Equilibrio liq-vap

P/(mmHg) T/(C) T/(K) Condiciones

30552 7.34 280.49 Punto Crtico
900 89.37 362.52
760 81 354.15 Punto de ebullicion normal
700 80.84 353.99
600 75.81 348.96
585 75 348.15 Punto de ebullicin CDMX
400 63.24 336.39
300 54.85 328
200 43.72 316.87
150 36.2639 309.4139
100 26.34 299.49
50 10.76 283.91
41 6.6 279.75 Punto triple

H vap terico= 33001.3 J/mol 2

1
=
1 1
H vap exp= 31466.74999 J/mol
2 1
P1 y T1 del punto de
1 2 2 1 1 ebullicion a 585mmHg
2 = [ ( )]1 = ( )
1 1 1 2 1

Equilibrio Sol-vap

P/(mmHg) T/(C) T/(K) Condiciones

41 6.6 279.75 Punto triple
38.8693 5 278.15
36.8351 4 277.15
34.8937 3 276.15
33.0417 2 275.15
31.2755 1 274.15
29.5919 0 273.15
22.3001 -5 268.15
16.6266 -10 263.15
8.9259 -20 253.15

H sub terico= 387710 J/mol = +

H sub exp= 34451.80879 J/mol

2 = 1 2
+
1

P1 y T1 del punto triple

Equilibrio sol-liq

P/(mmHg) T/(C) T/(K) Condiciones

900 7.13 280.28
760 6.47 279.62 Punto de fusin normal
650 6.79 279.94
585 6.7 279.85 Punto de fusin CDMX
41 6.6 279.75 Punto triple

H fus terico= 2662.6 J/mol 2

2 1 = ( )
H fus exp= 29.44128 L atm/mol 1
H fus exp= 2985.0588 J/mol
2 1
Vfus=0.0147 L/mol = ( )
2
1

P1 y T1 del punto de
(21)()
fusion a 585 mmHg 2 = 1

t (s) T (C)
0 24.6 220 8
10 24.8 230 7.8
20 24.4 240 7.6
30 23.2 250 7.5
40 21.7 260 7.5
50 20.4 270 7.4
60 19.3 280 7.3
70 18.4 290 7.3
80 17.6 300 7.1
90 16.4 310 7
100 15.3 320 6.9
110 14.4 330 6.9
120 13.9 340 6.9
130 12.9 350 6.8
140 12.2 360 6.8
150 11.5 370 6.2
160 10.9 380 6.7
170 10.3 390 6.7
180 9.7 400 6.7
190 9.1 410 6.7
200 8.7 420 6.7
210 8.3 430 6.7