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Summary
This work presents the results of an investigation of bbl/MMcf. The performance of each of these
the economic feasibility of using cryogenically reservoir fluid systems has been evaluated assuming
produced nitrogen as a substitute for natural gas to three different degrees of reservoir heterogeneity.
mairtain reservoir pressure during cycling operations Performance and economic projections have been
in gas-condensate reservoirs. Those economic factors made assuming three different depletion methods: (1)
unique to nitrogen cycling are discussed. It has been pressure depletion with no injection, (2) pressure
concluded that gas reservoirs with a condensate maintenance by nitrogen injection, and (3) pressure
content in excess of 100 bbl/MMcf should be con- maintenance by return of residue gas and purchase of
sidered as potential nitrogen cycling prospects. makeup gas. Multiple projections have been made
for the injection cases assuming blowdown of the
Introduction reservoir is initiated at various times, starting with
Historically, gas-condensate reservoirs which exhibit breakthrough of dry gas. Performance and economic
liquid loss through retrograde condensation with results are presented for those cases which produce
reduction in reservoir pressure have been depleted the maximum income discounted at a rate of 15070 per
under a full or partial pressure maintenance program year. Economic evaluations were made assuming
by injection of dry natural gas. The technology to prices and costs escalate at a rate of 6070 per year.
evaluate and accomplish this is available and well
proved. The increased value and the shortage of Projections of Performance
natural gas, however, has made it generally Reservoir Description
uneconomic to divert this gas from the sales line to To make an economic evaluation of cycling a gas-
injection for the purpose of maintaining pressure in condensate reservoir with nitrogen, it was necessary
gas-condensat, reservoirs. to obtain projections of reservoir performance. It
This paper is concerned with the economic was our desire to evaluate the effect of different
feasibility of using cryogenically produced nitrogen reservoir fluid compositions and degrees of reservoir
as a substitute for natural gas to maintain reservoir heterogeneity upon the economic potential of this
pressure during cycling operations in gas-condensate depletion mechanism. To isolate these effects, per-
reservoirs. Many factors affect the economics of a formance projections were made on a hypothetical
gas cycling project. Generally, the three most im- reservoir whose properties are shown in Table 1.
portant factors are prices, stock-tank liquid content The hypothetical field contained six contiguous
of the reservoir gas, and the degree of reservoir five-spot patterns of 360 acres each. This resulted in a
heterogeneity. conforming area under injection operations of 2,160
For the purpose of this evaluation, a hypothetical ,!cres or 75070 of the total field area. In all injection
reservoir has been defined. Projections of per- cases investigated there were six injection and 12
formance have been made assuming the reservoir producing wells. Under pressure depletion it was
contains three different reservoir fluids with stock- assumed that there were 18 producing wells.
tank liquid contents ranging from 76.1 to 220.7
'Now with Core Laboratories Canada Ltd.
Reservoir Fluid Properties
0149213618110002 7494$00.25
The compositions and basic properties of the three
Copyright 1981 Society of Petroleum Engineers of AIME reservoir fluids investigated are presented in Table 2.
FEBRUARY 1981 263
TABLE 1 - BASIC RESERVOIR PROPERTIES TABLE 2 - RESERVOIR FLUID COMPOSITIONS
AND PROPERTIES
Average depth, ft 10,000
Initial reservoir pressure, psia 4,475 Fluid
Reservoir temperature, F 194 A B C
Total field area, acres 2,880
Average thickness, ft 50 Composition, mol %
Average porosity, % 19.8 Nitrogen 0.37 0.42 0.46
Average water saturation, % 34.9 Carbon dioxide 0.57 0.59 0.61
Hydrocarbon pore volume, MMbbl 144.0 Methane 59.39 64.43 68.64
Ethane 13.78 13.82 13.90
Fluid Propane 7.58 7.24 6.89
Isobutane 0.79 0.73 0.66
A B C n-butane 3.28 2.98 2.66
Original volumes in place Isopentane 0.84 0.74 0.62
Gas, Bcf 200.506 208.307 212.300 n-pentane 1.31 1.13 0.94
Condensate, MMbbl 44.252 28.871 16.150 Hexanes 1.80 1.48 1.14
Heptanes plus 10.29 6.44 3.48
100.00 100.00 100.00
~LUID"S"
u bbl/MMscf 220.7 138.6 76.1
2:
2:
......
