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0 AIM
The aim of this experiment is to measure the rate constant of the reaction between
ethyl acetate and sodium hydroxide under batch condition.
3.0 INTRODUCTION
Chemical processes may be categorized into three main groups that are batch,
continuous or semibatch process; and as either steady-state or transient operation. In batch
process, the inputs are fed to a vessel before starting the process and the outputs are removed
when the process has completed. As for continuous process, the input and output flow
constantly throughout the process. On the other hand, semibatch process is any process that is
neither batch nor continuous process. A process is said to be in steady-state when the process
variable do not change with time. On the contrary, transient or unsteady-state operation is
when any of the process variable change with time (Richard M. Felder,).
This experiment aims to calculate the rate constant for the saponification reaction
between ethyl acetate and sodium hydroxide under batch condition. It is believed, the rate
constant can be determined using two methods which are the integrated rate law method and
the half-life method.
This experiment is conducted to calculate the rate constant from the saponification
process of the reaction between ethyl acetate (ester) and sodium hydroxide (lye) under batch
condition. By definition, saponification is a process where triglycerides react with sodium or
potassium hydroxide (lye) to produce glycerol and a fatty acid salt, called 'soap'. Specifically
in this experiment; ethyl acetate acts as the triglyceride, reacts with sodium hydroxide to
produce sodium acetate (soap) and ethanol (byproduct). The mechanism of saponification can
be showed from Figure 1.
During the saponification process, sodium hydroxide reacted with ethyl acetate and is
continuously consumed. When acid is added to the sample from the product of
saponification, the sample become an acidic solution. This is because the excess hydrochloric
acid will first react with unconsumed sodium hydroxide in the sample to neutralize the
solution and thereby halted any further reaction of ethyl acetate. Phenolphthalein is added to
the solution as an indicator. By using the method of titration to neutralize the acidic solution,
the volume and concentration of sodium hydroxide needed for the neutralization process can
be known. It can be said that the volume of sodium hydroxide needed to change the
colourless colour of solution to pink indicates the amount of ethyl acetate concentration. To
relate sodium hydroxide and ester in the original sample, the following formula can be used.
A+B C
r = k [A]m[B]n
where:
r = rate
k = rate constant
A = concentration of substance A
B = concentration of substance B
m and n = order of the reaction
Rate constant (k) quantifies the speed of a chemical reaction and can be
acknowledged as rate of reaction when the concentration of each reaction is taken as unity. It
can be said that the greater the value of the rate constant, the faster the reaction. Each reaction
has the same value of the rate constant at a particular temperature. The value of the rate
constant for the same reaction changes with temperature as rate constant depends on
temperature. Besides, the rate constant value does not depend on the concentration of reaction
but depend on the order of reaction. There are two ways of calculating rate constant which
are the integrated rate law method and using the half life method. Also, different order of
reaction has different styles of calculating the rate constant.
The order of reaction is the exponent to which the concentration of the reactant is
raised, and it shows to what extent the concentration of a species affects the rate of a reaction,
as well as which species has the greatest effect on the rate of the reaction. Orders of reaction
for each reactant are often positive integers, but they may also be zero, fractional, or negative.
As an example, if a reaction rate depends on a single reactant and the value of the exponent is
one, then the reaction is said to be first order. A reaction is said to be second order when the
overall order is two. The rate of a second-order reaction may be proportional to one
concentration squared or to the product of two concentrations. For zero-order reactions,
the reaction rate is independent of the concentration of a reactant, so that any changes in the
concentration has no effect on the speed of the reaction.
Integrated rate law method for each order of reactions is different and can be show
from the following equations. Firstly, for zeroth order reactions:
Rate = k [A]
[]
Differential rate law; =0
The graph for zeroth order of reaction should shows a negative gradient.
Rate = k [A]
[]
Differential rate law; = k[A]
[]
Integrated rate law; ln [] = -kt
0
The plot for first order reaction will produce a straight line.
Lastly for second order of reaction, the ways of expressing the rate law is depending
on the reactants. As example for the reaction between reactant A and reactant B:
Rate = k [A][B]
[] []
Differential rate law; = = k[A][B]
1 1
Integrated rate law; [] - [] = kt
0
[]0
Zero order reaction, 1/2 = 2
ln 2
First order reaction, 1/2 =
1
Second order reaction, 1/2 = []
0
1. https://www.thoughtco.com/definition-of-saponification-605959
2. http://www.wikipremed.com/03_organicmechanisms.php?mch_code=030209
_080
3. https://en.wikipedia.org/wiki/Le_Chatelier%27s_principle
4. http://www.scihub.org/AJSIR/PDF/2015/1/AJSIR-6-1-1-4.pdf
5. https://chem.libretexts.org/Core/Physical_and_Theoretical_Chemistry/Kinetic
s/Rate_Laws/The_Rate_Law/Reaction_Order
6. https://en.wikipedia.org/wiki/Order_of_reaction
7. https://chem.libretexts.org/Core/Physical_and_Theoretical_Chemistry/Kinetic
s/Experimental_Methods/Using_Graphs_to_Determine_Integrated_Rate_Law
s
8.