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By Dan Randall
Datacolor International
Charlotte, NC
Introduction
Color is defined as the sensation experienced or solution up to a light and judging whether they are of
caused by light reflected from or transmitted through equal strength and shade, except that the absorptiometer
objects. In the strict sense, we cannot directly measure provided a method of adjusting the thickness or path
perceived color, however we can measure and width so that this change in width could be read from a
subsequently calculate certain factors which are scale. In measuring reflected light from opaque
responsible for producing this sensation of color. The materials such as textiles, the first instruments were
quantification of the color properties of textile materials reflectometers developed around 1915-1920. These
is of great economic value in industry and instruments early instruments were designed to closely simulate the
are employed to some degree in almost every textile visual process as depicted in Fig. 1
operation involved in textile coloration.
The first devices for measuring color were The beginning of reflectance spectrophotometry dates
absorptiometers which were used to determine by visual back to 1928 when A.C. Hardy2 , Professor of Optics at
inspection whether two solutions were of equal color. M.I.T. began a project to produce the first
This is very similar to holding two glass cylinders of dye spectrophotometer specifically for the measurement of
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reflectance. Commercialization of Hardys design began Applications for Colorimeters
in 1935 when General Electric introduced the General
Electric Recording Spectrophotometer (GERS). This Since colorimeters are overall simpler to build than
instrument became the much needed reference spectrophotometers, they are usually lower in cost. As
spectrophotometer and provided the basis for modern such, they are commonly used as quality control
industrial color measurement. The elements of the instruments in applications such as color difference,
original Hardy are essentially the same as those used strength determination, fastness determination, shade
today even though dramatic changes have taken place in sorting, to name a few. The cost advantage and
their design. As in the visual model , the basic elements simplicity must however be weighed against several
of the spectrophotometer are the light source, the object serious disadvantages. Firstly, the colorimeter measures
being measured, a means of dispersing the light, and a the tri-stimulus values for one illuminant and one
detection system as shown in Fig. 2. observer. As such, it is not possible to detect and
quantify metamerism. Thus in practice, the colorimeter
is used in areas where the standard and the measured
batch are non-metameric such as in checking production
batches against a production standard made with the
lamp same dyes.
detector
slit
X Y Z
prism lamp
photo-detectors
a r g b filters
object
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Colorimeters
.
As the first measuring devices, colorimeters were crucial Fig. 3 Diagram of tristimulus colorimeter
in the development of the science of color, or
colorimetry. A colorimeter is a device of fairly simple
design based upon the visual concepts of color. The
sample is illuminated at a 45 angle relative to the
Spectrocolorimeters
perpendicular line to the plane of the mounted sample.
The reflected light is measured directly perpendicular to
A spectrocolorimeter is somewhat of a hybrid instrument
the sample through a series of three and sometimes four
which is capable of providing colorimetric data such as
colored filters which represent the relative amounts of
X,Y,Z or CIEL*a*b* values for various standard
red, green, and blue light reflected from the sample.
illuminants. In this regard, they are more capable qualtiy
More specifically these filters are designed to ideally
control instruments than colorimeters. They are
simulate the three functions, x,y,z for the Standard
generally priced only slightly higher than tri-stimulus
Observer so that the instrument directly measures the
colorimeters, but less than most spectrophotometers.
three Tristimulus values X,Y,Z for the specific illuminant
This price differential has been practically eliminated in
being used. This design is shown in Fig 3.
todays spectrophotometers, and as a result the spectro-
colorimeter does not enjoy the niche between the two.
The spectrocolorimeter is by design, a spectrophotometer
except that it does not output spectral data (%R) at the
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various wavelengths. These instruments are almost
exclusively used for applications of quality control.
