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BATCH SEDIMENTATION
Badiang, John Piox
Banting, Saturnino Jr.
Molinos, Jasper
Introduction
Sedimentation is the partial separation or concentration of suspended solid particles from
a liquid by gravity settling. This field may be divided into the functional operations of thickening
and clarification. The primary purpose of thickening is to increase the concentration of suspended
solids in a feed stream, while that of clarification is to remove a relatively small quantity of
suspended particles and produce a clear effluent. These two functions are similar and occur
simultaneously, and the terminology merely makes a distinction between the primary process
results desired (Green & Perry, 2008).
When a particle is at a sufficient distance from the walls of the container and from other
particles so that its fall is not affected by them, the process is called free settling. Interference is
less than 1% if the ratio of the particle diameter to the container diameter is less than 1:200 or if
the particle concentration is less than 0.2 vol% in the solution. When the particles are crowded,
they settle at a lower rate and the process is called hindered settling (Geankoplis, 2014).
A particle falling under the action of gravity will accelerate until the drag force balances
gravitational force, after which it falls at a constant terminal or free-settling velocity. For spherical
particles, the basic principle behind the settling of particles is given by Stokes law (Green & Perry,
2008):
2 ( )
=
18
Where = free-settling velocity
= particle diameter
= particle density
= liquid density
= liquid viscosity
For many cases of settling, a large number of particles are present, and the surrounding
particles interfere with the motion of individual particles. The velocity gradients surrounding each
particle are affected by the close presence of other particles. The particles settling in the liquid
displace the liquid, and an appreciable upward velocity of the liquid is generated. Hence, the
velocity of the liquid is appreciably greater with respect to the particle than with respect to the
apparatus itself (Geankoplis, 2014):
2 ( ) 2
= ( )
18
Where 2 = volume fraction of the slurry mixture occupied by the liquid
1
= dimensionless quantity which is equal to 101.82(1)
During the settling of particles, different compositions, wherein there are differe nt
concentrations of particles, could be observed within the sedimentation tank. These differences of
compositions are termed as zones. Different zones are shown in figure 1:
Figure 1. Sedimentation zones during slurry settling through time (Slurries Sedimentation of
Slurries, n.d.)
Zone A is the constant composition zone, where the suspension moves at a uniform rate.
Free settling occurs in this zone. Zone B is variable composition zone, where hindered settling
occurs. Concentration of the particles does not remain the same in different areas. Zone C is the
sediment zone. Solid particles which are obtained at the end of sedimentation process are found
here. Zone D is the clear liquid zone, where it is free of particles. As the interface of the particles
moves down, sludge builds up and the point where two levels becomes equal is known as Critical
Point as shown in figure 2: (XnaXia, 2012). The critical point is shown at point C 2 .
Figure 2. Graphic analysis of interface (Sedimentation)
Objectives
This experiment is done in order to establish the settling curve of a cornstarch slurry. Thus
the material that will be used in the experiment will be limited only to cornstarch particles. The
cornstarch that will be utilized in the experiment will be purchased at the local market of Miagao,
Iloilo.
The effect of cornstarch slurry concentration on its settling rate will also be determined in
the experiment, thus concentration of 25 g/L, 50 g/L, 75 g/L, and 100 g/L will be prepared and
used in the experiment. Concentrations beyond 100 g/L will be out of the scope of the study since
bigger concentration may result in a more hindered settling, thus requiring a lot of time to let it
settle. Also, concentrations less than 25 g/L are not considered since the mixture may be negligib le
and settling may not properly occur. Only batch sedimentation process will be conducted in the
experiment using 1 L graduated cylinders.
The experiment will only cover the determination of the following: establishment of
settling curve, effect of concentration on settling rate, and critical settling rate. The average particle
diameter on the other hand will not be determined because the particle density, liquid density, and
liquid viscosity are outside the scope of the experiment.
50
z, Interphase Height (cm)
40
Slurry A
30
Slurry B
Slurry C
20
Slurry D
10
0
0 500 1000 1500 2000
t (min)
Figure 3. Plot of the interphase height as a function of time with its corresponding concentration.
0.16
0.14
0.12
Slurry A
0.1
Slurry B
0.08
Slurry C
0.06 Slurry D
0.04
0.02
0
0 200 400 600 800 1000 1200 1400 1600
Figure 4. Plot of settling rates as a function of time with its corresponding concentration.
Interphase Height vs Time
60
50
z, Interphase Height (cm)
40
Slurry A
30
Slurry B
10
0
0 500 1000 1500 2000
t (min)
Conclusion
The settling curve for corn starch slurry at various concentrations was established. Varying
concentrations of the slurry definitely affect its settling rate. The settling curve will change
depending on how concentrated or diluted the slurry is, with the steepness of the slope
corresponding to how fast the solid particles settled. Settling time for concentrated slurries is
longer compared to the dilute ones. Critical settling point is achieved faster for dilute slurry than a
concentrated one, which in turn will make it enter the compression stage faster.
Recommendations
In order to achieve an experiment with more accurate data, the group recommend the
following:
(a) It is recommended to use a graduated cylinder with smaller increment of the volume of
graduation in order to accurately read the volumes during the experiment
(b) Do not conduct the sedimentation experiment in LR4 since no levelled surface is
available in LR4; place the graduated cylinders in an equally levelled surface in order
to accurately measure the volumes
(c) Use an automatic measuring device that can monitor the volume of the clear zone,
transition zone, and settled solids over a wide range of time.
(d) Use another sample for sedimentation process
(e) Increase the trial for every concentration
References
Geankoplis, C. J. (2014). Transport Processes & Separation Processes Principles (Includes Unit
Operations). Pearson Educated LImited: pp 931-934.
Green, D., & Perry, R. (2008). Perry's Chemical Engineer's Handbook. The McGraw- Hill
Companies, Inc.:p22-64
Sedimentation. (n.d.). Retrieved from Wastewater Engineering Handbook.on February 4, 2017.
Slurries Sedimentation of Slurries. (n.d.). Retrieved from Big Chemical Encycloped ia :
http://chempedia.info/page/061113151247010240228226186051060248009217054174/
XnaXia, V. (2012, April 19). Sedimentation. Retrieved from Engineering: Its a Learning &
Informative blog for Engineering Students:
http://engrsl.blogspot.com/2012/04/sedimentation.html
Appendices
A. Raw Data
For Slurry A:
Internal diameter of graduated cylinder: 4.92 cm
Cross-sectional are of graduated cylinder:
= 2
4
= 4.922
4
= 19.002 2
Conversion of volume to height:
=
1000 3
=
19.002 2
= 52.626
Determination of settling rate:
1
1 = 2
2 1
52.3629 52.626
1 =
42
1 = 0.13156
C. Photos