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PHYSICAL CHEMISTRY
by: SHAILENDRA KR.
Meq. Approach
Classes at: -
SCIENCE TUTORIALS; Opp. Khuda Baksh Library, Ashok Rajpath, Patna
PIN POINT STUDY CIRCLE; House No. 5A/65, Opp. Mahual Kothi, Alpana Market, Patna
01. 0.2 M solution of monobasic acid is dissociated to 0.95%. Calculate its dissociation constant.
Ans: 1.8 105
02. Calculate concentration of H+ and degree of dissociation of 0.2 M acetic acid solution having
Ka = 1.8 105.
Ans: 0.0095 or 0.95 %
03. Ka for HA is 4.9 108. After making the necessary approximation. Calculate for its decimolar
solution.
(a) % dissociation. (b) OH concentration. (c) pH.
Ans: 1.43 1010
04. Nicotinic acid (Ka = 1.4 105) is represented by the formula HNiC. Calculate its percent disso-
ciation in a solution which contains 0.10 moles of nicotinic acid per 2.0 litre of solution.
Ans: 1.67 102 or 1.67 %
05. A solution of 0.01 M concentration of NH4OH is 2.6% dissociated. Calculate [H+], [OH],
[NH4+], [NH4OH] and pH of solution.
Ans: 10.4145
06. Calculate the concentration of fluoroacetic acid which is required to get [H+] = 1.50103 M . Ka
of acid = 2.6 103.
Ans: 237 103 M
07. Determine degree of dissociation of 0.05 M NH3 at 25C in a solution of pH = 11.
Ans: 2 102 or 2%
08. Calculate pH of (i) 103 N HNO3, (ii) 103 M H2SO4, (iii) 103 N H2SO4, (iv) 0.01 N HCl,
(v) 108 N HCl, (vi) 102 M HCl.
Ans: (i) pH = 3, (ii) pH = 2.6989, (iii) pH =3, (iv) pH = 2, (v) pH = 6.9586 or pH = 6.9788,(vi) pH=2
09. Calculate pH for acid solutions having [H+] as (a) [H+] = 0.05 M (b) [H+] = 5.0 M (c) [H+] = 108 M.
Ans: (a) pH = 1.3010 (b) pH = 2 (c) pH = 6.9586
10. Calculate pH for
(a) 0.001 N NaOH (b) 0.01 N Ca(OH)2 (c) 0.01 M Ca(OH)2
8 2
(d) 10 M NaOH (e) 10 M NaOH (f) 0.0008 M Mg(OH)2