Spectrophotometers ref. spectrometer
mirror
lamp
Spectrophotometers differ from colorimeters in that they
measure reflectance, transmittance, or absorbance for
reference beam
various wavelengths in the spectrum. In the case of
reflectance measurement, the quantity measured is specular port
computer
termed Reflectance Factor and is defined as the sample beam
reflectance of the sample at a given wavelength
compared to the reflectance of the perfect diffuse white sphere
measured under the exact same conditions. This is transmission
sample cell
expressed in the following equation: sample spectrometer
Designs of Spectrophotometers
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The first angle given is the angle of illumination relative determination of color change such as fastness and
to a perpendicular drawn to the plane of the sample to staining testing. It is often said that a 45/0 instrument
be measured. This perpendicular is the normal angle, or measures not only color difference but also some
0 deg angle. The second angle is the viewing angle attributes of appearance such as surface gloss because of
again expressed relative to the normal angle for the its directional illumination(45/0) or viewing (0/45).
sample being meaured. The term diffuse is used to While the instrument does not directly measure these
indicate that the illumination or viewing is not directional geometric attributes, it is no doubt more sensitive to
but is rather diffuse, usually by the use of an integrating surface texture as is illustrated in the following example:
sphere.
Take two samples A and B which are printed on the
While these are the official C.I.E. recommended same small flat-bed machine. To avoid discussions of
geometries, a great deal of variation is allowed in pigment printing density and penetration, we will print
commercial instruments. When A.C. Hardy built his both samples with acid dyes using the same dye mix
first spectrophotometer he found that the surface texture however, sample A is printed on a very low gloss (de-
of textile samples lead to poor reproducibility in lustered) nylon, whereas sample B is printed on a highly
measurement. As a result, he developed an integrating glossy nylon. Now a 45/0 instrument will measure a
sphere which provided diffuse illumination thereby fairly large color difference (2-3 dE CIELAB) because
reducing the variability due to surface texture. In many the glossy substrate will give much higher reflectances
45/0 instruments today, this problem has been resolved but lower chroma or saturation. On a diffuse/0
by the use of a circumferential ring used either in the instrument with the specular component included, the
illumination or in the detection mode as depicted in Fig same samples will show little color difference (< 0.40 dE
6. This geometry is termed 45/0 Circumferential to CIELAB) because the diffuse illumination creates such
differentiate it from the bi-directional 45/0 geometry. multiple reflectances that the effects of the gloss are
minimized. The question then becomes What do you
really want to measure?. For this reason, most
spectrometer instruments for color formulation are diffuse/0 since the
colorist wants to measure strictly color, especially when
standards are often not dyed or printed on the same
substrate as requested for the match. Likewise, in many
illumination ring inspection areas, it is necessary to verify both the
geometric quality and color, and in these cases a 45/0 or
0/45 will provide the best assessment.
450
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The integrating sphere may be, in theory, of any measurement, it has much lower energy in the UV-Violet
diameter provided the sample port is not more than 10% region compared to daylight. This could be a
of the total area of the sphere. Bench-top instruments disadvantage when measuring white samples treated with
usually have a 3-6 diameter, whereas a portable may use fluorescent whitening agents where sufficient UV energy
a sphere as small as two inches. Their sole purpose is to is needed to excite the fluorescing agent. For this
create illumination which is uniformly diffuse at the reason, some instruments have been fitted with a
point at which at sample is placed. The inside of the secondary UV source such as deuterium to achieve near-
sphere is coated with multiple layers of Barium Sulfate daylight illumination.
which is highly reflective (>90% Reflectance) at all
wavelengths. Despite its high reflectance, Barium
Sulfate is not ideal in that the coating is not extremely Xenon Discharge Lamps
durable and tends to yellow over time. Instruments with
double-beams can compensate for this loss in sphere Xenon lamps have been in use since the 1970s in
efficiency, however re-coating the sphere is advisable instruments made by Kollmorgen (Macbeth), Zeiss, and
every few years. Datacolor. Xenon has many advantages and a few
disadvantages. Among the advantages, xenon is a good
daylight simulator as shown in Fig 7. In the UV region,
Light Sources in Instruments un-filtered xenon is much higher than daylight (D65) and
usually requires the use of a UV filter to approximate
For non-fluorescent materials, the reflectance factors are daylight. If left un-filtered, xenon may over-excite a
independent of the illumination (lamp) since they are fluorescent material, therefore most all instruments today
ratios to the reflectance of the perfect white diffuser use a low wattage xenon lamp, or provide a means of
(PWD) under the exact same illumination. The only filtering the UV portion (360-400nm).
