Escolar Documentos
Profissional Documentos
Cultura Documentos
Fundamentals
of leak detection
Editor: Leybold GmbH
Cat. No. 199 79_VA.02
Authors:
Hans Rottlnder
Walter Umrath
Gerhard Voss
Leybold GmbH
Bonner Str. 498 D-50968 Kln
T +49 (0) 221-347-0
F +49 (0) 221-347-1250
info@leybold.com
www.leybold.com
Preface
Leybold, a member of the globally active industrial
Atlas Copco Group of companies has developed into the
world market leader in the area of vacuum technology.
In this leading position, we recognize that our customers
around the world count on Leybold to deliver technical
superiority and maximum value for all our products and
services.
This brochure is meant to provide an easy to read over-
view covering the entire range of vacuum technology
and is independent of the current Leybold product
portfolio. The presented product diagrams and data
are provided to help promote a more comprehensive
understanding of vacuum technology and are not offered
as an implied warranty.
To us, partnership-like customer relationships are a
fundamental component of our corporate culture as well
as the continued investments we are making in research
and development for our next generation of innovative
vacuum technology products.
In the course of our over 165 year-long corporate history,
Leybold developed a comprehensive understanding of
process and application know-how in the field of vacuum
technology. Jointly with our partners and customers, we
plan to continue our efforts to open up further markets,
implement new ideas and develop pioneering products.
Leybold GmbH
Cologne, December 2016
1
Fundamentals of Leak Detection
Table of Contents
Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
1 Types of leaks . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
2 Leak rate, leak size, (gas) mass flow . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
2.1 Helium standard leakrate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
2.2 Conversion formulas . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
3 Terms and definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
4 Leak detection methods without leak detector . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
4.1 Pressure rise test . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
4.2 Pressure drop test . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
4.3 Leak test using vacuum gauges which are sensitive to the type of gas . . . . . . . . . . . . . . . . . . . . 12
4.4 Bubble immersion test . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
4.5 Foam-spray test . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
4.6 Vacuum box check bubble . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
4.7 Krypton 85 test . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
4.8 High-frequency vacuum test . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
4.9 Test with chemical reactions and dye penetration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
5 Leak detectors and how they work . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
5.1 Halogen leak detectors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
5.1.1 Halogen diode principle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
5.1.2 Infrared principle (HLD 5000) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
5.2 Leak detectors with mass spectrometers (MS) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
5.2.1 The operating principle of a leak detector with mass spectrometer . . . . . . . . . . . . . . . . . . . . . . 16
5.2.2 Detection limit, background, gas storage in oil (gas ballast),
floating zero-point suppression . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17
5.2.3 Calibrating leak detectors; calibration leaks . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18
5.2.4 Leak detectors with quadrupole mass spectrometer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21
5.2.5 Leak detectors with 180 sector field mass spectrometer . . . . . . . . . . . . . . . . . . . . . . . . . . . 21
5.2.6 Direct-flow and counter-flow leak detectors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22
5.2.7 Counter-flow leak detector in partial-flow operation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24
5.2.8 Connection to vacuum systems . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24
5.2.9 Time constant . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26
6 Limit values / specifications for the leak detector . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27
7 Leak detection techniques using vacuum leak detectors . . . . . . . . . . . . . . . . . . . . . . . . . 27
7.1 Vacuum method spray technique (local leak test) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27
7.2 Positive pressure method sniffer technique (local leak test) . . . . . . . . . . . . . . . . . . . . . . . . . 29
7.3 Envelope test (integral leak test) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 29
7.3.1 Envelope test according to the positive pressure method . . . . . . . . . . . . . . . . . . . . . . . . . . . 29
7.3.2 Envelope test according to the vacuum method . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 30
7.4 "Bombing" test, "storage under pressure" . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 30
2
Fundamentals of Leak Detection
3
Fundamentals of Leak Detection
4
Fundamentals of Leak Detection
55
Fundamentals of Leak Detection
In order to achieve an overview of the correlation between Shown in Fig. 1 is the correlation between the hole size
the geometric size of the hole and the associated leak and leak rate for air, with the approximate value of qL (air)
rate it is possible to operate on the basis of the following, = 104 mbarl/s for the "1 cm hole".
rough estimate: The table shows that when the hole diameter D is reduced
A circular hole with a diameter D = 1 cm in the wall of to 1 mm = 0.001 mm (= reduction of D by the factor
a vacuum vessel is closed with a valve. Atmospheric 10000) the leak rate will amount to 1.010-4 mbarl/s,
pressure (p = 1013 mbar) prevails outside, a vacuum a value which in vacuum technology already represents
inside. When the valve is opened, the air flows a major leak (see the rule of thumb above).
at the speed of sound (vS = 330 m/s) through the A leak rate of 1.010-12 mbarl/s corresponds to hole
opening cross section of A = p(D2/4) ~ 0.79 cm2 into the diameter of 1 angstrom ();
vessel. The air quantity flowing into the vessel amounts to this is the lower detection limit for modern helium leak
qL(air) = pvSA ~
2.6104 mbarl/s. detectors. Since the grid constants for many solids amount
If all other conditions are kept identical and helium is to several and the diameter of smaller molecules (H2,
allowed to flow into the hole at its speed of sound of He) are about 1 , inherent permeation through solids can
970 m/s, then the helium leak rate be registered metrologically using helium leak detectors.
qL (helium) is ~ This has led to the development of calibrated test leaks
7.7104 mbarl/s, so the leak rate is
significantly higher. with very small leak rates. This is a measurable "lack of
tightness" but not a "leak" in the sense of being a defect
This greater "sensitivity" for helium is used in leak
in the material or joint.
detection and has resulted in the development and mass
production of highly sensitive helium-based leak detectors
(see Section 5.2).
