A.

Analisi Data
1. Penentuan Ksp dan s pada suhu kamar
Reaksi:
PbCl2(s) Pb2+ + 2 Cl-
a. Tabung 1
Dik : V Pb(NO3)2 = 10 mL
V KCl = 0,5 mL
[Pb(NO3)2] = 0,075 M
[KCl] = 1,0 M
Dit : Ksp dan S =.....?
Penye:
V total = V Pb(NO3)2 + V KCl
= 10 ml + 0,5 ml
= 10,5 ml
(3)2 (3)2
[Pb2+] =
0,075 10
= 10,5

= 0,0714 M

[Cl-] =
0,5 1,0
= 10,5

= 0,0476 M
PbCl2 Pb2+ + 2 Cl-
Ksp PbCl2 = (0,0714M) (0,0476M)2
= 1,61 x 10-4 M3
PbCl2 Pb2+ + 2 Cl-
S S 2S
Ksp = 4 S3

= 4
1,61 104 3
= 4

= 0,034 M
b. Tabung 2
Dik : V Pb(NO3)2 = 10 mL
 V KCl = 1 mL
[Pb(NO3)2] = 0,025 M
[KCl] = 1,0 M
Dit : Ksp dan S =.....?
Penye:
V total = V Pb(NO3)2 + V KCl
= 10 ml + 1,0 ml
= 11 ml
(3)2 (3)2
[Pb2+] =
0,075 10
= 11

= 0,0681 M

[Cl-] =
1 1,0
= 11

= 0,0909 M
PbCl2 Pb2+ + 2 Cl-
Ksp PbCl2 = (0,0681M) (0,0909M)2
= 5,61 x 10-4 M3
PbCl2 Pb2+ + 2 Cl-
S S 2S
Ksp = 4 S3

= 4
5,61 104 3
= 4

= 0,052 M
c. Tabung 3
Dik : V Pb(NO3)2 = 10 mL
V KCl = 1,5 mL
[Pb(NO3)2] = 0,025 M
[KCl] = 1,0 M
Dit : Ksp dan S =.....?
Penye:
V total = V Pb(NO3)2 + V KCl
= 10 ml + 1,5 ml
 = 11,5 ml
(3)2 (3)2
[Pb2+] =
0,075 10
= 11,5

= 0,0672 M

[Cl-] =
1,5 1,0
= 11,5

= 0,1304 M
PbCl2 Pb2+ + 2 Cl-
Ksp PbCl2 = (0,0672M) (0,1304M)2
= 1,1086 x 10-3 M3
PbCl2 Pb2+ + 2 Cl-
S S 2S
Ksp = 4 S3

= 4
1,1086 103 3
= 4

= 0,07 M
d. Tabung 4
Dik : V Pb(NO3)2 = 10 mL
V KCl = 2 mL
[Pb(NO3)2] = 0,025 M
[KCl] = 1,0 M
Dit : Ksp dan S =.....?
Penye:
V total = V Pb(NO3)2 + V KCl
= 10 ml + 2,0 ml
= 12 ml
(3)2 (3)2
[Pb2+] =
0,075 10
= 12

= 0,0625 M

[Cl-] =
 2 1,0
= 12

= 0,1666 M
PbCl2 Pb2+ + 2 Cl-
Ksp PbCl2 = (0,0625M) (0,1666M)2
= 1,734 x 10-3 M3
PbCl2 Pb2+ + 2 Cl-
S S 2S
Ksp = 4 S3

=
4
1,734 103 3
= 4

= 0,075 M

1. Penentuan Ksp dari 5 PCl2 (perlakuan 3)

a. Tabung 1
Diketahui : [Pb(NO3)2] = 0,075 M
[KCl] = 1,0 M
V Pb(NO3)2 = 10,00 mL
V KCl = 1,50 mL
T = 45 + 273 = 318 K
Ditanyakan : Qsp =.... ?
Penyelesaian :
n Pb(NO3)2 = M x V
= 0,075 M x 10,00 mL
= 0,75 mmol
n KCl =MxV
= 1,0 M x 1,50 mL
= 1,50 mmol
Pb(NO3)2 + 2KCl PbCl2 + 2KNO3
M: 0,75 mmol 1,5 mmol - -
T : 0,75 mmol 1,5 mmol 0,75 mmol 1,5 mmol
S : - - 0,75 mmol 1,5 mmol
 n
[PbCl2] =
V total
0,75 mmol
=
11,5 mL

= 0,065 M

PbCl2 Pb2+ + 2Cl-

Ksp = [Pb2] + [Cl-]2
= (s) + (2s)2
= 4s3
= 4 (0,065 M)3
= 1,098 x 10-3 M3
ln Ksp = ln 1,098 x 10-3 M3
= - 6,8142
1
318 K =
T
1
=
318 K

