Tabla B.

2 Capacidades calorificast
Forma I: Cp[kJ/mol0C)J o [kJ/(mol K)] =a+ bT+ cT2 + dT3
Forma 2: Cp[kJ/mol C)] o [kJ/(molK)] =a+ bT+ cT- 2

Ejemplo: (Cp)acctona(g) = 0.07196 + (20.10 X I o-5)T - (12.78 X I o- 8)T 2

+ (34.76 X I o- 12)T3, dondc T esta en C.

Nola: Las formulas para gases se aplican en forma estricta a presiones lo bastante bajas para que la ecuaci6n de estado de los gases ideales sea valida.

Rango
Peso Unidad (unidades
Compuesto Formula molecular Estado Forrna de temp. a X 103 b X 105 CX 10 8 dX 1Q l2 de 7)
Acetileno C2H2 26.04 g oc 42.43 6.053 -5.033 18.20 0-1200
Acetona CH3COCH3 58.08 I oc 123.0 18.6 -30-60
g oc 7 l.96 20.10 -12.78 34.76 0-1200
Acido nitrico NH03 63.02 oc 110.0 25
Acido suln1rico H2S04 98.08 oc 139.1 15.59 10-45
Agua T-120 18.016 oc 75.4 0-100
"'a oc 33.46 0.6880 0.7604 -3.593 0-1500
Aire 29.0 g oc 28.94 0.4147 0.3191 -1.965 0-1500
g K 28.09 0.1965 0.4799 -1.965 273-1800
Alcohol ctilico (etanol) C2 H50H 46.07 oc 103.1 0
oc 158.8 100
g oc 61.34 15.72 -8.749 19.83 0-1200
Alcohol metilico CH30H 32.04 oc 75.86 16.83 0-65
(metanol) g oc 42.93 8.301 -1.87 -8.03 0-700
Amoniaco NH3 17.03 g oc 35.15 2.954 0.442 l -6.686 0-1200
Azufre s 32.07 C K 15.2 2.68 273-368
(R6rnbico)
C K 18.3 1.84 368-392
(Monoclinico)

(con tim,a)
Tabla B.2 (Continuaci6n.)

Rango >
Peso Unidad (unidades O

Compuesto Formula molecular Estado Forma de temp. aX 103 bX 105 C X 108 dX 10 12 de 7) ;;

to
Benceno C6H 6 78.11 oc 126.5 23.4 6-67
g 1 oc 74.06 32.95 -25.20 77.57 0-1200
Bromuro de hidr6geno HBr 80.92 g oc 29.10 -0.0227 0.9887 -4.858 0-1200
n-Butano C4H 10 58.12 g l oc 92.30 27.88 -15.47 34.94 0-1200
Carbonato de calcio CaC03 100.09 C 2 K 82.34 4.975 -12.87 X 10 10 - 273-1033
Carbonato de sodio Na2C03 105.99 C 1 K 121 288-371
Carbonato de sodio Na2C03 286.15 C 1 K 535.6 298
decahidratado lOH20
Carbono C 12.01 C 2 K 11.18 t.095 -4.891 X I010 273-1373
Carburo de calcio CaC2 64.10 C 2 K 68.62 1.19 -8.66 X l0 10 - 298-720
Cianuro de hidr6geno HCN 27.03 g oc 35.3 2.908 1.092 0-1200
Ciclohexano C6H12 84.16 0
b oc 94.140 49.62 -31.90 80.63 0-1200
Ciclopentano C5H 10 70.13 g oc 73.39 39.28 -25.54 68.66 0-1200
Cloro C12 70.91 b
a oc 33.60 1.367 -1.607 6.473 0-1200
Cloruro de hidr6geno HCI 36.47 g oc 29.13 -0.1341 0.9715 -4.335 0-1200
Cloruro de mag nesio MgCl2 95.23 C K 72.4 1.58 273-991
Cobre Cu 63.54 C K 22.76 0.6117 273-1357
Cumeno C9H 1 2 120.19 g oc 139.2 53.76 -39.79 120.5 0-1200
(isopropi lbenceno)
Di6xido de azufre S02 64.07 g oc 38.91 3.904 -3.104 8.606 0-1500
Di6xido de carbono CO2 44.01 g oc 36.11 4.233 -2.887 7.464 0-1500
Di6xido de nitr6g eno N02 46.01 g oc 36.07 3.97 -2.88 7.87 0-1200
Etano C2H 6 30.07 g oc 49.37 13.92 -5.816 7.280 0-1200
Etileno C2H4 28.05 g oc +40.75 11.47 -6.891 17.66 0-1200
Formaldehido CH20 30.03 g oc 34.28 4.268 0.0000 -8.694 0-1200
Helio He 4.00 g oc 20.8 0-1200
n-Hexano C6H14 86.17 oc 216.3 20-100