Correlation between hole diameter and leak rate, estimation for air
Volume/second: 330 s s s
4
4 mbar 4 mbar
Quantity/second: 1013 mbar 26 s = 2,6 10 s 10 s
-3 2
10 m= 1,0 mm 10
-4 0
10 m= 0,1 mm 10 (= 1)
-5 -2
10 m= 0,01 mm 10
10 m= 1,0 m
-6 -4
10
0,1 m
-7 -6
10 m= 10
0,01 m
-8 -8
10 m= 10
-9 -10
10 m= 1,0 nm 10
-10 -12
10 m= 1,0 Angstrm 10 (Detection limit of helium leak detectors)
Fig. 1: Correlation between hole diameter and leak rate, estimation for air
6
Fundamentals of Leak Detection
Concept / criterion Comment qL (mbar l/s) Relevant particle size
Water-tight*) Droplets < 102
Vapor-tight "Sweating" < 103
Bacteria-tight*)
(cocci) < 104 1 m
(rod-shaped) 0.5 - 1 m, 2 - 10 m long
103................100 10-1 10-2 10-3 10-4 10-5 10-6 10-7 10-8 10-9 10-10 10-11 10-12 mbar s-1
Positive pressure method
Bubble test
Fig. 2: Nature and detection limits of frequently used leak detection methods
7
Fundamentals of Leak Detection
2.1 Helium standard leakrate (p < 1 mbar, internal), which is frequently found in
practice, the designation "helium standard leak rate"
Required for unequivocal definition of a leak are the
has been introduced in the standard DIN EN 1330-8.
pressures prevailing on either side of the (vessel) wall
and the nature of the medium passing through that wall In order to indicate the rejection rate for a test using
(viscosity, molar mass). For the case where the test is helium under standard helium conditions it is necessary
carried out with helium4 at a pressure difference of first to convert the real test conditions of use to helium
1 bar from the atmosphere pressure (external) to standard conditions (see 2.2). Some examples of such
the vacuum conversions are shown in Fig. 3.
Leak Quantity of substance per time unit through hole Standard helium conditions:
p1 = 1 bar, p2 < 1 mbar (p = 1 bar)
Test gas = Helium
Known leaks: Leaking quantity of substance: Standard helium leak rate:
mg
Water faucet dripping 34 s Water = 6,45 mbars Air 0,17
mbar
s He Std
4 mm , 1 Hz, p = 4 bar
mbar mbar
Hair lies on seal 10 2 s Air 0,9 10 2 s He Std
2.2 Conversion formulas In the intermediate range the manufacturer (who is liable
under the guarantee terms) must assume values on the
Regarding the conversion of pressure and gas type
safe side.
(viscosity, molar mass), it must be noted that different
formulas apply to laminar viscous and molecular The equations are listed in Table 2.
flow. The boundary between these areas is very difficult Here indices "I" and "II" refer to the one or the other pressure
to determine. As a guideline, the following can be ratio and indices "1" and "2" reference the inside and
assumed: at leak rates outside of the leak point, respectively. For a sensible use
of the formulas, the pressure p1 must always be the higher
q L > 104 mbarl/s laminar viscous flow
pressure ( p1 > p2 ).
and at leak rates
q L < 106 mbarl/s molecular flow
Pressure q I ( p 1 2 p 2 2 ) II = q II ( p 1 2 p 2 2 ) I q I (p 1 p 2 ) II = q II (p 1 p 2 ) I
q G a sA (M G a sA ) 1/2
Gas type q G a s A h G a s A = q G a s B h G a sB =
q G a sB (M G a sB ) 1/2
Table 2:
Formulae for the conversion of pressure and gas type, p = pressure, q = gas flow (leak rate), h = viscosity, M = molar mass
8
Fundamentals of Leak Detection
3 Terms and definitions situation in regard to the pressures inside and outside the
test object and the type of gas (or liquid) being handled.
When searching for leaks one will generally have to
distinguish between two tasks: Where a vacuum is present inside the test object (p < 1 mbar),
atmospheric pressure outside, and helium4 is used at
1. locating leaks and
the test gas, one refers to standard helium conditions.
2. measuring the leak rate
Standard helium conditions are always present during
In addition, we distinguish, based on the direction of flow helium leak detection for a vacuum system when the
for the fluid, between the system is connected to a leak detector, if the system is
a. vacuum method pumped down to p less than 1 mbar and if it is sprayed
(sometimes known as an "outside-in leak"), where the with helium4 (spray technique) (see Fig. 4b).
direction of flow is into the test object; the pressure inside If the test object is evacuated solely by the leak detector,
the test object is less than ambient pressure then one would say that the leak detector is operating in
and the the direct-flow mode of the leak detector (LD).
If the test object is itself a complete vacuum system with
b. positive pressure method
its own vacuum pump and if the leak detector is operated
(often referred to as the inside-out leak), where the
in parallel to the systems pumps, then one refers to
flow takes place from inside the test object outward; the
partial-flow mode of the leak detector. One also refers
pressure inside the test object is higher than the ambient
to partial-flow mode when a separate auxiliary pump is
pressure.
used parallel to the leak detector.
The test objects should wherever possible be examined in
When using the positive pressure method it is sometimes
a configuration corresponding to their later application, i.e.
either impractical or in fact impossible to measure the
components for vacuum applications using the vacuum
leakage rate directly while it could certainly be sensed
method and using the positive pressure method for parts
in an envelope which encloses the test specimen. The
which will be pressurized on the inside.
measurement can be made by connecting that envelope
When measuring leak rates, we differentiate between to the leak detector or by accumulation ( = increasing
registering the concentration) of the test gas inside the envelope
a. individual leaks (local measurement), Fig. 4b (see Fig. 4c). The bombing test is a special version of
and 4d, the accumulation test (see 7.4).
and registering
In the so-called sniffer technique, another variation
b. the total of all leaks in the test object (integral
of the of the positive pressure technique, the (test) gas
measurement) Fig. 4a and 4c.
issuing from leaks is collected (extracted) by a special
The smallest leak rate which is no longer tolerable in apparatus and fed to the leak detector (see Fig. 4d).
accordance with the acceptance specifications is known This procedure can be carried out using either helium
as the rejection rate. Its calculation is based on the or refrigerants or SF6 as the test gas.
condition that the test object may not fail during its
planned utilization period due to faults caused by leaks,
and this to a certain degree of certainty.
Often it is not the leak rate for the test object under
normal operating conditions which is determined, but
rather the throughput rate of a test gas under similar
conditions. The achieved measuring values have to be
converted to correspond to the actual application
9
Fundamentals of Leak Detection
a: c:
b: d:
Fig. 4:
Usage options for a vacuum leak detector based on the vacuum method (a, b) and based on the positive pressure method (c, d)
a: Enclosure test (integral leak detection) c: Enclosure test (integral leak detection)
b: Spray technique (local leak detection) d: Sniffer technique (local leak detection)
10
Fundamentals of Leak Detection
4 Leak detection methods without constant, then a leak is present, assuming that the waiting
period between the two pressure rise measurements was
leak detector
long enough. The appropriate length of the waiting period
The most sensible differentiation between the test methods depends on the nature and size of the device. If the time
used is the differentiation as to whether or not special leak for the pressure rise p increases, this effect is most likely
detection equipment is used. caused by a reduced gas liberation on the inside of the
In the simplest case a leak can be determined qualitatively apparatus.
and, when using certain test techniques, quantitatively as well One may also attempt to differentiate between leaks and
(this being the leak rate) without the assistance of a special contamination by interpreting the curve depicting the rise
leak detector. in pressure ( = pressure as a function of time).