= 3,14 x 10-3 K-1

b. Tabung II
Diketahui : [Pb(NO3)2] = 0,075 M
[KCl] = 1,0 M
V Pb(NO3)2 = 10,00 mL
V KCl = 2,00 mL
T = 47 + 273 = 320 K
Ditanyakan : Qsp =.... ?
Penyelesaian :
n Pb(NO3)2 = M x V
= 0,075 M x 10,00 mL
= 0,75 mmol

n KCl =MxV
= 1,0 M x 2,00 mL
= 2 mmol
 Pb(NO3)2 + 2KCl PbCl2 + 2KNO3
M: 0,75 mmol 2 mmol - -
T : 0,75 mmol 1,5 mmol 0,75 mmol 1,5 mmol
S : - 0,5 mmol 0,75 mmol 1,5 mmol

n
[PbCl2] =
V total
0,75 mmol
=
12 mL

= 0,0625 M
n
[KCl] =
V total

0,5 mmol
=
12 mL

= 0,0416 M

PbCl2 Pb2+ + 2Cl-

Ksp = [Pb2] + [Cl-]2
= (s) + (2s + b)2
= (o,o625 M) (2 . 0,0625 M + 0,0416 M)2
= 1,735 x 10-3 M3
ln Ksp = ln 1,735 x 10-3 M3
= - 6,3567
1
320 K =
T
1
=
320 K

= 3,12 x 10-3 K-1

c. Tabung III
Diketahui : [Pb(NO3)2] = 0,075 M
[KCl] = 1,0 M
V Pb(NO3)2 = 10,00 mL
V KCl = 2,50 mL
 T = 47 + 273 = 320 K
Ditanyakan : Qsp =.... ?
Penyelesaian :
n Pb(NO3)2 = M x V
= 0,075 M x 10,00 mL
= 0,75 mmol

n KCl =MxV
= 1,0 M x 2,50 mL
= 2,5 mmol

Pb(NO3)2 + 2KCl PbCl2 + 2KNO3

M: 0,75 mmol 2,5 mmol - -
T : 0,75 mmol 1,5 mmol 0,75 mmol 1,5 mmol
S : - 1 mmol 0,75 mmol 1,5 mmol

n
[PbCl2] =
V total
0,75 mmol
=
12,5 mL

= 0,06 M
n
[KCl] =
V total
1 mmol
=
12,5 mL

= 0,086 M
PbCl2 Pb2+ + 2Cl-
Ksp = [Pb2] + [Cl-]2
= (s) + (2s + b)2
= (0,06 M) (2 . 0,06 M + 0,08M)2
= (0,06 M) (0,04 M2)
= 2,4 x 10-3 M3

ln Ksp = ln 2,4 x 10-3 M3

= - 6,0322
 1
320 K =
T
1
=
320 K

= 3,12 x 10-3 K-1

d. Tabung IV
Diketahui : [Pb(NO3)2] = 0,075 M
[KCl] = 1,0 M
V Pb(NO3)2 = 10,00 mL
V KCl = 3,00 mL
T = 71 + 273 = 344 K
Ditanyakan : Qsp =.... ?
Penyelesaian :
n Pb(NO3)2 = M x V
= 0,075 M x 10,00 mL
= 0,75 mmol
n KCl =MxV
= 1,0 M x 3,00 mL
= 3 mmol

Pb(NO3)2 + 2KCl PbCl2 + 2KNO3

M: 0,75 mmol 3 mmol - -
T : 0,75 mmol 1,5 mmol 0,75 mmol 1,5 mmol
S : - 1,5 mmol 0,75 mmol 1,5 mmol

n
[PbCl2] =
V total
0,75 mmol
=
13 mL

= 0,0576 M
n
[KCl] =
V total
1,5 mmol
=
13 mL
 = 0,1153 M
PbCl2 Pb2+ + 2Cl-
Ksp = [Pb2] + [Cl-]2
= (s) + (2s + b)2
= (0,0576 M) (2 . 0,0576 M + 0,1153M)2
= 3,060 x 10-3 M3

ln Ksp = ln 3,060 x 10-3 M3

= - 5,7893
1
344 K =
T
1
=
344 K

= 2,90 x 10-3 K-1

e. Tabung V
Diketahui : [Pb(NO3)2] = 0,075 M
[KCl] = 1,0 M
V Pb(NO3)2 = 10,00 mL
V KCl = 3,50 mL
T = 74 + 273 = 347 K
Ditanyakan : Qsp =.... ?
Penyelesaian :
n Pb(NO3)2 = M x V
= 0,075 M x 10,00 mL
= 0,75 mmol
n KCl =MxV
= 1,0 M x 3,50 mL
= 3,5 mmol

Pb(NO3)2 + 2KCl PbCl2 + 2KNO3

M: 0,75 mmol 3,5 mmol - -
T : 0,75 mmol 1,5 mmol 0,75 mmol 1,5 mmol
S : - 2 mmol 0,75 mmol 1,5 mmol
 n
[PbCl2] =
V total
2 mmol
=
13,5 mL

= 0,0576 M
n
[KCl] =
V total
0,75 mmol
=
13,5 mL

= 0,0556 M
PbCl2 Pb2+ + 2Cl-
Ksp = [Pb2] + [Cl-]2
= (s) + (2s + b)2
= (0,0556 M) (2 . 0,0556 M + 0,11481M)2
= 3,738 x 10-3 M3

ln Ksp = ln 3,738 x 10-3 M3

= - 5,5892
1
347 K =
T
1
=
347 K

= 2,88 x 10-3 K-1

Grafik