Maximum retrograde liquid,
~.
en vol% 42.2 21.8 8.3
...J
~ 100
/
./ FLUID C
Plant recovery efficiencies, %
V Propane 75
~ Butane 90
o Pentanes plus 100
\
"""FLUID "s"
Q..
/" psia, respectively. Physical properties of these two
fluids were obtained in the same manner as described
---
10 for Fluid A. The three fluids exhibited stock-tank
\ contents of 220.7, 138.6, and 76.1 bbllMMcf at their
"'1\
FLUID"C"
respective dewpoint pressures. Fig. 1 describes the
o retrograde behavior and stock-tank liquid content of
o 1000 2000 3000 4000 500C
the three fluids investigated as a function of reservoir
RESERVOIR PRESSURE, psig
pressure.
The effect of both displacing and mixing a
Fig. 1 - Stock-tank liquid content and retrograde liquid
saturation. hydrocarbon gas with nitrogen is the subject of a
paper by Moses and Wilson. 2 The results of
laboratory tests presented by these authors confirm
that an elevation in dewpoint pressure with resulting
retrograde condensation will occur when nitrogen
and a rich gas condensate are mixed. These same
phenomena occur to a lesser degree when a lean gas is
mixed with a rich gas condensate. This retrograde
loss will occur, however, only in those areas where
the two gases contact each other. The mixing volume
during the nitrogen injection phase of the cycling
program should be small in reservoirs normally
considered conducive to a cycling program. The
major mixing of the two gases will occur during the
264 JOURNAL OF PETROLEUM TECHNOLOGY
100
blowdown phase of the operation when retrograde 80
normalities associated with the high and low ends of Fig. 2 - Vertical stratification factor.
the permeability distribution. Average permeabilities
over lO-percentile ranges were selected for
calculation of recovery and dry gas cut as a function pressure depletion with no injection, (2) pressure
of pore volumes injected. An example distribution maintenance with nitrogen injection, and (3) pressure
for a ratio of 20 is presented in Fig. 2. In this in- maintenance with residue and makeup gas injection.
vestigation maximum/minimum permeability ratios It was assumed in all cases that a natural gas
of 5, 10, and 20 were used to describe the reservoir processing plant would be available from the start of
heterogeneity from slight to relatively severe. production with a capacity of 33.0 MMcflD of inlet
feed gas. Total producing and injection rates were
Performance Calculation Method limited by this plant capacity.
The object of this investigation was to evaluate the The two pressure maintenance depletion systems
economic potential of a process and some of the were evaluated assuming various times for the
factors which influence the economics of the process. commencement of blowdown for all three of the
For this purpose a material balance computer degrees of heterogeneity previously described.
model was used to make the performance Summaries of total project life recoveries for those
calculations. The aerial sweep as a function of pore cases which yielded the greatest discounted net
volumes injected is input data for the computer working interest income are presented in Table 3.
program. The data used in this paper was for a five- When cycling with residue gas, the most ad-
spot pattern assuming a mobility ratio of one as vantageous time to commence blowdown was at the
presented by Dyes et al. 3 The vertical displacement time of dry gas breakthrough in all cases using Fluids
efficiency was calculated in the computer program by Band C. Only with Fluid A was it profitable to cycle
the method proposed by Muskat 4 assuming an with residue gas beyond the time of breakthrough.
exponential permeability distribution as previously In the nitrogen injection cases the Fluid A and B
described and a mobility ratio of one. systems with heterogeneity indices of 5 and 10 ob-
This model permitted us to make many repetitive tained their maximum profitability when blowdown
calculations of performance varying the fluid was delayed to some point beyond the breakthrough
properties, degrees of heterogeneity, and time at of dry gas. All other nitrogen injection cases in-
which the initiation of blowdown occurred. This dicated maximum profitability when blowdown was
material balance model calculated well stream flow initiated when breakthrough occurred.
rates, dry gas cut, separator gas rates, plant residue These observations indicate that cycling becomes
and sales gas rates, condensate and plant yields, less attractive economically as the reservoir fluids
volumes injected, and reservoir pressure as a func- investigated become leaner and as the reservoir
tion of time. becomes more heterogeneous. This axiom has been
When the scope of the investigation is reduced to with the industry for some time.
the evaluation and design of a specific project, a
more sophisticated mathematical model could and Economic Projections
should be used. The economic factors used in making the economic
evaluations of the projections summarized in Table 3
Performance Projection Results fall into two categories. These categories are those
Performance projections were made for each of the items peculiar to nitrogen injection and basic
three reservoir fluid systems previously described economic parameters common to all gas injection
assuming three different depletion methods: (1) operations. These are discussed separately for clarity.