requirement is that the lamp possess sufficient radiant
energy throughout the visible spectrum. There are in
general two types of lamps used in instruments - tungsten relative energy
filament and xenon discharge lamps. The early
instruments used tungsten filament, usually filtered to filtered xenon
simulate daylight. Modern filament lamps are quartz
enveloped with a halogen to provide a very stable and
intense illumination from 400-700nm. This continuous
stable illumination was used extensively in single beam
instruments such as the Hunter D53, and the ACS
Spectro-Sensor. The lamps are very inexpensive but do
not last more than six months under normal conditions. D65
tungsten
There are however, some disadvantages with the
wavelength nm
tungsten lamps which have contributed to the recent
increase in xenon lamps. Continuous tungsten lamps
create heat and must be cooled. Secondly, the heat and
continuous light exposes the sample which may lead to Fig. 7 Relative Energy Distributions for D65, xenon,
variation in sample measurement due to such sensitivity. and tungsten filament lamps.
The lamps are usually equipped with infra-red absorbing
filters and some models provide a shutter to open only Xenon is an inert gas which when highly charged will
when measuring. In practice, the user should minimize convert the electron build-up to photons, emitting a flash
the amount of time a sample is exposed at the for a fraction of a second. A sample being measured is
measurement port. For these reasons, some therefore not exposed to continuous light, nor is there
manufacturers use pulsed tungsten illumination, however any heat to dissipate. Although the lamp is intense, it is
these instruments must also be designed with dual beam not as spectrally consistent or stable as a continuous
optics to account for illuminant fluctuations. The lamp such as tungsten. For this reason, all instruments
spectral distribution of tungsten filament, xenon, and which use xenon must be dual-beam designs. A
Daylight are shown in Fig 7. Although tungsten has reference beam, usually aimed at a point inside the
adequate energy in the visible spectrum for most color integrating sphere, provides a reference measurement
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against which the sample measurement is adjusted to be produced at various angles. A ruled grating with
account for any change in the illumination. about 300 lines per millimeter will produce a distribution
of visible light suitable for measurement.
Light Dispersion - Filters and Gratings
The earliest gratings were of the plane type in that they
The earliest records of experiments involving the were made using flat glass and etched. These gratings
separation of light into spectral colors were those of produced a distribution which was detected by placing
Newton4 in 1730 when he used a prism to separate photo-diodes along the distribution at certain
sunlight into the seven spectral colors or bands. In bandwidths, usually 10nm or 20nm. The plane grating
todays instruments, there are primarily two types of has been superseded now by a technique of laser etching
dispersing elements used - gratings and filters, with to produce a pattern of grooves in a concave glass
gratings being the most commonly used. surface. This concave holographic grating has the
advantage of providing both the dispersing and the
It must first be pointed out that the quality or collecting mechanisms into a single component. The
performance of most dispersing elements such as filters dispersed light can then be imaged or projected onto an
and gratings is determined by its ability to separate light array of photo-diodes. The concave grating requires less
into bands of colors. These bands or spectral distribution optical space and when combined with fiber optics, the
are measured in nanometers across the width of the instrument can be made extremely small and lightweight.
individual band (depending upon the detection type) at This optical design is used in the Datacolor Spectraflash,
the point of detection. The width is determined at 50% Dataflash, and Microflash instruments.
of maximum peak height for the band measured.
Detectors
Interference Filters Just as gratings have improved in performance due to
microprocessor technology, the detector assemblies have
The interference filter is very common in instruments, undergone similar revolutionary advancement. While
especially those produced during the early rise of the later version of the Hardy, and the Diano Match-Scan
industrial color matching in the 1970s and 80s. The utilized the conventional analytical grade photo-
interference filter is mounted as a filter wheel which is multiplier tubes (PMT), this highly accurate detector
usually rotated by a small electric motor directly in line required the use of a moving slit to bring monochromatic
with the sample and/or reference beam. This simple light to the detector. Most modern instruments use fixed
design uses a single photodiode detector which measures gratings and an array of photo-diode detectors to achieve
the dispersed light as the filter rotates resulting in bands the same purpose, but at a much lower cost of production
of variable width. Most are designed to provide an and lower cost of maintenance in the long term.
average rather than a fixed bandwidth of about 10nm.
