SAMPLE PAPER-6 (1 MARK QUESTIONS)

1. Give IUPAC name of the following organic compound.

CH3 Br
CH3 CH= C- CH CH3
2. What are the physical states of dispersed phase and dispersion medium of froth.
3. Why is NH3 liquid whereas PH3 gas.
4. Write the structure of 4-methylpent-3-en-2-one.
5. What is the no. of atoms per unit cell in a body centred cubic structure.
6. What is the expected value of Vant Hoff factor for a compound which undergoes
tetramerization in an organic solvent.
7. What is the role of CO in the refining of Ni?
8. Draw the structure of XeF4.
2 MARK QUESTION
9. Calculate the mass of ascorbic acid (vit C-C6H8O6) to be dissolved in 75g of acetic acid to lower its
melting point by 1.5C (Kf for acetic acid 3.9K kg mol-1)
10. (a) What do you understand by zero order reaction.
(b) Identify the order of reaction from the value of rate constt.
K = 4.2 X 10-5 L mol-1 s-1
11. Calculate the osmotic pressure of a solution in pascal exerted by a solution prepared by
dissolving 1.0g of polymer of molar mass 1,85,000g mol-1 in 450ml of water at 37C.
12. Differentiate between the nucleotides of DNA and RNA.
13. Name the two components of starch. How do they differ from each other structurally.
14. How can phenol be prepared from cumene?
15. (a) Arrange the following in decreasing order of basic character.

NH2 NH2 NH2

CH3 NO2

NO2

(b) Ethylamine is soluble in water, whereas aniline is not.

16. Arrange following on the basis of acidic character o- methoxy phenol, m-methoxy phenol, o-
nitro phenol, m-nitrophenol & phenol.
17. Write short note on:
(a) Hoffmann-Ammonolysis Reaction.
(b) Diazotisation.
18. The value of for formation of Cr2O3 is -540KJ mol-1 and that of Al2O3 is -827 KJ mol-1. Is the
reduction of Cr2O3 possible with Al?

3 MARK QUESTION
19. An element having atomic mass 60 has face centred cubic unit cells. The edge of the unit cell is
400pm. Find out density of the element.
20. If the decomposition of Nitrogen oxide 2N2O5 4NO2 + O2 following a first order kinetics.
(i) Calculate the role constant for a 0.04M solution if the instantaneous rate is 1.4 x 10-6mol L-1S-1
(ii) Also calculate the rate of reaction when the concentration of N2O5 is 1.20M.
 (iii) What concentration of N2O5 would give a rate of 2.45 x 10-5 mol L-1S-1?
21. Account for the following:
(a) Silica gel is used as dehumidizer?
(b) Medicines are colloidal in nature.
(c) Ferric hydroxide sol coagulates on addition of aqueous solution of sodium sulphate.
22. Explain for the following observations:
(a) ClF3 exists but FCl3 does not.
(b) Chlorine water has both oxidizing and bleaching properties.
(c) Most of the known noble gas compounds are those of Xenon.
23. (a) Write differences between double salt & complex.
(b) Calculate the overall complex dissociation equilibrium constt. for [Cu(NH3)4]2+ ion, given that
4 for this complex is 2.1 x 1013
(c) Name the central atom present in haemoglobin and chlorophyll.
24. How will you bring about the following conversions:
(a) Benzene to biphenyl
(b) Propene to 1-nitropropane
(c) But-1-ene to But-2-ene.
25. (a) Menation the conditions for the maximum yield of ammonia.
(b) What is the oxidation state of nitrogen in nitrous acid and nitric acid.
OR
Write balanced equations for the following reactions:
(a) Ca3P2 + H2O
(b) Cu + Conc. H2SO4
(c) H3PO3
26. (a) What is the role of benzoyl peroxide in polymerization of ethane.
(b) Arrange the following polymers in increasing order of their intermolecular forces- Nylon-6,
Neoprene, PVC.
27. How do antiseptics differ from disinfectants? Name a substance that can be used as an
antiseptic as well as a disinfectant.
5 MARK QUESTIONS
28. State Kohlrausch law of independent migration of ions. Write an expression for the molar
conductivity of acetic acid at infinite dilution according to kohlrausch law.
(a) Write difference between Electrochemical cell & electrolytic cell.
(b) Predict the products of electrolysis in each of following
(i) An aqueous solution of AgNO3 with silver electrodes
(ii) An aqueous solution of CuCl2 with Pt electrodes.
(c) Calculate m for acetic acid
Given that m (HCl) = 426 S cm2 mol-1
m (NaCl) = 126 S cm2 mol-1
m (CH3COONa) = 91 S cm2 mol-1
OR

(a) Write the anode & cathode reactions and the overall reaction occurring in a Mercury Cell.
(b) Given the following cell, Al/Al3+(0.01M) II Fe2+(0.02M)
Calculate the value of E cell at 298K when E Al3+/Al & E Fe2+/Fe are -1.66 & -0.44
respectively.
29. (a) Out of Ag2SO4, CuF2, MgF2 and CuCl which compound will be coloured and why?
(b) Explain:
 (i) CrO42- is a strong oxidizing agent while MnO42- is not.
(ii) Transition metals and many of their compounds show paramagnetic behaviour.
(iii) The lowest oxidation state of manganese is basic while the highest is acidic.
(iv) Mn(II) shows maximum paramagnetic character amongst the divalent ions of the first
transition series.
OR
(a) In the titration of FeSO4 with KMnO4 in the acidic medium. Why is all H2SO4 used instead of
dil HCl?
(b) Give reasons:
(i) Among transition metals the highest oxidation state is exhibited in oxoanions of a metal.
(ii) Ce4+ is used as an oxidizing agent in volumetric analysis.
(iii) Transition metals forms a no. of interstitial compound Zn2+ salts are white while Cu2+ salts
are blue.
(iv) Among lauthanoid cations Ce4+ is oxidizing and Eu2+ is reducing.
30. An unknown aldehyde A on reacting with dil alkali gives a - hydroxyl aldehyde which losses
water to form an unsaturated aldehyde-2-butenal. Another aldehyde B undergoes
disproportionation reaction in the presence of conc. alkali to form products C & D. C is an aryl
alcohol with the formula C7H8O
(i) Identify A & B
(ii) Write the sequence of reaction involved.
(iii) Name the product when B reacts with Zn amalgam & HCl.
OR
Two isomers A + B molecular formula A reacts with conc. NaOH to give two compound C & D
while B reacts with dil NaOH to give one compound E only. Both A & B on oxidation give
carboxylie acids F & G. F gives HVZ reaction with Cl2/P while G does not give this reaction

CHO COONa CH2OH

NaOH
+

CH3 CH3 CH3

A Oxi COOH C D

CH3 F

OH

CH2CHO CH2 C CH CHO

NaOH

B E

oxi CH2COOH

P/Cl2