UNAM-FESC, Ingeniera Qumica, Transferencia de masa II, Destilacin multicomponente, Henley 12.

Para la operacin de destilacin que se indica seguidamente, calclese el nmero mnimo de etapas de equilibrio y la
distribucin de los componentes no clave utilizando la ecuacin de fenske y los valores de Ki de la figura 7.5 de la pgina
302.

chemical
components Zi Kgmol/h A B C Pc
formule
propane C3H8 0.63613232 2500 5.353418 3371.084 414.488 617.4
i-butane i-C4H10 0.10178117 400 5.611805 3870.419 409.949 529.01
n-butane LK n-C4H10 0.15267176 600 5.741624 4126.385 409.5179 550.7
i-pentane HK i-C5H12 0.02544529 100 5.49978 4221.154 387.287 483
n-pentane n-C5H12 0.05089059 200 5.853654 4598.287 394.4148 489.5
n-hexane n-C6H14 0.01017812 40 6.039243 5085.758 382.794 440
n-heptane n-C7H16 0.01272265 50 5.98627 5278.902 359.5259 396.9
n-octane n-C8H18 0.01017812 40 6.4141 5947.491 360.26 362.1
TOTAL 1 3930
 destilledd
chemical
components yi di=Kgmol/h
formule
propane C3H8 0.63613232 2500
i-butane i-C4H10 0.10178117 400
n-butane LK n-C4H10 0.15114504 594
i-pentane HK i-C5H12 0.00381679 15
n-pentane n-C5H12 0 0
n-hexane n-C6H14 0 0
n-heptane n-C7H16 0 0
n-octane n-C8H18 0 0
TOTAL 0.89287532 3509

tails
chemical
components xi bi=Kgmol/h
formule
propane C3H8 0 0
i-butane i-C4H10 0 0
n-butane LK n-C4H10 0.00152672 6
i-pentane HK i-C5H12 0.0216285 85
n-pentane n-C5H12 0.05089059 200
n-hexane n-C6H14 0.01017812 40
n-heptane n-C7H16 0.01272265 50
n-octane n-C8H18 0.01017812 40
TOTAL 0.10712468 421

Para la t en las colas

1 2
= +3

Entonces

1 2 1 2 1 2 1 2 1 2 1 2
= nC4 +3 + iC5 +3 + nC5 +3 + nC6 +3 + nC7 +3 + nC8 +3

1 2
+3
1 2
+3
1 2
+3
1 2
+3
1 2
+3
1 2
+3
= + + + + +
nC8
nC4
Resolviendo con Texas instriment voyage 200

= 254.9258027 = 123.8476682 = 124

 tails
chemical
components xi bi=Kgmol/h XiPc xi*KI=1 ki i
formule
propane C3H8 0 0 0 0 0 0
i-butane i-C4H10 0 0 0 0 0 0
n-butane LK n-C4H10 0.01425178 6 7.84845606 0.03990499 2.8 2.24
i-pentane HK i-C5H12 0.20190024 85 97.5178147 0.30285036 1.5 1.2
n-pentane n-C5H12 0.47505938 200 232.541568 0.59382423 1.25 1
n-hexane n-C6H14 0.09501188 40 41.8052257 0.06365796 0.67 0.536
n-heptane n-C7H16 0.11876485 50 47.1377672 0.04038005 0.34 0.272
n-octane n-C8H18 0.09501188 40 34.4038005 0.01900238 0.2 0.16
TOTAL 1 421 461.254632 1.05961995

Para el destilado
iC5

1 2

1 2

1 2

1 2
= + 3 + + 3 + + 3 + +3

C3
Resolviendo con Texas instriment voyage 200

= 136.2113478 = 57.8951932 = 58

destilledd
chemical
components yi di=Kgmol/h Yi/Pc yi/KI=1 ki i
formule
propane C3H8 0.71245369 2500 0.00115396 0.27402065 2.6 1
i-butane i-C4H10 0.11399259 400 0.00021548 0.10856437 1.05 0.16
n-butane LK n-C4H10 0.169279 594 0.00030739 0.62695925 0.27 0.2376
i-pentane HK i-C5H12 0.00427472 15 8.8504E-06 0.00610675 0.7 0.006
n-pentane n-C5H12 0 0 0 0 0 0
n-hexane n-C6H14 0 0 0 0 0 0
n-heptane n-C7H16 0 0 0 0 0 0
n-octane n-C8H18 0 0 0 0 0 0
TOTAL 1 3509 0.00168568 1.01565102

Nmero mnimo de etapas

log[, , ]
, ,
=
,

Donde =

, = , ,

, = 2.5925 2 = 2.2770
Por lo que te queda

log[11.8777429 47.2311956] 2.778837

= = = 7.7757
(2.277059) 0.357374