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electron in 3 orbit is nearly:
(A) 2x (B) 6x
x
(C) 9x (D)
3
3h
Solution: mvr3 =
2
9 x 3h h
mv = mv =
1 2 6x
h
= = 6x
mv
(B)
Solution: Since s-orbital is spherically symmetrical and has equi-distance from the
nucleus. Hence the probability is identical
(A)
+ +2 +2
(a)He (b)Li (c) Deuterium (d) Be
Solution: Be+2 contains two electrons, rest all contain one electron each.
5. Which of the following curves may represent the speed of the electron in a hydrogen atom as
a function of principal quantum no. n.
Ans: (C)
Speed of an electron is inversely proportional to n. So, vxn = constant, resulting in a
rectangular hyperbola
6. Photoelectric emission is observed from a surface for frequencies v, and v2 of the incident
radiation (where v1 v2). If the maximum kinetic energy of the photoelectrons in two
cases are in the ratio of 1:k, then the threshold frequency v0 is given by
v v2 Kv 1 v 2
(A) 1 (B)
K 1 K 1
Kv 2 v1 v 2 v1
(C) (D)
K 1 K
Ans: (B)
Use Einsteins P.E. Equation, K.E = hv - hv0 for both the cases. Then solve.
Ans: (C) While both Cu & Ag have a pseudo noble gas configuration (ns 2 np 6 nd 1 0 ),
Cu has a smaller size than Ag hence, Cu + > Ag +
8. Among the following MgCl 2 , NaCl, Na 2 S, MgS, the compounds having the
least melting point and the highest melting point are respectively:
(A) MgS & NaCl (B) NaCl & Na 2 S
(C) MgCl 2 & NaCl (D) NaCl & MgS
Ans: (A) Higher the ionic nature of the bond, higher will be the melting point. MgS
has the highest polarization while NaCl has the least.
Ans: (A) Larger the size of the anion, greater is its polarisability.
O has two lone pairs while N has one, hence B.A. of NH 3 is greater than H 2 O
F is more electronegative than O, hence the bp -bp repulsion is less than in case of
H 2 O. Hence, B.A. of H 2 O is greater.
P has a lp, hence its B.A. is less than methane
While O has 2 lps in Cl 2 O, Cl has three electrons in ClO 2
Ans: C
Similar logic as that of Q. 14
For Questions, 16 to 18, read the passage given below:
The valence bond theory was the first quantum mechanical theory of bonding to be
developed, and can be regarded as a way of expressing Lewis concepts in terms of wave
functions.
In valence bond theory, the wave function of an electron pair is formed by superimposing
the wave function for the separated fragments of the molecule. And, the shape of the
molecule depends on the orientation of the hybridized orbitals.
16. The maximum number of combinations of atomic orbitals that are possible in the valence
shell of C-atom is
(A) 4 (B) 3 (C) 2 (D) 1
Ans: (A)
Carbon by excitation of its electron can create 4 orbitals that contain 1 electron each
leading to covalent bonding.
(A) 1 only (B) 1 & 3 only (C) 2 &3 only (D) 1 & 2 only
Ans: (A)
Sulphur has 1 lp and forms 3 sigma bonds. This leads to Trigonal pyramidal structure.
21. Which of the following option is correct? [State T for true and F for false ]
(I) Dipole moment is a vector quantity, i.e. it has both magnitude as well as
direction.
(II) CO 2 is non polar because its dipole moment 0
(III) Generally in any molecule, if bond angle increases, then dipole moment
will be also increase
(IV) We can determine percentage ionic character with the help of dipole
moment
(A) TTFF (B) TFFT (C) FFTT (D) FTTF
Ans: B
Glenn Theodore Seaborg was an American chemist whose involvement in thesynthesis, discovery
and investigation of ten transuranium elements earned him a share of the 1951 Nobel Prize in
Chemistry. His work in this area also led to his development of the actinide concept and the
arrangement of the actinide series in the periodic table of the elements. He was also the only person
after whom an element was named while the person was alive.
Assuming that in the time to come, students reading this question paper now became scientists who
would discover newer elements and come up with path-breaking theories, the periodic table would
change as compared to what it looks today.
So, how many elements would there be in the periodic table if:
22. There were 8 periods and the 8 t h period was completely full
Ans: (C) 2,8,8,18,18,32,32 these are the number of elements in the first seven periods.
The next term would be 50. Hence the number of elements would be 118+50 = 168
Ans: Total elements in s -block = 14, p-block = 36, d block = 40, f -block = 28
Now, the elements where m has non -negative values are all s -block (14), 2/3 of p -block
(24), 3/5 of d-block (24) and 4/7 of f -block (16) = 78
In each of the above questions, assume you start with 118 element s (as it exists in the
current version of the periodic table).
26. Two ice cubes when pressed, unite to form one cube. Which force is responsible for holding
them together :
(A) van der Waals forces (B) Covalent attraction
Ans: (C)
27. The nodal plane in the -bond of ethene is located in
(A) the molecular plane
(B) a plane parallel to the molecular plane
(C) a plane perpendicular to the molecular plane which bisects, the carbon-carbon bond
at right angle.
(D) a plane perpendicular to the molecular plane which contains, the carbon-carbon bond.
Ans: (A) -bonds are perpendicular to the molecular plane. Hence their nodal plane will be
located in the molecular plane.
28. The decreasing size of K+, Ca2+, Cl & S2 follows the order:
(A) K+ > Ca+2 > S2 > Cl (B) K+ > Ca+2 > Cl > S2
(C) Ca+2 >K+ > Cl > S2 (D) S2 > Cl > K+ > Ca+2
Ans: Each of these have the same number of electrons. The radius will be the smallest in the ion
where the number of protons is the highest. Hence, D
Directions: The questions below to consist of an assertion in column-1 and the reason in
column-2. Against the specific question number, write in the appropriate space.
(A) If both assertion and reason are CORRECT, and reason is the CORRECT explanation
of the assertion.
(B) If both assertion and reason are CORRECT, but reason is not the CORRECT
explanation of the assertion.
(C) If assertion if CORRECT but reason is INCORRECT
(D) If assertion is INCORRECT reason in CORRECT.
Q.29 Assertion: F atom has a less negative electron gain enthalpy than Cl atom.
Reason: Additional electron is repelled more efficiently by 3p electron in Cl atom than
by 2p electron in F atom.
Ans: A
Q.30 Assertion: Al(OH)3 is amphoteric in nature.
Reason: Al O and O H bonds can be broken with equal ease in Al(OH)3.
Ans: A