For example, the quantity of water dripping from a
Plotted on a graph with linear scales, the curve for the rise
leaking water faucet over a certain period of time can
in pressure must be a straight line where a leak is present,
be determined by collecting the water with a measuring
even at higher pressures.
vessel. In this case, however, one would hardly refer to
this as a leak detector. If the pressure rise is due to gas being liberated from the
walls, then the pressure rise will gradually taper off and
In those cases where the leak rate can be determined
will approach a final and stable value. In most cases both
during leak detection without using a leak detector, this
phenomena will occur simultaneously so that separating the
leak rate will often be converted to the helium standard
two causes is often difficult if not impossible.
leak rate (see 2.1). The helium standard leak rate is often
required for issuing acceptance certificates but can also These relationships are shown schematically in Fig. 5.
be of service when comparing leak rate values determined
via helium leak detector devices.
In spite of careful inspection of the individual engineering
components, leaks may also be present in an apparatus
following its assembly be it due to poorly seated seals
or damaged sealing surfaces. The processes used to
examine an apparatus depend on the size of the leaks and
on the desired degree of tightness as well as on whether
the apparatus is made of metal, glass or other materials.
Below, you will find the description of a few leak detection
methods. These methods are used in accordance with
the particular application situations while economic factors
often play an important part as well.
Once it has become clear that the rise in pressure is due since the flange connectors used in vacuum technology
solely to a real leak, then the leak rate can be determined will as not tolerate higher pressures. On the other hand,
quantitatively from the pressure rise, plotted against time, the pressure drop test is a technique commonly employed
in accordance with the following equation: in tank engineering. When dealing with large containers
(3) qL = V(p/t) and the consequentially long measuring periods required
for the pressure drop, it may under certain circumstances
with
be necessary to consider the effects of temperature
q L = Leak rate in mbar l/s changes. As a consequence it may happen, for example,
V = Volume of the vacuum reservoir in l that the system cools to below the saturation pressure
for water vapor, causing water to condense so that the
p/t = Pressure rise in the vacuum reservoir p divided
measurement is distorted.
by the measuring time t in mbar/s
Example:
4.3 Leak test using vacuum gauges
After closing the pump-end valve, the pressure p in a
which are sensitive to the type of gas
vacuum vessel with the volume V = 20 l rises from 110 4
mbar to 110 3 mbar in t = 300 s Thus, p = ( 110 3 The fact that the pressure reading at vacuum gauges
110 4 ) mbar = 910 4 mbar and the leak (leak rate) is sensitive to the type of gas involved can, to a certain
for air in accordance with relation (3) qL(air) = V (p/t) extent, be utilized for leak detection purposes. Thus it is
= 610 5 mbarl/s. possible to brush or spray suspected leaks with alcohol.
The alcohol vapor which flows into the device changes
Via relation (1), one obtains the gas mass flow m/t
the pressure reading of the vacuum gauge since the
through
thermal conductivity and ionizability of alcohol vapor vary
the leak by means of the leak rate qL = 610 5
greatly from the same properties for air. The availability
mbarl/s:
of more precise, easy-to-use helium leak detectors has,
m/t = 7108 g/s however, rendered this method almost completely obsolete.
(temperature T = 293 K, molar mass for air M ~
29 g/mol)
12
Fundamentals of Leak Detection
13
Fundamentals of Leak Detection
When evaluating tiny leaks for liquids it will be necessary Some widely used leak detection methods are shown
to consider the wetability of the surface of the solid and together with the test gas, application range and their
the capillary action. particular features in Table 4.
Loss of refrigerant
Equivalent R134a Time for Detection time using
R134a per year
leak rate at 25 C 10 gas bubbles, 2 mm helium leak detector
g/a mbar . /s s s
430 3,32 10-3 3.2 a few seconds
86 6,63 10-4 15.8 a few seconds
21,5 1,66 10-4 63.1 a few seconds
17,2 1,33 10-4 1 min 48 s a few seconds
4,3 3,32 10-5 5 min 15 s a few seconds
0,86 6,63 10-6 26 min 19 s a few seconds
0,1 *) 7,70 10-7 3 h 46 min a few seconds
*) This leak rate represents the detection limit for good halogen leak detectors ( 0.1 g/a).
Table 3: Comparison of bubble immersion test with helium leak detector
Pressure drop test Air and other gases 10-4 7 . 10-1 Positive pressure Yes
14
Fundamentals of Leak Detection
15
Fundamentals of Leak Detection
Every mass spectrometer consists of three At any other position x, the following applies while taking
fundamental assemblies: the line losses into account:
ion source, (4a) qx = q = px Sx with
separation system and px = pressure at position x in mbar
ion trap.
Sx = pumping speed of the vacuum pump at
The ions must be able to travel along the path from the position x in l/s (Sx < S !)
ion source and through the separation system to the ion
Equation (4a) applies to all gases which are pumped
trap, to the greatest possible extent without colliding with
by the vacuum pump and thus also for the test gas TG
gas molecules. This path amounts to about 15 cm for all
(e.g. TG = helium 4). At the mass spectrometer (x = MS),
types of spectrometers and thus requires a medium free
the following applies:
path length of at least 60 cm, corresponding to pressure
of about 110-4 mbar; in other words, a mass spectrometer (4b) qMS, TG = qTG = pMS, TG SMS, TG = qL with
will operate only in high vacuum. In modern leak detectors, pMS, TG = partial test gas pressure at mass spectrometer
turbomolecular pumps are used to create the high vacuum. in mbar
Associated with the individual component groups are SMS, TG = pumping speed of the vacuum pump for the
the required electrical and electronic supply systems test gas at mass spectrometer in l/s
and software which, via a microprocessor, allow for the In this case, the test gas flow qTG equals the lake rate qL
greatest possible degree of automation in the operating being sought. It must be noted that, in case of equation
sequence, including all adjustment and calibration routines (4b), the partial test gas pressure pMS, TG is present at the
and measured value display. mass spectrometer. The measuring value for pMS, TG is
provided by the mass spectrometer which must be set to
the mass M of the test gas (e.g. M = 4 for TG = helium4).
The value of SMS, TG is an experimentally determined con-
5.2.1 The operating principle of a leak stant for each leak detector.
detector with mass spectrometer The value for pMS, TG provided by the mass spectrometer
Fig. 6 is provided to explain the operating principle of a is multiplied by the value SMS, TG which is stored in the
leak detector with mass spectrometer: This sketch shows microprocessor of the leak detector. The result of this
the most commonly found configuration for leak detection multiplication is then displayed as leak rate qL.
using the test gas spray method (see Chapter 7.1) at a
vacuum component (= test object).
