectric
modulus and was calculated by eqns. 6 and 7: 3
Film
Film
No.
No.
1
2
M = (6) Film No. 3
2 + 2 2 Film No. 4
M = (7)
1
+ 2 2
Film No. 4
2E-3 REFERENCES
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0
2.0 2.5 3.0 3.5 4.0 4.5 5.0 5.5 2. M. Kozako, R. Kido, N. Fuse, Y. Ohki, T. Okamoto and T. Tanaka,
log Hz IEEE Conf. Electr. Insul. Dielectr. Phenomena, pp. 398-401 (2004).
Fig. 6. Real dielectric modulus of PVA-poly acetal composite at different 3. B.J. Ash, R.W. Siegel and L.S. Schadler, J. Polym. Sci. B, 42, 4371
concentration of ZnO nano particles (2004).
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Film No. 1 pp. 295-298 (2002).
4E-4 Film No. 2
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Film No. 3
Film No. 4
and R. Mulhaupt, IEEE Trans. Dielectr. Electr. Insul., 11, 754 (2004).
M