Many instruments still in use today are based upon this The manufacturing of micro-processors and integrated
interference filter such as the Hunter D53, D54, and the circuits has resulted in the development of high quality
ACS Spectro-Sensor, and the ACS Chroma-Sensor 5. photo-diodes built on a single solid state electronic
Interference filters may also be positioned statically in micro-chip. These silicon based diodes are ideal when
sequence to provide the necessary spectral distribution. placed in an array across the spectral distribution from a
The resulting bands are measured with diode array fixed diffraction grating or filter assembly. This optical
detectors situated accordingly and are usually 12-15 nm assembly consisting of both grating and detector is
in bandwidth. Instruments of this type are the X-rite referred to as the spectrometer shown in Figure 8.
portable spectrophotometers such as 968, and SP series. Because the optical components are fixed, these
instruments are extremely stable exhibiting very little
Diffraction Gratings short-term or long-term drift in accuracy or precision.
Another advantage is that these gratings and integrated
The first grating was produced in 1821 by Joseph von detectors are highly reproducible. This has resulted in
Fraunhofer and is the most common light dispersing
mechanism used today in high performance instruments.
A grating is essentially a glass plane with a large number
of grooves etched or ruled into the surface. When light
strikes this grating, a pattern of diffraction and
interference will cause light of different wavelengths to
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the life of the lamp or instrument. By always comparing
DIFFRACTION GRATING
the standard to the batch, this variation is usually not a
problem provided the lamp has sufficient UV energy to
excite the fluorescence.
LIGHT FROM LIGHT FROM
SAMPLE REFERENCE
Many producers of white textiles prefer a more stable or
DISPERSED LIGHT DISPERSED LIGHT absolute determination of whiteness. Instruments are
(REFERENCE BEAM) (SAMPLE BEAM)
available which are equipped with a filter calibrator for
controlling the ratio of UV to visible output so that the
illumination can approximate the distribution of standard
illuminant D65. The method of calibration is that of
REFERENCE BEAM PHOTODETECTORS SAMPLE BEAM PHOTODETECTORS
Ganz and Griesser5 and after illuminant calibration, the
OUTPUT OUTPUT instrument is used to measure a more absolute whiteness,
namely the Ganz Whiteness index. This method of
TO illumination control is also useful for the measurement of
COMPUTER
visible fluorescent materials since the calibrated
Fig. 8 Dual Beam Spectrometer with twin detectors illumination leads to improved long-term repeatability.
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or detector so that no light is allowed to enter the Wavelength Accuracy - the average difference in
detector. nanometers between an instruments working
wavelength scale and the absolute scale as determined by
The measurement of transmittance may be measured in the spectral emission lines from a discharge lamp.
two ways on sphere type instruments as either the total
transmittance or regular transmittance. Total Photometric Accuracy - the accuracy in % Reflectance
transmittance is measured by placing the cell flush of the reflectance scale - usually 0-100% range. This is
against the sphere as shown in Fig. 9 . In this way, the usally determined by measuring neutral tiles of known
forward as well as side-scattered light is collected by the absolute reflectance.
detector. In the other mode, the cell is positioned away
from the sphere and closer to the detector. This
measurement excludes all scattering except forward. In Performance Specifications
the measurement of transparent dyes in solution, the two
methods yield identical results, however the total Measurement speed - the time required to measure a
transmittance is most commonly used. sample including the time of actual data collection and
the processing time to send the corrected data to the
computer.
Guide to Instrument Specifications
Inter-instrument agreement - the average color
The selection of an instrument for color measurement difference expressed in either CIELAB dE or CMC dE
can be a rather confusing and time consuming task since between the instrument and a theoretical or real master
there are many varieties in models with differing features instrument. This is usually determined in the factory by
and options. The following sections are given as a help measuring a set of BCRA ceramic tiles on each
to the colorist or lab manager in understanding some of instrument and calculating color differences from the
the terms likely to appear on the technical brochures. master instrument. The BCRA tiles are suitable working
More detailed descriptions of color terminology are standards although they are known to be thermochromic
given in ASTM E-284-93a Standard Terminology of and manufacturers must work within controlled
Appearance.6 conditions.