If gas enters the component through a leak, it is pumped Test gas
thorough the interior of the leak detector to the outlet,
where it leaves the detector again. Assuming, that the leak
detector is properly sealed, the gas flow q is always the Test object
same at any point between the inlet and the outlet of the Inlet
leak detector. The following applies directly at the pumping
port of the vacuum pump:
MS
(4) q = pS with
p = Inlet pressure directly at the pumping port Leak detector
of the vacuum pump in mbar
S = Pumping speed of the vacuum pump directly at
the pumping port of the vacuum pump in l/s
Outlet Vacuum pump
16
Fundamentals of Leak Detection
17
Fundamentals of Leak Detection
106
107
108
109
1010
1011
Equipment background level: < 2 1010 1 108 1 1010 (suppressed)
Leak: 2 108 2 108 2 108
Display: 2 108 3 108 2 108
Fig. 8 is provided to illustrate the zero-point Internal calibration of a leak detector uses a calibration
suppression: leak which is permanently built into the leak detector.
Chart on the left: The signal is clearly larger than the Using this "internal calibration leak", only the leak
background. detector, in which the calibration leak is built in, itself
may be calibrated.
Center chart: The background has risen considerably;
the signal can hardly be discerned. All Leybold leak detectors are equipped with an internal
calibration leak. Via the automatically operated calibration
Chart on the right: The background is suppressed
routine, each leak detector may be "internally calibrated"
electrically; the signal can be clearly identified again.
within just a few seconds.
External calibration of a leak detector uses a calibration
leak which is installed at the inlet of the leak detector.
5.2.3 Calibrating leak detectors; Using this "external calibration leak", the leak detector
calibration leaks may be calibrated in just a few minutes.
The calibration of a leak detector is to be understood Furthermore, the external calibration leak may be used to
as the adjustment of the display at a leak detector, to check the proper functioning and operation of the internal
which a calibration leak (or test leak) is attached. calibration leak. In particular, external calibration leaks are
A calibration leak is a leak whose leak rate at a certain always used if complete leak detector systems or partial
temperature and under specific pressure conditions flow arrangements must be calibrated.
is known precisely. This leak rate is provided on the Sniffer devices and sniffer arrangements must also usually
calibration certificate of the calibration leak or documented be calibrated with external calibration leaks. In this case,
on a label which is attached to the calibration leak. it must be ensured that on the one hand the entire test
In vacuum operations (spray technique, see Chapter 7.1) gas from the calibration leak reaches the sniffer tip and on
one must differentiate between two types of calibration: the other hand the gas flow through the sniffer unit is not
hindered by the calibration process (see Fig. 9).
a) internal calibration and
When making measurements using the sniffer technique
b) external calibration.
(see Chapter 7.2) it is also necessary to take into account
the distance from the probe tip to the surface of the specimen
and the scanning speed; these must be included as a
part of the calibration. In the special case where helium4
18
Fundamentals of Leak Detection
Capillaries Air
Probe tip
concentration is being measured, calibration can be made Calibration leaks used with a refrigerant charge represent
using the helium content in the air, which is a uniform a special situation since the refrigerants are liquid at room
5 ppm worldwide. Calibration leaks normally comprise temperature and usually feature a vapor pressure between
a gas supply, a choke with a defined conductance value, 4 bar and 10 bar. One technological problem which is
and a valve. The configuration will be in accordance with difficult to solve is the risk of clogging of the capillaries.
the leak rate required. All refrigerants are also very good solvents for oil and
Fig. 10 shows different helium calibration leaks. grease and thus are often seriously contaminated so that
Permeation leaks are usually used in case of leak rates of it is difficult to fill the calibration leaks with pure refrigerant.
1010 to 107 mbarl/s. Capillaries are usually used for leak Decisive here is not only the chemical composition but
rates between 107 to 104 mbarl/s and, for very large leak above all dissolved particles which can repeatedly clog
rates in a range from 10 to 1000 mbarl/s, pipe sections the fine capillaries.
or orifice plates with exactly defined conductance values.
a b c d e
Fig. 10:
Examples for the composition of calibration leaks
a Calibration leak without gas supply TL4, TL6
b Calibration leak for sniffer and vacuum applications TL4-6
c (Internal) capillary calibration leak TL7
d Permeation calibration leak (also called "diffusion calibration leak") TL8, TL9
e Refrigerant calibration leak
19
Fundamentals of Leak Detection
Fig. 11:
Calibration leak for sniffing method with pressure regulator
20
Fundamentals of Leak Detection
5.2.4 Leak detectors with quadrupole 5.2.5 Leak detectors with 180
mass spectrometer sector field mass spectrometer
Leak detectors with quadrupole mass spectrometers Helium leak detectors with 180 sector field mass spectro-
(QMS) are mostly build to detect masses greater than meter are the most sensitive and reliable leak detection
helium4. Apart from special cases, these will be refrigerants devices. There is no other leak detection method with
or lamp filling gases. Therefore, leak detectors with QMS which one can, with greater reliability and better stability,
are mostly used to inspect refrigeration units for leaks. locate leaks and measure them quantitatively. Therefore,
Fig. 12 shows the vacuum diagram of a leak detector with helium leak detectors even though the purchase price
QMS. One may recognize the twofold gas inlet system is relatively high are very economical in the long run
which consists of the (direct flow) inlet for refrigerant via since the required for the leak detection procedure itself
flow divider 1 and the (counter flow) inlet for helium into is very short.
the turbomolecular pump via flow divider 2. This way, the A helium leak detector with 180 sector field
device may be used to sniff for refrigerants as well as for mass spectrometer basically consists of
helium. three assemblies:
Another special feature is the use of a two-stage diaphragm 1. the mass spectrometer
vacuum pump for evacuation of the QMS as well as for 2. the high-vacuum pump system
delivery of the sniffer gas flow (1st stage of the diaphragm 3. the roughing pump system.
vacuum pump). The mass spectrometer (see Fig. 13) consists of the
ion source (14), the separation system (510), and the
ion trap (1114). The ion beam is extracted through the
orifice (5). The ions always enter the magnetic field (10) at
a certain speed. Inside this magnetic field the ions move
Inlet
Quadrupole mass spectrometer
Flow splitter 1
Flow limiter 2
Flow meter
Pressure measurement
along circular paths whereby the radius for low masses 5.2.6 Direct-flow and counter-flow
is smaller than that for higher masses. With the correct leak detectors
setting of the acceleration voltage during tuning one can
Depending on the way in which the gas from the test
achieve a situation in which the helium4 ions move exactly
object is supplied to the mass spectrometer, one can
on the circular arc which is required for them to pass
differentiate between two types of helium leak detectors:
through the intermediate orifice plate (9). They way, the
1. The direct-flow leak detector
helium4 ions reach the ion trap (13).
