Instrument Name:Instrument Tune Type:Standard Ion Ion Date:Friday, Jul 7 Time:05:38:40

1 Autotune Source:ESI Polarity:Positive 2006 PM

220K Area: 453256 120K Area: 366526
118.08579 2721.8923
Mass: 118.08579 Mass: 2721.8923
200K FWHM: 0.027 110K FWHM: 0.175
Height: 209931 Height: 116925
180K Resolution: 4428 100K
Resolution: 15563
Time: 20017.119 90K
Time: 92272.325
160K
80K
140K
Abundance

Abundance
70K
120K
60K 2722.89601
100K
50K
80K
40K
60K
30K
40K 20K
2723.90049
20K 10K
118.22103 119.08875
115.96324 120.09034
0 0
115 116 117 118 119 120 121 2719 2720 2721 2722 2723 2724 2725
m/z m/z

220K Area: 457180

Mass: 118.08582
200K FWHM: 0.027
1521.97074 2121.93242
Height: 211206
180K Resolution: 4420
Time: 20017.121
160K
2421.91339
140K
n
ace

120K
d

2721.89422
b
An
u

100K

80K

60K 2722.89738

40K

20K

0
-0 500 1000 1500 2000 2500 3000
m/z

Mass Calibration Table

Expected Mass Actual Mass Flight Time (sec) Height Resolution FWHM (m/z) Mass Error (m/z) Mass Error (ppm)
118.086255 118.086031 20.01714 210930 4461 .0265 -.00022 -1.9
322.048121 322.047703 32.40028 144287 7334 .0439 -.00042 -1.3
622.028960 622.028398 44.63633 155650 9723 .0640 -.00056 -.9
922.009798 922.008977 54.12481 175731 11055 .0834 -.00082 -.9
1221.990637 1221.989898 62.15833 183901 12438 .0983 -.00074 -.6
1521.971475 1521.970368 69.25261 196029 13179 .1155 -.00111 -.7
1821.952313 1821.951346 75.67587 157712 13887 .1312 -.00097 -.5
2121.933152 2121.932307 81.58873 187874 14293 .1485 -.00085 -.4
2421.913990 2421.912989 87.09642 149685 15126 .1601 -.00100 -.4
2721.894829 2721.893373 92.27234 115789 15660 .1738 -.00146 -.5

Tune Parameter and Setpoint Tables

Source Optical Param TOF Pulser Calibration Coeff
Capillary 4000 Fragmentor 215.0 Pusher 1250.0 #Trans. 10000 a 0.571655
Corona Current N/A Skimmer 60.0 Puller -800.0 #Points 104992 t0 1.007841
Charging Electrode N/A OCT RFV 250.0 Puller Offset 32.0 Pulse Width 125 a2 1.069 E-07
Drying Gas 7.0 OCT DC1 31.50 Acc Focus -1940.0 Pulse Delay 25
b2 -2.652 E-13
Drying Gas Actuals 6.9 OCT DC2 33.10 Mirror Front -6500.0
c2 1.400 E-19
Neb Press 15.0 Ion Focus -110.0 Mirror Mid -1372.5
Neb Press Actuals 15.0 Horiz Q 25.50 Mirror Back 1650.0 d2 -2.945 E-26
Gas Temp 300 Vert Q 25.50 MCP 650 e2 2.770 E-33
Gas Temp Actuals 300 Top Slit 16.50 PMT 661 f2 -9.690 E-41
Vapor Temp N/A Bottom Slit 16.70 Amp Offset 1961
Vapor Temp Actuals N/A Slicer -12.00 Rough Vac (Torr) 2.3
High Vac (Torr) 1.3 E-06

ND - Not Detected