FEBRUARY 1981 265
TABLE 3 - SUMMARY OF PERFORMANCE PROJECTIONS
Product Recovery at
Economic Limit Makeup
Cycling Project Abandonment Sales Plant Gas Percent Recovery
Life Life Pressure Gas Condensate Products Injected Reservoir
Case Identification (years) (years) (psia) (Bcf) (MMbbl) (MMbbl) (Bcf) Gas Condensate
------ ... -~- -~- ------- -- .. _--
Fluid A
Pressure depletion 0 24 932.0 115.5 7.0 7.7 0.0 66.0 15.8
R=5
Nitrogen injection 20 35 1,256.1 138.8 35.7 11.3 239.8 90.0 80.8
Residue gas injection 8 33 908.6 138.7 27.3 10.5 30.3 83.3 61.7
R=10
Nitrogen injection 19 36 1,162.3 134.5 32.4 10.8 227.6 86.3 73.3
Residue gas injection 7 32 904.3 135.7 23.9 10.0 25.8 78.9 54.1
R=20
Nitrogen injection 16 36 1,044.2 127.6 28.4 10.2 191.7 81.0 64.2
Residue gas injection 6 31 900.1 132.7 21.0 9.4 21.9 75.2 47.5
Fluid B
Pressure Depletion 0 25 910.5 132.0 7.7 8.9 0.0 72.6 26.6
R=5
Nitrogen injection 12 31 1,039.9 155.0 21.1 11.5 132.6 90.0 73.0
Residue gas injection 6 31 887.8 144.3 17.2 10.9 15.4 85.4 59.5
R= 10
Nitrogen injection 7 31 961.9 148.1 16.8 10.7 76.5 84.7 58.3
Residue gas injection 5 30 886.6 142.4 15.3 10.4 12.8 81.5 53.0
R=20
Nitrogen injection 4 31 932.5 143.3 13.7 10.1 43.5 80.9 47.3
Residue gas injection 4 29 885.0 140.4 13.7 9.9 10.2 78.4 47.4
FluidC
Pressure Depletion 0 26 868.2 146.0 7.2 9.7 0.0 78.3 44.7
R=5
Nitrogen injection 7 30 946.9 166.3 11.4 11.6 71.3 90.5 70.8
Residue gas injection 7 32 862.1 154.8 11.6 11.8 11.3 89.5 71.7
R=10
Nitrogen injection 6 32 911.7 161.4 10.5 11.2 61.2 87.7 65.2
Residue gas injection 6 31 861.9 153.5 10.6 11.3 9.6 85.7 65.9
R=20
Nitrogen injection 5 32 906.3 157.1 9.8 10.9 51.0 85.2 60.7
Residue gas injection 5 30 861.7 152.3 9.9 10.8 8.0 82.9 61.2
NITROGEN
16.5; /MCF ELECTRIC
POWER
@U/KWH
25e /MCF
10
10 20 30 40 ~o 6p
-
80 100
NITROGEN VOLUME - MMSCFO
applications are in remote locations, it is important The nitrogen rejection facility has three major
that potential users evaluate this cost component components:
carefully. Pretreating. H 2 S- and water-removal requirements
Fig. 4 shows approximate costs for nitrogen at low are similar to those for LPG plants. The level of
pressure and at 5,000 psig for an all-electric plant. carbon dioxide that can be tolerated in the nitrogen-
When using this figure, it is important to keep in rejection cold box is dependent on the hydrocarbon
. mind these parameters (1) power - excluded from composition of the feed stream. The level is generally
cost curves (see text), (2) purity-99.995OJo nitrogen lower than that required for LPG plants.
with all water vapor removed, (3) production rate-
100% of capacity, and (4) cost basis-Oct. 1978. Nitrogen-Rejection Cold Box. In this unit the
The nitrogen costs used in this investigation ranged feedstream is cooled down to the liquefaction
from $0.5121Mcf for a cycling period of 4 years to temperature of the gas mixture before entering the
$0.450/Mcf for cycling periods of 16 years or
distillation column, where it is distilled against a
liquid nitrogen reflux. In nitrogen rejection plants
greater. These figures include the cost of compressing
designed for cycling projects, a double distillation
nitrogen to an injection pressure of 5,000 psi.