2. The counter-flow leak detector
The ion source features a simple and rugged design.
Fig. 14 shows the vacuum diagrams for the two leak
It can be replaced without much effort. During operation,
detector types. In both cases, the mass spectrometer
the ion source is permanently heated and therefore
is evacuated by a high-vacuum pump system.
unsusceptible to contamination.
In case of the direct flow leak detector (left diagram),
The two selectable yttrium oxide coated iridium cathodes
the gas to be inspected is supplied to the mass spectro-
have a long service life. These cathodes are largely in-
meter via a cold trap. The cold trap is cooled with liquid
sensitive to air ingress, i.e. the quick-acting safety cut-out
nitrogen (LN2) and is basically a cryopump in which all the
will keep them from burning out even if air enters.
vapors and other contaminants condense. In case of the
However, as for any annealed metals, prolonged use
diffusion pump, which was usually used in the past, the
of the ion source may eventually lead to cathode
LN2-cooled cold trap was therefore an effective protection
embrittlement and can cause the cathode to splinter
for the mass spectrometer against the oil vapors discharged
if exposed to vibrations or shock.
from the diffusion pump.
8 7
Fig. 13: Structure of a 180 sector field mass spectrometer
22
Fundamentals of Leak Detection
The auxiliary pump serves for pre-evacuation of the test In should be noted that, in case of the counter-flow leak
object and the required connection lines. In order to be detector, the supply of the gas to be inspected is carried
able to connect the high-vacuum side of the running out between the roughing pump and the high-vacuum
high-vacuum pump with the test object, the auxiliary pump. This means that the roughing pump and the
pump must evacuate the test object to a pressure below auxiliary pump must bring the test object to a pressure at
5102 mbar. Only then it is possible to open the valve which the roughing side of the running high-vacuum pump
between auxiliary pump and cold trap. The high-vacuum can be connected to the test object. In case of today's
pump must not evacuate the test object, the required counter-flow leak detectors, this so-called start pressure
connection lines and the mass spectrometer to a pressure amounts to several millibars (Leybold counter-flow leak
below 2104 mbar. Afterwards, the mass spectrometer detector PHOENIX L300: start pressure = 15 mbar). If the
may start operating in order to detect leaks. start pressure at the inlet of the leak detector is reached, it
Depending on the size of the leak in the test object and immediately switches over to the measuring mode.
the pumping performance of the vacuum pumps used, The partial test gas pressure p FV, TG between roughing
pumping times may be very long. In case of a very large pump and high-vacuum pump is increased by the test gas
leak, the abovementioned pressure values may not even TG (TG = helium4 or hydrogen) which flows into the leak
be reached at all. detector. When the high-vacuum pump is running, the
The right part of Fig. 14 shows the diagram for partial test gas pressure (pHV, TG) on the high-vacuum side
the counter-flow leak detector. One immediately of the pump is significantly smaller than on the fore-vacuum
recognizes the substantial difference to the diagram of side of the pump (p FV, TG). Therefore, a certain amount of
the direct-flow leak detector: Here, the high-vacuum the test gas flows against the delivery direction of the
pump only evacuates the mass spectrometer (smaller high-vacuum pump from the fore-vacuum side to
volume, very small leak rate) and not the test object the high-vacuum side of the high-vacuum pump. This
(large volume, large leak rate in general). phenomenon is the reason why this kind of leak detector
MS MS
He He
PMS < 2 . 10-4 mbar PMS < 2 . 10-4 mbar
LN2
Fig. 14: Comparison between main flow leak detector (left) and counterflow leak detector (right)
23
Fundamentals of Leak Detection
24
Fundamentals of Leak Detection
In systems with high vacuum and Roots pumps, the sur- valve. In order to avoid this valve being opened inadver-
est option is to connect the leak detector between the tently, it should be sealed off with a blank flange during
rotary vane pump and the roots pump or between the normal vacuum system operation.
roots pump and the high-vacuum pump. If the pressure Another method for connecting a leak detector to lager
there is greater than the permissible inlet pressure for the vacuum systems is to insert a sniffer into the atmosphere-
leak detector, then the leak detector will have to be con- side outlet of the system. One then sniffs the increase in
nected by way of a metering (variable leak) valve. Naturally the test gas concentration in the exhaust.
one will have to have a suitable connector flange available.
SLD = S R , He = pumping speed of the roughing pump built into
It is also advisable to install a valve at this point from
the leak detector for helium in l/s at the branching point
the outset so that, when needed, the leak detector can
quickly be connected (with the system running) and leak SAP = SAP, He = pumping speed of the auxiliary pump for helium
detection can commence immediately after opening the in l/s at the branching point
Auxiliary pump
_ 17 l/s
SAP(He) = 60 m3/h ~
At the branching point, the helium flow qL which is discharged from the vacuum reservoir is divided into a helium
flow qL, display towards the leak detector and a helium flow qAP towards the auxiliary pump.
Helium flow towards leak detector:
The leak rate qL, display which is displayed by the leak detector equals the product of the true leak rate
qL and the partial flow ratio !
The calculation shows = SLD/(SLD + SAP) ~ (8 l/s)/(8 l/s + 17 l/s) = 0.32 and
qL, display = qL = (3.010-1 mbarl/s) 0.32 = 9.6 10-2 mbarl/s
Conclusion: The leak detector shows a leak rate which is smaller than the true leak rate by a factor of
1/ = 1/0.32 ~
3.1!
Fig. 15: Example for usage of a leak detector with partial flow principle
25
Fundamentals of Leak Detection
5.2.9 Time constant 1. Center: The test object (volume Vch) is directly
connected to the leak detector LD (effective
The time constant of a vacuum system is provided by
pumping speed for the test gas = SLD).
