Appendix C

Antoine Constants

Compiled From
R.C. Reid, J.M. Prausnitz and T.K. Sherwood, The Properties of Gases and
Liquids, 3rd Ed., McGraw-Hill, New York, 1977.
The vapor pressure is expressed as a function of temperature in the form
B
ln P vap = A ,
T +C
where P vap is in bar and T is in K.

The Thermodynamics of Phase and Reaction Equilibria. DOI: http://dx.doi.org/10.1016/B978-0-44-4594976.00017-7

2013 Elsevier B.V. All rights reserved. 667
668 Tosun

Name A B C Tmax Tmin

Elements
Argon 8.6128 700.51 5.84 94 81
Bromine 9.2239 2582.32 51.16 354 259
Chlorine 9.3408 1978.32 27.01 264 172
Hydrogen 7.0131 164.90 3.19 25 14
Nitrogen 8.3340 588.72 6.60 90 54
Oxygen 8.7873 734.55 6.45 100 63
Hydrocarbons
Acetylene 9.7279 1637.14 19.77 202 194
Benzene 9.2806 2788.51 52.36 377 280
n-Butane 9.0580 2154.90 34.42 290 195
Cumene 9.3520 3363.60 63.37 454 311
Cyclohexane 9.1325 2766.63 50.50 380 280
Cyclopentane 9.2372 2588.48 41.79 345 230
n-Decane 9.3912 3456.80 78.67 476 330
Ethane 9.0435 1511.42 17.16 199 130
Ethylbenzene 9.3993 3279.47 59.95 450 300
Ethylene 8.9166 1347.01 18.15 182 120
n-Heptane 9.2535 2911.32 56.51 400 270
1-Heptene 9.2692 2895.51 53.97 400 265
n-Hexane 9.2164 2697.55 48.78 370 245
Isobutane 8.9179 2032.73 33.15 280 187
Isopentane 9.0136 2348.67 40.05 322 216
Methane 8.6041 597.84 7.16 120 93
Naphthalene 9.5224 3992.01 71.29 525 360
n-Octane 9.3224 3120.29 63.63 425 292
1-Octene 9.3428 3116.52 60.39 420 288
n-Pentane 9.2131 2477.07 39.94 330 220
Propane 9.1058 1872.46 25.16 249 164
Propylene 9.0825 1807.53 26.15 240 160
Styrene 9.3991 3328.57 63.72 460 305
Toluene 9.3935 3096.52 53.67 410 280
m-Xylene 9.5188 3366.99 58.04 440 300
o-Xylene 9.4954 3395.57 59.46 445 305
p-Xylene 9.4761 3346.65 57.84 440 300
Antoine Constants 669

Name A B C Tmax Tmin

Inorganic compounds
Ammonia 10.3729 2132.50 32.98 261 179
Carbon dioxide 15.9696 3103.39 0.16 204 154
Carbon disulfide 9.3642 2690.85 31.62 342 228
Carbon monoxide 7.7484 530.22 13.15 108 63
Carbon tetrachloride 9.2540 2808.19 45.99 374 253
Chloroform 8.3530 2696.79 46.16 370 260
Hydrogen chloride 9.8838 1714.25 14.45 200 137
Hydrogen sulfide 9.4838 1768.69 26.06 230 190
Nitric oxide 13.5112 1572.52 4.88 140 95
Nitrous oxide 9.5069 1506.49 25.99 200 144
Sulfur dioxide 10.1478 2302.35 35.97 280 195
Sulfur trioxide 14.2201 3995.70 36.66 332 290
Water 11.6834 3816.44 46.13 441 284
Organic compounds
Acetaldehyde 9.6729 2465.15 37.15 320 210
Acetic acid 10.1878 3405.57 56.34 430 290
Acetone 10.0311 2940.46 35.93 350 241
Acetonitrile 9.6672 2945.47 49.15 390 260
Aniline 10.0546 3857.52 73.15 500 340
n-Butanol 10.5958 3137.02 94.43 404 288
Chlorobenzene 9.4474 3295.12 55.60 420 320
Diethyl ether 9.4626 2511.29 41.95 340 225
Dimethyl ether 10.2265 2361.44 17.10 265 179
Ethanol 12.2917 3803.98 41.68 369 270
Ethyl acetate 9.5314 2790.50 57.15 385 260
Ethylene oxide 10.1198 2567.61 29.01 310 200
Formaldehyde 9.8573 2204.13 30.15 271 185
n-Heptanol 8.6866 2626.42 146.6 449 333
Isobutanol 10.2510 2874.73 100.3 388 293
Isopropanol 12.0727 3640.20 53.54 374 273
Methanol 11.9673 3626.55 34.29 364 257
Methyl acetate 9.5093 2601.92 56.15 360 245
Methyl ethyl ketone 9.9784 3150.42 36.65 376 257
Phenol 9.8077 3490.89 98.59 481 345
n-Propanol 10.9237 3166.28 80.15 400 285