(contimia)
 g oc 137.44 40.85 -23.92 57.66 0-1200
Hidr6geno H2 2.016 g oc 28.84 0.00765 0.3288 -0.8698 0-1500
Hidr6xido de calcio Ca(OH)i 74.10 C K 89.5 276-373
lsobutano C4Hio 58.12 g oc 89.46 30.13 -18.91 49.87 0-1200
lsobuteno C4Hs 56.10 "'
0 oc 82.88 25.64 -17.27 50.50 0-1200
Metano CH4 16.04 g oc 34.31 5.469 0.3661 -11.00 0-1200
g K 19.87 5.021 1.268 -11.00 273-1500
Metilciclohexano C1H14 98.18 g oc 121.3 56.53 -37.72 100.8 0-1200
Metilciclopentano C6H 12 84.16 g oc 98.83 45.857 -30.44 83.81 0-1200
Monoxide de carbono co 28.01 g oc 28.95 0.4110 0.3548 -2.220 0-1500
Nitr6geno N2 28.02 g oc 29.00 0.2199 0.5723 -2.871 0-1500
6xido de calcio Cao 56.08 C 2 K 41.84 2.03 -4.52 X 10 10
273-1173
6xido de magnesia MgO 40.32 C 2 K 45.44 0.5008 -8.732 X 10 1 0 273-2073
6xido ferrico Fe2O3 159.70 C 2 K 103.4 6.711 -17.72 x10 10 273-1097
6xido nitrico NO 30.01 "'
a oc 29.50 0.8188 -0.2925 0.3652 0-3500
6xido nitroso N2O 44.02 g oc 37.66 4.151 -2.694 10.57 0-1200
Oxi geno 02 32.00 "'a oc 29.10 1.158 -0.6076 l .311 0-1500
n-Pentano CsH12 72.15 oc 155.4 43.68 0-36
g oc 114.8 34.09 -18.99 42.26 0-1200
Propane C3Hs 44.09 g oc 68.032 22.59 -13.11 31.71 0-1200
PropiJeno C3H6 42.08 g oc 59.580 17.71 -10.17 24.60 0-1200
Tetracloruro de carbono CCl4 153.84 I K 93.39 12.98 273-343
Tetr6xido de nitr6geno N2O4 92.02 g oc 75.7 12.5 -11.3 0-300
:;;i
Toluene C1Hs 92.13 I oc 148.8 32.4 0-110
g oc 94.18 38.00 -27.86 80.33 0-1200
Trioxide de azufre SO3 80.07 g oc 48.50 9.188 -8.540 32.40 0-1000
-0

-0
Sulfate de amonio (NH4) 2SO4 132.15 C K 215.9 275-328 ;;;
..,
Cl.
Sulfuro de hidr6 geno H2S 34.08 g oc 33.51 1.547 0.3012 -3.292 0-1500 Cl.

aAdaptado en parte de D. M. Himmelblau, Basic Principles and Calculations in Chemical Engineering, 3a. cdici6n, 1974, tabla E.1. Adaptado con autorizaci6n !!?.
de Prentice-Hall, Inc., Englewood Cliffs, NJ. ..,