(9) = Vch /Seff with
Vch = volume of the vessel in l 2. Left: In addition to 1, an auxiliary pump
S eff = effective pumping speed for the test gas at the ( = partial-flow pump) with the same
vessel in l/s effective pumping speed SAP = SLD
Fig. 16 shows the course of the signal after spraying a is connected to the test object.
leak in a test object attached to a leak detector, for three 3. Right: Same as 1, however, SLD is throttled
different configurations: down to 0.5 SLD.
qL qL qL
Vch Vch Vch
MS MS MS
)(
Throttle
LD LD LD
100%
2,0
95%
100%
1,0
95%
100%
0,5
95%
Time
0
t0 0,5 1 1 2 1
Fig. 16: Example for usage of a leak detector with partial flow principle
p1 = qL/Seff , 1 = 3 Vch /Seff
26
Fundamentals of Leak Detection
The three corresponding signal curves are shown below: the signal is doubled as well. A reduction of the pumping
Curve 1: After a "dead time" t0 the signal proportional speed is always associated with a higher expenditure of
to the partial test gas pressure pTG time and thus by no means always an advantage.
increases over time t according to the relation An estimate of the overall time constants for several
(10) pTG = (qL /Seff ) { 1 exp[ (t t0)/ ] } volumes connected one behind to another and to the
associated pumps can be made in an initial approximation
After a certain period of time, the signal reaches a portion
by adding the individual time constants.
of its ultimate value
t t0 = 1 63.3 % of ultimate value
t t0 = 3 95.0 % of ultimate value
t t0 = 6 99.8 % of ultimate value 6 Limit values / specifications
The ultimate value of the signal is proportional to for the leak detector
pTG = qL/Seff since the exponential term in (10) will 1. The smallest detectable leak rate (qL, min)
disappear for t - t0 >> . The time span t - t0 which is
2. The effective pumping speed for the test gas
required to reach 95 % of the ultimate value is referred
at the inlet (Seff, TG)
to as response time. This is given by 3 .
2a. The effective pumping speed for air at the
This provides the following result for curve 1:
inlet (Seff)
The ultimate value of the signal is proportional to
pTG = qL/Seff = qL/SLD = p1 3. The maximum permissible pressure inside the test
Response time = 3 = 3 Vch/Seff = 3 Vch/SLD = 1 object (pmax)
(= the maximum permissible inlet pressure)
The following applies for curve 2 ( = partial-flow operation):
The maximum permissible inlet pressure pmax is about
The ultimate value of the signal is proportional to
101 mbar for leak detectors with classic turbomolecular
pTG = qL /Seff = qL /(SLD + SAP) = 0.5 p1
pump and 2 to 15 mbar for leak detectors with compound
Response time = 3 = 3 Vch/Seff = 3 Vch/(SLD + SAP) =
turbomolecular pump.
0.5 1
4. The maximum permissible gas flow for air (qmax)
Due to the installation of an auxiliary pump ( = partial-flow
pump), the response time will always be shortened The product of the maximum permissible inlet pressure
and the ultimate value of the signal will always be pmax and the effective pumping speed for air at the inlet
decreased. In the above example, the response time is Seff equals the maximum permissible gas flow for air
halved but the ultimate value of the signal is halved as well. qmax. If a gas flow which is greater than qmax enters the
leak detector due to one large or several small leaks, the
A short response time means a quick change and
device is inoperable.
display of the signal. This provides that advantage that
the expenditure of time required for leak detection can be
significantly reduced. The consequential downside that the
ultimate value of the signal is smaller does, in most cases, 7 Leak detection techniques using
not result in any severe problems due to the very high vacuum leak detectors
sensitivity of today's leak detectors.
7.1 Vacuum method spray technique
Conclusion: Partial-flow operation reduces the (local leak test)
expenditure of time for leak detection!
The test object connected to the vacuum leak detector is
Accordingly, the following applies to curve 3: traced with a very fine stream of test gas from the spray
Ultimate value of the signal is proportional to pistol at likely leakage points (flange connections, welding
pTG = qL/Seff = qL/(0.5 SLD) = 2 p1 seams, etc,) in an appropriately slow manner. The
Response time = 3 = 3Vch /Seff = 3Vch /(0.5SLD) = 2 1 appropriate speed for this process is determined by the
Due to the throttling of the pumping speed, the response response time of the system (see Chapter 5.2.9). The test
time will always be prolonged and the ultimate value of gas amount sprayed must be adjusted to suit the leak rate
the signal will always be increased. In the above example, to be detected as well as the size and accessibility of the
the response time is doubled but the ultimate value of object being tested.
27
Fundamentals of Leak Detection
Although the test gas (hydrogen, helium) is lighter than air With helium leak detectors, it is also easy to detect the
and will therefore accumulate beneath the ceiling of the natural amount of helium4 in the atmosphere.
room, it will be so well distributed by drafts and turbulence The natural amount of helium4 in the atmosphere amounts
induced by movements within the room that one need not to 5104 volume percent ( = 5 ppm). If air enters the test
assume that test gas will be found primarily (or only) at the object through a very large leak, the leak detector will
top of the room during search for leaks. In spite of this, therefore already detect helium4 gas flowing through the
it is advisable particularly when dealing with larger leak. The leak rate is then:
components to start the search for leaks at the top.
(11) Display (helium4 from spray pistol) / 100 % =
In order to avoid a surge of test gas when the spray pistol Display (helium4 from atmosphere) / 510-4 %
is opened, it is advisable to install a choke valve to adjust or
the test gas flow directly before or after the spray pistol (11a) Display (helium4 from spray pistol) =
(see Fig. 17). The easiest way to set the desired test gas 2 105 Display (helium4 from atmosphere)
flow is to submerge the spray pistol in a water container and
determine the setting based on the rising test gas bubbles.
Fig. 17: Handling information for using test gases (e.g. helium)
28
Fundamentals of Leak Detection
7.2 Positive pressure method 7.3 Envelope test (integral leak test)
sniffer technique (local leak test) An envelope test is an integral leak test using helium4
In case of this method, the test object is filled with test as test gas. In case of this method, the test object is
gas to an extend so that the partial test gas pressure in enclosed in a rigid (usually metal) enclosure or in a light
the test object is significantly larger than that around the plastic envelope. The helium4 which flows through the
test object. If possible, the test object should be evacuated leaks of the test object is detected using a helium leak
prior to filling it with test gas. detector.
The likely leak positions of the test object are traced with a Envelope tests are carried out according to the vacuum
sniffer tip in an appropriately slow manner. A typical tracing method (test object under vacuum, Fig 4a) as well as
speed is 1 cm/s. the positive pressure method (test object under positive
The sniffer tip is connected to the roughing pump (see Fig. pressure, Fig. 4c). In both cases it might be necessary to
4d) via a long, thin line (length ~ ~ 1 mm).
1 m, diameter carry out the conversion to the helium standard leak rate.
Test gas which enters the sniffer tip is delivered to the leak
detector by the roughing pump and then detected there
by the mass spectrometer.
