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Some Ozone Depleting Substances in Different Industry Sectors


Aerosols, Sterilants and Carbon Tetrachloride

CFCs are used in aerosol products, as sterilants of medical equipment, and in a range of
miscellaneous applications including food freezing, tobacco expansion, fumigation and cancer
therapy. Carbon tetrachloride is used as a feedstock in the production of CFC-11 and CFC-
12, in the production of key pharmaceuticals and agricultural chemicals, and as a catalyst
promoter.

CFCs and carbon tetrachloride are ozone depleting substances whose production and
consumption is controlled under the Montreal Protocol. With support from the Protocol's
Multilateral Fund delivered by UNEP, UNDP, UNIDO, the World Bank and bilateral agencies,
developing countries are phasing out these ozone depleting chemicals in this sector.

Foams

CFCs have been used extensively in the manufacture of polyurethane, phenolic, polystyrene
and polyolefin foam polymers, used in many different products. Common blowing agents have
included CFC-11, CFC-12, CFC-113 and CFC-114.

CFCs are ozone depleting substances whose production and consumption is controlled under
the Montreal Protocol. With support from the Protocol's Multilateral Fund delivered by UNEP,
UNDP, UNIDO, the World Bank and bilateral agencies, developing countries are phasing out
these ozone depleting chemicals in this sector.

Halons

Halon 1211 has been widely used in portable fire extinguishers. Halon 1301 has seen
widespread use in fixed systems throughout the industrial, commercial, marine, defence, and
aviation industries. Halon 2402 has primarily been used in the defence, industrial, marine and
aviation sector in some countries.

Halons are ozone depleting substances whose production and consumption is controlled
under the Montreal Protocol. With support from the Protocol's Multilateral Fund delivered by
UNEP, UNDP, UNIDO, the World Bank and bilateral agencies, developing countries are
phasing out these ozone depleting chemicals in this sector.

The strategy for the halon sector essentially consists of two approaches: replacing halons with alternatives, and halon banking.
Alternatives to halons include halocarbon alternatives, inert gases, water mist, fine particulate aerosols and streaming agents. In
some cases, fire protection strategies may be re-considered and the need for halons eliminated. Halon banking, which includes
recovery, recycling and establishing inventories, is used by companies and countries for managing existing halon supplies to cover
remaining critical uses.

HCFCs (hydrochlorofluorocarbons)

HCFCs (hydrochlorofluorocarbons) are widely used in the refrigeration, foam, solvent, aerosol
and fire fighting sectors as a transitional substance to substitute CFCs. HCFCs are also used as
feedstock (raw material) in the production for other chemical products.

HCFCs were introduced in the 1990s as alternative chemicals for CFCs and added to the list of
substances controlled by the Montreal Protocol. It was acknowledged at the time that these
chemicals, with considerably lower ozone depleting potentials (ODP), were transitional and their
production and consumption was also to be phased out under the Montreal Protocol. Although
having considerably lower ozone depleting potentials than CFCs, many HCFCs have high global
warming potentials, of up to 2000 times that of carbon dioxide.

In 2006 global HCFC production was 34,400 ODP tonnes and approximately 75% of global HCFC use is in air-conditioning and
refrigeration sectors. The main HCFC used is HCFC-22 or chlorodifluoromethane.
http://www.un.org/en/events/ozoneday/substances.shtml

At the 20th anniversary meeting of the Montreal Protocol on Substances that Deplete the Ozone layer agreement was reached to
adjust the Montreal Protocol's HCFC phase out schedule to accelerate the phase-out of production and consumption of HCFCS.
This decision will result in a significant reduction in ozone depletion and well as in global warming.

Methyl bromide

Methyl bromide is widely used as a fumigant in agriculture, for pest control in structures and
stored commodities, and for quarantine treatments. Fumigation is a technique that allows the
gas to reach pests which are in soil, in durables, in perishables, and in structures and vehicles.
This chemical controls a wide range of pests, including pathogens (fungi, bacteria and soilborne
viruses), insects, mites, nematodes and rodents.

Methyl bromide is an ozone depleting substance that is controlled under the Montreal Protocol.
With support from the Protocol's Multilateral Fund and the Global Environment Facility,
developing countries and countries with economies in transition are reducing and ultimately
phasing out their consumption of this chemical.

Use of methyl bromide can be reduced and eliminated by adopting alternatives, which have been identified for more than 90 percent
of applications. These include chemicals, non-chemical measures - - including Integrated Pest Management (IPM) - or a
combination of both.

Solvents, Coatings & Adhesives

In the past, CFC-113 use was essential in many industrial applications: in electronic
assembly production processes, precision cleaning and general metal degreasing during
manufacture, as well as in dry cleaning and other industrial applications. CFC-113 began to
be used in the 1970s in metal degreasing and other areas owing to concern over the toxicity
of the chlorinated solvents used previously.

For many years 1,1,1-trichloroethane was the solvent of choice to replace other more toxic
chlorinated solvents for general metal cleaning. Carbon tetrachloride is no longer used as a
solvent in most countries because of its toxicity, but it is still used in some parts of the world.

CFC-113, 1,1,1-trichloroethane, CTC, and bromochloromethane are ozone depleting


substances whose production and consumption is controlled under the Montreal Protocol. With support from the Protocol's
Multilateral Fund delivered by UNEP, UNDP, UNIDO, the World Bank and bilateral agencies, developing countries are phasing out
these ozone depleting chemicals in this sector.

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