TABLA DE DATOS EXPERIMENTALES.

Presin de trabajo: 0.6 kg/cm2

h (cm) g/cm3 Porciento Volumen L
peso %

Alimentacin 44 0.955 23 37
Destilado 1 16 0.932 37 34
Residuo 7.5 0.985 8 16.5
Condensado de vapor 19

Temperatura en el destilador 87C

Temperatura de salida del condensador 1 78 C

SECUENCIA DE CALCULOS
Fraccin peso a fraccin mol
0.23
( )
32
XF= 0.23 10.23 =0.1439
( )+( )
32 18

Residuo
PMmetanol = 32
PMH2O = 18
0.08
( )
32
XW= 0.08 10.08 =0.04663
( )+( )
32 18

Destilado
0.37
( )
32
XD= 0.37 10.37 =0.2483
( )+( )
32 18
Balance de materia:
F=D+W
Masa de alimentacin:
kg
F= 37L 0.955 =35.335 Kg
L

Peso molecular promedio de alimentacin:

PMF= 32 0.1439 + 18(1 0.1439) = 20.0146Kg/Kgmol

Alimentacin en Kmol
kmol
F = 35.335kg 20.0156kg =.17653 Kmol

DESTILADO

Masa de destilado:
kg
D= 34L 0.932 =31.668 Kg
L

Peso molecular promedio del destilado:

PMD= 32 (0.2483) + 18(1 0.2483) =21.4262 Kg/Kgmol

Destilado en Kmol
1kmol
D= 31.688kg 21.4762 kg=1.4755 Kmol

Residuo
F= D + W
W = F D = 1.7653 1.475 =0.289 Kmol

Relacin destilado/alimentacin
w
D/F= 1 F
0.289 Kmol D
D/F=1 1.7653 = 0.8358 (experimental)
Kmol F

Relacin D/F en funcin de las composiciones

 x x
D/F= x F xw
D w

0.14390.04663
D/F= 0.24830.04663 =0.2575 Kmol

Porcentaje de error en la relacin D/F

0.8358 0.2725
%error= x100 = 63.39%
0.8358

Volatilidad relativa

3 (1)
= = (1)
2

De acuerdo a los valores de la grfica de concentraciones se obtiene

Po metanol y(1x) 1730.52mmHg
= = x(1y) = 465.297 mmHg = 3.7192
P0 Agua

Relacin F/W con la ecuacin de Rayleigh

1 1
F/W= [ ] [ ]
1

3.71921 3.7292
F/W= [ 0.1439 ] [10.04663] = 2.43093
0.04663 10.1439

Relacin F/W con balance de materia

F/W= + 1
1.47549
F/W= + 1 = 1.83583
1.7653

Porcentaje de error en la relacin alimentacin

2.43091.8358
%error= 100 = 32.41%
1.8358
Balance de calor
Calor absorbido:
Qabs= +

Entalpia de alimentacin:

+
hLF= [ (1 ) ] [ ]
3 3 2 2

0.605 32
hLF= [( ) (0.1439) ( ) + (1 ) (1 0.1439) (18 )] [27

0] =491.284 Kcal

Entalpia del residuo

+
hLW= [ (1 ) ] [ ]
3 3 2 2

0.605 32
hLw= [( ) (0.04663) () + (1 ) (1 0.04663) (18 )]

[82 0]=1408.95 Kcal

Entalpia del destilado

+
hLD= [ (1 ) ] [ ] + [
3 3 2 2 3
+ 2 (1 )]
0.605 32
hLD= [( ) (0.2483) ( ) + (1 ) (1 0.2483) (18 )] [78


0] + [(8185.6 ) (0.2483) + (552.5 ) (1 0.2483)]=3877.76 Kcal

= (3877.76 ) (0.2483 ) + (1408.95 ) (0.04663 )


(491.284 ) (0.1439 )=987.851 Kcal

Calor suministrado:

Qs= +
Donde el gasto msico de vapor es:

Mv= (4 ) 2

Mv= (4 ) (0.385 )2 (0.19) (955 3 )=21.1236 Kg

= 547.1

Qs= (21.1236) (547.1 ) + (35.335) (491.284 ) =28916.2 Kcal

CURVA DE EQULIBRIO METANOL-AGUA

Temperatura Presin sat Presin sat agua x y

metanol
63.63 732.178 175.019 1 1
65 772.861 186.143 0.93 0.98
67 835.618 203.456 0.84 0.95
69 902.554 222.113 0.75 0.92
71 973.884 242.196 0.67 0.89
73 1049.83 263.792 0.6 0.85
75 1130.61 286.99 0.53 0.81
77 1216.46 311.882 0.46 0.77
79 1307.63 338.566 0.41 0.73
81 1404.36 367.144 0.35 0.68
83 1506.91 397.718 0.3 0.62
85 1615.54 430.398 0.25 0.56
87 1730.52 465.297 0.21 0.5
89 1852.13 502.532 0.17 0.43
91 1980.65 542.222 0.13 0.36
93 2116.39 584.492 0.1 0.28
95 2259.62 629.473 0.06 0.19
97 2410.67 677.297 0.03 0.1
99 2569.85 728.102 0 0.01
99.15 2582.12 732.037 0 0
 Constantes de Metanol Agua log P=A-(B/(t+C)
Antoine
A 8.0724 7.96681 Pt 732.1442
B 1574.99 1669.21 pt 585
C 238.8 228
1
98
0.9
0.8 93

0.7 88
0.6
83
0.5
0.4 78

0.3 73
0.2
68
0.1
63
0
0 0.5 1
0 0.2 0.4 0.6 0.8 1