7.3.1 Envelope test according to the
Vacuum detectors by Leybold are able to "sniff" helium4 or positive pressure method
hydrogen.
a) Envelope test with concentration measurement
The sensitivity of the method and the accuracy of
and subsequent leak rate calculation
the localization of leaks depend on
In order to determine the overall leakage of the test object,
it is enclosed with an envelope which may be rigid or
a) the type of sniffer unit used
flexible. The helium4 which flows through the leaks of
(sniffer tip + line),
the test object accumulates in the envelope so that the
b) the response time of the leak detector used,
helium concentration in the envelop increases. After an
c) the tracing speed
accumulation time (operating period) to be determined,
and
the change in concentration inside the envelope will be
d) the distance of the sniffer tip
measured with a sniffer connected to the helium leak
from the surface of the test object.
detector (Fig. 4c). The overall leak rate ( = integral leak
The many parameters which play a part here make it more rate) can be calculated following the calibration of the test
difficult to determine the leak rates quantitatively. Using configuration with a known concentration, e.g. atmospheric
sniffer processes, it is possible to detect leak rates of more air (5 ppm).
than 1107 mbarl/s. The limitation regarding the sensitivity
This method makes it possible to detect even the smallest
for detecting helium4 is due primarily to the natural amount
overall leakage and is suitable in particular for automated
of helium4 in the atmosphere. For quantitative measure-
industrial leak testing. Due to gas accumulation, the limits
ments, the leak detector and sniffer unit will have to be
for normal sniffer techniques are shifted toward lower leak
calibrated together. In this case, the distance of the sniffer
rates and the ambient conditions such as temperature,
tip from the outlet of the calibration leak will be included in
air flow and sniffer tracing speed lose influence. When
the calibration as well.
using plastic envelopes it is necessary to take into account
helium permeation through the plastic envelope during
long enrichment periods.
b) Direct measurement of the leak rate with the
leak detector (rigid envelope)
When the test object, pressurized with helium, is placed in
a rigid vacuum vessel which is connected to a helium leak
detector, the integral leak rate can be read directly at the
leak detector.
29
Fundamentals of Leak Detection
31
Fundamentals of Leak Detection
V = 100.00 l
32
Fundamentals of Leak Detection
Legend p = The pressure with which the gas has been pressurized
(gas pressure) in mbar
V = The volume which the gas occupies
(gas volume) in l
m = The mass of the gas
(gas mass) in g
M = The molar mass of the gas
(formerly: molecular weight) in g/mol
T = The temperature of the gas
(gas temperature) in K
R = The molar gas constant
= 83.145 (mbarl)/(molK)
33
Fundamentals of Leak Detection
Unit mbarl/s
34
Fundamentals of Leak Detection
Molecular flow
qL(T2) (T1)1/2 = qL(T1) (T2)1/2
Legend qL(T1) = The leak rate measured at the temperature T1
in mbarl/s
qL(T2) = The leak rate measured at the temperature T2
in mbarl/s
T1 = Temperature T1
in K
T2 = Temperature T2
in K
35
Fundamentals of Leak Detection
Molecular flow
qL = qN (pB - pA) Vacuum technique
qL = qN (pB - pA) Positive-pressure technique
Legend qL =
Leak rate in mbarl/s
The test gas flows through the leak due to a difference between the
partial test gas pressures pA and pB.
qN = The "standard leak rate" in mbarl/s
The test gas flows from 1 bar absolute partial test gas pressure to
0 bar absolute partial test gas pressure.
qA = Partial test gas pressure inside test object in bar absolute
qB = Partial test gas pressure outside the test object in bar absolute
Molecular flow
qL, gas A (Mgas A)1/2 = qL, gas B (Mgas B)1/2
36
Fundamentals of Leak Detection
S qL, display
g = LD
=
SLD + SPF qL
qL, display = g qL
Legend SLD = The pumping speed of the leak detector
in l/s
SPF = The pumping speed of the partial-flow pump
in l/s
qL, display = The leak rate displayed by the leak detector
in mbarl/s
qL = The true leak rate
in mbarl/s
38
Fundamentals of Leak Detection
V
tR 95% = 3
S eff
V
tR 87% = 2
S eff
V
tR 63% = 1
S eff
Legend V = The volume of the test object
in l
Seff = The effective pumping speed at the test object
in l/s
V pstart
t(pstart ptarget) = 2.3 log ( )
Seff ptarget
V pstart
t(pstart ptarget) = ln ( )
Seff ptarget
Legend V = The volume of the test object
in l
Seff = The effective pumping speed at the test object
in l/s
pstart = The start pressure inside the test object
in mbar
ptarget = The target to be reached in the test object
in mbar
39
Fundamentals of Leak Detection
V pstart
Seff = 2.3 log ( )
t ptarget
V pstart
Seff = ln ( )
t ptarget
Legend V = The volume of the test object
in l
t = The pump-down time
in s
pstart = The start pressure inside the test object
in mbar
ptarget = The target to be reached in the test object
in mbar
40
1 = .. mbar Pa dyn cm2 atm Torr inch Hg Micron cm H2O kp cm2 lb in2 lb ft2
mbar 1 102 103 9.87 104 0.75 2.953 102 7.5 102 1.02 1.02 103 1.45 102 2.089
Pa 102 1 10 9.87 106 7.5 103 2.953 104 7.5 1.02 102 1.02 105 1.45 104 2.089 102
mbar 103 0.1 1 9.87 107 7.5 104 2.953 105 7.5 101 1.02 103 1.02 106 1.45 105 2.089 103