column normally is used to permit the cold box to
Nitrogen Rejection handle a wide range of nitrogen concentrations. A
turbo expander uses the energy in part of the process
Like nitrogen generation, the rejection of nitrogen
stream to provide refrigeration for the process. A
from a produced gas stream after breakthrough
liquid methane pump normally is used to minimize
employs a specialized cryogenic technology. This
the product recompression requirements. Product
section will describe briefly the basic process of
and waste streams are reheated to appropriate
nitrogen rejection and the factors that affect its cost.
temperatures before leaving the cold box. An ef-
Unlike nitrogen production, nitrogen rejection
usually is accomplished most economically if the ficient nitrogen rejection unit will recover 99% of the
field operator owns and operates the nitrogen methane and essentially all heavier hydrocarbons.
rejection facility, although it can be accomplished as Recompression. The pressure of the sales gas stream
a processing service provided by outside suppliers. as it leaves the nitrogen-rejection cold box varies with
The primary reason for this is that the nitrogen the concentration of nitrogen in the feed gas stream.
rejection plant must be integrated fully into existing As the nitrogen concentration in the feed increases,
or planned gas processing facilities to be fully cost the pressure at which the sales gas is produced may be
effective. Much of the feed pretreatment necessary increased. For example, in the analysis used in this
for nitrogen rejection frequently is required for paper, at 10% nitrogen the suction pressure to the
propane or ethane recovery systems. Furthermore, sales gas booster compressors is 62 psia, while at 500/0
the extremely low temperatures required for nitrogen nitrogen the pressure had increased to 200 psia.
rejection mean that propane and ethane recovery can
be accomplished within the nitrogen rejection unit. Factors Affecting Cost of Nitrogen Rejection
The basic process in nitrogen rejection is the Like that of nitrogen generators, the cost of nitrogen
distillation of nitrogen from the methane-rich rejection plants is susceptible to economies of scale as
hydrocarbon feedstream. Since this takes place at shown in Fig. 5.
low cryogenic temperatures, less volatile impurities The feed composition also can have a pronounced
such as water, CO 2 , H 2 S, and heavy hydrocarbons effect on the cost of nitrogen rejection. Because of
must be removed first. Also, since distillation must the very low cryogenic temperatures involved, only
be carried out below the critical pressure (480 psig for small quantities of H2 S, CO 2 , water, or heavy
nitrogen), product recompression to pipeline hydrocarbons can be tolerated in the nitrogen-
pressure usually is needed. rejection cold box. Since the amount of ethane and
FEBRUARY 1981 267
total cost of the nitrogen-rejection cold box will
increase when other process requirements are added
to it, the total cost of all gas processing will be
decreased markedly.
The final factor that will influence the cost of
nitrogen rejection is the cost of energy. Since the
total horsepower requirements for nitrogen rejection
depends on all the factors previously mention, it is
not possible to provide a general quantification for
the total power required for a nitrogen rejection
plant. The primary uses of power are product
precompression (if necessary), power required for
pretreatment (such as amine and mole sieve
regeneration), power required for methane pumps,
and power required for compression of sales gas to
pipeline pressure.