Geometry - the angle of illumination / angle of detection Repeatability - the color difference obtained when
in the optical system of the instrument measuring a stable sample (usually a BCRA ceramic tile)
repeatably on the same instrument, usually over a short
Wavelength Range - total range (in nanometers nm) in period of time.
which the instrument is capable of measuring, generally
somewhere between 360-750nm, with 400-700 most Reproducibility - the color difference obtained when
common. measuring a stable sample (usually a BCRA tile) over a
longer period of time. This term usually includes
Bandwidth- in abridged or scanning variables such as time, operator, and conditions of the
spectrophotometers, the width of the measured band at instrument. Some manufacturers report reproducibility
1/2 peak height used as a single point in the calculation as the color difference obtained on a single standard
and reporting of reflectance factors.. Bandwidths may when measured on different instruments of the same
range from 5nm - 20nm and is an important parameter in model or type.
achieving good agreement between two instruments.
Instruments for Special Purposes
Spectral Resolution - very similar to bandwidth, but
indicates the actual spectral width being measured but There are a variety of other insruments which have been
not necessarily reported as a single point. An instrument developed for special purposes such as portability,
may have diodes placed every 1nm however the data is continuous on-line measurement, goniophotometers, and
integrated for every 10 diodes to give a bandwidth of extended wavelength instruments. A more complete
10nm but a spectral resolution of 1nm. This term is description of instruments for the measurement of
sometimes called sampling interval. geometric and chromatic attributes of appearance is
given by Hunter and Harold7 .
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reversible optics also allow for the measurement of
Portable Instruments fluorescence by the two-mode method8.
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Extended Wavelength Instruments References
Instruments have been developed for measuring 1. Derby, Roland E. Jr, (1983), Color Technology
reflectance and transmittance at wavelengths other than in the Textile Industry, AATCC, Research
the visible (400-700 nm). Reflectance in the near Triangle Park, NC.
infrared region of 700-1100 nm is of interest to those
providing textiles for military use such as uniforms, 2. Hardy, Arthur C., (1935), Journal of Optical
tents, and vehicle fabrics. Although not visible, this Society of America, Vol. 25, p 305.
reflected light is detectable using infra-red sensitive
photography and filters. Instruments which are capable 3. Commission International Eclairage, (1986),
of measuring 700-1100nm are equipped with a special Colorimetry, Publication 15.2
grating or interference filters.
4. Newton, Sir Isaac, (1730), OPTICKS, Reprinted
Likewise, those involved in measuring fluorescent by Dover Publications, New York, N.Y., Fourth
whites may want to measure the near ultraviolet Edition
reflectance or transmittance below 400nm. For liquids,
a precision UV/VIS analytical spectrophotometer is 5. Griesser, Rolf, (1981), Rev. Prog. Coloration,
recommended. For reflectance measurement below Vol 11, p 25-36
400nm, some manufacturers provide measurement down
to about 350nm. If the instrument uses a tungsten 6. American Society for Testing and Materials
filament lamp, a supplemental UV lamp, such as a (ASTM), Publication ASTM Standards on
deuterium gas lamp, may be installed to provide the Color and Appearance Measurement, (1994)
required output in the UV region.
7. Harold, Richard and R.S. Hunter (199?), The
Measurement of Appearance, 2nd Edition John
Conclusion Wiley and Sons, New York, N.Y.
The words of Ruth Johnston-Feller9 in 1979 still hold 8. Simon, Fred T., (1972), Journal of Color
true today in that a whole generation of instruments is Appearance, Volume 1
available with far greater speed, better precision,
better short-term repeatability and more flexibility in 9. Johnston-Feller, Ruth, (1979), Color
application. These high standards of performance in Technology in the Textile Industry, AATCC,
instrumentation, the powerful new software programs, Research Triangle Park, N.C.
and increased flexibility continue to provide tremendous
tools toward achieving total color control. As a result,
those companies who have invested in color
instrumentation in the past, as well as those who will
invest in the future, are certain to reap the rewards of
effective color measurement and control.
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