atm 1013 1.01 105 1.01 106 1 760 29.92 7.6 105 1.03 103 1.033 14.697 2116.4
Torr 1.33 1.33 102 1.33 103 1.316 103 1 3.937 102 103 1.3595 1.36 103 1.934 102 2.7847
in Hg 33.86 33.9 102 33.9 103 3.342 102 25.4 1 2.54 104 34.53 3.453 102 0.48115 70.731
3 1 6 3 5 3 6 5
m 1.33 10 1.33 10 1.333 1.316 10 10 3.937 10 1 1.36 10 1.36 10 1.934 10 2.785 103
cm H2O 0.9807 98.07 980.7 9.678 104 0.7356 2.896 102 7.36 102 1 103 1.422 102 2.0483
at 9.81 102 9.81 104 9.81 105 0.968 7.36 102 28.96 7.36 105 103 1 14.22 2048.3
9.13 Conversion of pressure units
psi 68.95 68,95 102 68,95 103 6.804 102 51.71 2.036 51.71 103 70.31 7.03 102 1 1.44 102
lb ft2 0.4788 47.88 478.8 4.725 104 0. 3591 1.414 102 359.1 0.488 4.88 104 6.94 103 1
Normal conditions: 0 C and sea level, therefore p = 1013.25 mbar = 760 mm Hg = 760 Torr = 1 atm
1 dyn cm2 (cgs) = 1 mbar (microbar) = 1 barye; 1 bar = 0.1 MPa; 1 cm WS (cm water column = g/cm2 at 4 C) = 1 Ger (Geryk)
atm ... physical atmosphere at ... technical atmosphere; 100 (x mbar / 10.13) = y % vacuum
41
Fundamentals of Leak Detection
1 = .. mbarl/s kg h1 kg h1 cm3/h cm3/s Torr l/s g/a g/a m cfm lusec Pa l/s slpm
42
(20 C) (0 C) (NTP) (NTP) (R12, 20 C) (F134, 20 C)
mbarl/s 1 4,28 103 4,59 103 3554 0,987 0,75 1,56 105 1,54 105 1593 7,52 102 100 59,2 103
kg h1 (20 C) 234 1 1,073 8,31 105 231 175 37,2 104 1,75 105 23,4 103 13,86
kg h1 (0 C) 218 0,932 1 7,74 105 215 163 34,6 104 1,63 105 21,8 103 12,91
Fundamentals of Leak Detection
cm3/h (NTP) 2.81 104 1.20 106 1.29 106 1 2,78 104 2,11 104 44 44,7 102 2,11 101 2,81 102 1,66 105
cm3/s (NTP) 1.013 4,33 103 4,65 103 3600 1 0,760 1,58 105 1611 760 101 6 102
Torr l/s 1.33 5,70 103 6,12 103 4727 1,32 1 2,08 105 2,05 105 2119 1 103 133 78,8 103
g/a (R12, 20 C) 6.39 106 2,27 102 6,31 106 4,80 106 1 10,2 103 4,8 103 6,39 104 37,9 108
g/a (F134, 20 C) 6,50 106 4,88 106 1 10,4 103 4,89 103 6,5 104 38,5 108
m cfm 6.28 104 2.69 106 2.89 106 2.24 6,21 104 4,72 104 98,16 96,58 1 0,472 6,28 102 37,2 106
lusec 1.33 103 5.70 106 6.12 106 4.737 1,32 103 1 103 208 205 2,12 1 13,3 102 78,8 106
Pa l/s 1 102 4.28 105 4.59 105 35.54 9.87 103 7.5 103 1.56 103 1.54 103 15.93 7.50 1 59.2 105
slpm 16,88 72.15 103 77.45 103 60.08 103 16.67 12.69 2.64 106 2.60 106 26.9 103 12.7 103 16.9 102 1
9.14 Conversion of gas flow/leak rate units
NTP = normal temperature and pressure (1 atm; 0 C); R = 83.14 mbar l mol1 K1
1 cm3 (NTP) s1 = 1 sccs = 60 cm3 (NTP) min1 60 sccm = 60 std ccm = 60 Ncm3 min1
Caution: Abbreviations of Anglo-American units are inconsistent! Example: Standard cubic centimeter per minute -> sccm = sccpm = std ccm = std ccpm
1 = ... mbarl/s cm3/s **) Torrl/s Pam3/s g/a *) oz/yr *) lb/yr *) atmft3/min ml/s mft3/h mft3/min
mbarl/s 1 0,987 0,75 101 1,56 105 5,5 103 3,4 102 2,10 103 7,52 102 9,56 104 1593
cm3/s **) 1.013 1 0,76 1,01 101 1,58 105 5,6 103 3,44 102 2,12 103 760 96,6 103 1614
Torrl/s 1.33 1,32 1 1,33 101 2,08 105 7,3 103 4,52 102 2,79 103 103 1,27 105 2119
Pam3/s 10 9,9 7,5 1 1,56 106 5,51 104 3,4 103 2,09 102 7,5 103 9,54 105 15,9 103
g/a *) 6.39 106 6.31 106 4.80 106 6.41 107 1 3,5 102 2,17 103 1,34 108 4,8 103 0,612 10,2 103
oz/yr *) 1.82 104 1.79 104 1.36 104 1.82 105 28.33 1 6,18 102 3,80 107 0,136 17,34 0,289
lb/yr *) 2.94 103 2.86 103 2.17 103 2.94 104 4.57 102 16 1 6,17 106 2,18 280 4,68
atmft3/min 4.77 102 4.72 102 3.58 102 47.7 7,46 107 2,63 106 1,62 105 1 3,58 105 4,55 107 7,60 105
ml/s 1.33 103 1.32 103 103 1.33 104 208 7.34 4.52 101 2.79 106 1 127 2.12
3 5 5 6 6 2 3 8 3
mft /h 1.05 10 1.04 10 7.87 10 1.05 10 1.63 5,77 10 3,57 10 2,20 10 7,86 10 1 1,67 102
mft3/min 6.28 104 6.20 104 4.72 104 6.28 105 98 3.46 2.14 101 1.32 106 0.472 60 1
9.15 Conversion of Anglo-American units
1 m ft3 h1 = 1.04 105 stsd cc per second 1 micron cubic foot per hour = 0.0079 micron liter per second
1 cm3 s1 (NTP) = 1 atm cm3 s1 = 1 scc s1 = 1 sccss 1 micron liter per second = 0.0013 std cc per second = 1 lusec
1 atm ft3 min1 = 1 cfm (NTP) 1 micron cubic foot per minute = 1 m ft3 min1 = 1 m cuft min1 = 1m cfm
1 Pa m3/s = 1 Pa m3/s (Anglo-American) = 103 Pal/s 1 standard cc per second = 96.600 micron cubic feet per hour
*) F12 (20 C) CCl2F2M = 120.92 g mol **) (NTP) normal temperature and pressure 1 atm and 0 C
43
Fundamentals of Leak Detection
Units/symbol Conversions to
44
1 = .. Kelvin K Celsius C Fahrenheit F Rankine Ra Reaumur Re
Fahrenheit F 5/9 (F - 32) + 273.15 5/9 (F - 32) 1 F + 459.67 5/9 (F - 32) 8/10
Fundamentals of Leak Detection
Reaumur Re 5/4 Re + 273.15 5/4 Re 9/4 (Re + 32) 9/4 (Re + 32) + 459.67 1
9.16 Conversion of temperature units
Kelvin Celsius Reaumur Fahrenheit Rankine
45
Fundamentals of Leak Detection
Fundamentals of Leak Detection
i pi = ptotal
S Dalton's law
k
p V **) = const. (adiabatic) Poisson's law
m1 m2
: = M1:M2 Avogadro's law
V1 V2
m
p V = R T General gas equation
M
VM = molar volume
also: Equation of state for real gases
dp
L = T (VM, S - VM, LI) Clausius-Clapeyron equation
dT
L = Evaporation heat
T = Evaporation temperature
*) U = Temperature in C
46
Fundamentals of Leak Detection
Notes
47
Preface
Grundlagen der
Lecksuch-Technik
Herausgeber: Leybold GmbH
Kat.-Nr. 199 79_VA.01
Autoren:
Hans Rottlnder
Walter Umrath
Gerhard Voss
Leybold GmbH
Bonner Str. 498 D-50968 Kln
T +49 (0) 221-347-0
F +49 (0) 221-347-1250
info@leybold.com
www.leybold.com