Capital Investments
Thousands of Dollars
Pressure Cycling Cycling
Item Depletion Residue Gas Nitrogen
Producing wells 13,500 9,000 9,000
Injection wells 0 4,500 4,500
LPG plant 3,600 3,600 3,600
Nitrogen rejection plant 0 0 1,900
Field booster compressors 100 100 100
Injection compressors 0 1,170to 1,365 0
Total 17,200 18,370 to 18,565 19,100
Operating Costs
Producing wells, $/yr/well 13,000
Injection wells, $/yr/well 13,000
LPG plant, $/yr 723,000
Nitrogen rejection plant, $/yr 42,000
Field booster compressors, $/yr 42,000
Injection compressors, $/yr 457,000 to 533,000
Sales line booster compressor, $/Mcf
Without nitrogen rejection 0.04
With nitrogen rejection 0.08
Nitrogen purchase, $/Mcf 0.450to0.512
Makeup gas purchase, $/Mcf 1.75
Net Working
Cycling Total Operating Capital Interest Discounted
Life Income Cost Investment Income Net Income, 15%
Case Identification (years) (M$) (M$) (M$) (M$) (M$)
Fluid A
Pressure depletion 0 420,180 50,765 17,200 352,216 160,964
R=5
Nitrogen injection 20 1,140,043 229,913 19,743 890,387 295,578
Residue gas injection 8 1,012,172 167,137 18,565 826,470 218,239
R= 10
Nitrogen injection 19 1,084,648 230,223 19,599 834,826 272,129
Residue gas injection 7 908,530 148,678 18,565 741,286 207,172
R=20
Nitrogen injection 16 974,348 209,809 19,463 745,076 248,205
Residue gas injection 6 817,405 132,300 18,565 666,540 197,658
Fluid B
Pressure depletion 0 497,370 54,810 17,200 425,360 175,604
R=5
Nitrogen injection 12 886,170 149,176 19,895 717,099 225,744
Residue gas injection 6 847,308 119,387 18,435 709,485 174,971
R= 10
Nitrogen injection 7 752,994 121,333 19,743 611,918 210,618
Residue gas injection 5 774,468 106,909 18,435 649,124 172,388
R=20
Nitrogen injection 4 663,975 104,407 19,599 539,969 199,920
Residue gas injection 4 708,726 95,272 18,435 595,019 171,431
Fluid C
Pressure depletion 0 553,563 59,097 17,200 447,266 175,634
R=5
Nitrogen injection 7 742,580 113,055 19,895 609,630 181,196
Residue gas injection 7 879,075 118,235 18,370 742,469 132,047
R= 10
Nitrogen injection 6 722,689 119,368 19,743 583,579 173,376
Residue gas injection 6 817,656 107,336 18,370 691,950 133,728
R=20
Nitrogen injection 5 697,222 114,139 19,599 563,484 167,840
Residue gas injection 5 762,373 97,221 18,370 646,782 136,959
A plot of differential discounted net income Retrograde Condensate Reservoirs," J. Pet. Tech. (Feb. 1981)
between nitrogen injection and pressure depletion is 256-262.
presented in Fig. 6. This figure indicates that with the 3. Muskat, M.: "Effect of Permeability Stratification in Com-
plete Water-drive Systems," Trans., AI ME (1950) 189, 349-
economic factors used in this study the liquid content 358.
which a reservoir fluid must have to justify pressure 4. Dyes, A.B., Caudle, B.H., and Erickson, R.A.: "Oil
maintenance by nitrogen injection will range between Production after Breakthrough as Influenced by Mobility
65 and 96 bbl/MMcf for corresponding hetero- Ratio," Trans., AIME (1954) 20181-86.
5. Wilson, K.: "Inert Gas Processes for Enhanced Recovery
geneity indices of 5 and 20. Compared," Oi/and Gas J. (July31, 1978) 162.
It is our conclusion that gas-condensate reservoirs
with liquid contents of approximately 100 bbl/MMcf SI Metric Conversion Factors
or greater should be evaluated to determine if acre x 4.046
873 E+03 m2
pressure maintenance by nitrogen injection is bbl x 873 E-Ol
1.589 m3
economically attractive. Economic factors associated bhp x 999 E-Ol
7.456 kW
with a specific prospect which differ substantially cu ft x 685 E-02
2.831 m3
from those used in this investigation would alter this OF CF - 32)/1.8 C
limiting liquid content value. ft x 3.048* E-Ol m
psi x 6.894 757 E+OO kPa
References scf x 2.863 640 E-02 std m 3
*Conversion factor is exact. JPT
1. O'Dell, H.G. and Miller, R.N.: "Successfully Cycling a Low-
Permeability, High-Yield Gas Condensate Reservoir," J. Pet.
Original manuscript received in Society of Petroleum Engineers office July
Tech. (Jan. 1967)41-47. 26, 1978. Paper accepted for publication May 18, 1979. Revised manuscript
2. Moses, Phillip L. and Wilson, Keith: "Phase Equilibrium received Dec. 30, 1980. Paper (SPE 7494) first presented at the SPE 53rd Annual
Considerations in Using Nitrogen for Improved Recovery From Technical Conference and Exhibition, held in Houston, Oct. 1-4, 1978.