TEST CHEMISTRY 22-10-17

Time 2.5 hrs CH# 02 + 03

MCQs 10X1

1. The central atom is sp2 hybridized in_______.

(a) CH4 (b) BeCl2 (c) BF3 (d) H2O

2. Which one of the following has greater bond energy?

(a) CC (b) NN (c) CO (d) CN

3. The radius of 1st orbit of Li+2 is_______.

(a) 0.176Ao (b) 0.2645Ao (c) 0.529Ao (d) 2.116Ao

4. The molecular geometry determined by the repulsion between only bond pairs in:

(a) SnCl2 (b) PbCl3 (c) PCl3 (d) BCl3

5. The energy of 2px orbital is higher than 2py & 2pz orbital in the MOT diagram of:

(a) N2 (b) O2 (c) F2 (d) H2

6. According to MOT which of the following species resemble to He2 w.r.t filling of orbitals?

(a) B2 (b) Be2 (c) Li2 (d) C2

7. Bond length in C=C is_________ pm.

(a) 154 (b) 120 (c) 133 (d) 122

8. According to VESPR theory shape of AB3E type molecule is________.

(a) Triangular pyramidal (b) Octahedral (c) Tetrahedral (d) Trigonal planar

9. Bond energy is independent of ________.

(a) Atomic size (b) Bond length (c) London dispersion (d) Bond order

10. According to VESPR theory bond order of N2 and Ne2 is______.

(a) 3 & 4 (b) 1 & 3 (c) 3 & 2 (d) 3 & 0

Short answers questions. 10X3

1. Calculate the radius of 1st orbit of hydrogen atom and helium ion. Which one has smaller

radius give reason?

2. Explain briefly the structure of SnCl2 and PCl5 w.r.t VESPR theory.

3. The observed dipole moment in HCl is 1.03D and bond length is 127pm. Calculate its ionic

character.

4. How do you justify that the distance between adjacent orbitals of hydrogen atom go on

increasing from lower to higher orbits?

5. Give two examples of each AB4, AB3E and AB2E2 type molecules.

6. Bond angle of NH3 is 107.5o and NH4+ is 109.5o. Justify these values by drawing structures.

7. Describe the shape of following molecules by using VESPER theory.

(a) PH3 (b) H2S.

8. Explain sigma and pi bonds giving one example of each.

9. Briefly explain bond energy. Write parameters which determine its strength.

10. Explain the structure of methane by using concept of hybridization.

Long questions and answers.

1. (a) Define hybridization. Name its types and explain structure of ethyne.

(b) Derive relation to find total energy of nth orbital of an atom.

2. (a) BF3 and NF3 have identical formula like MX3 but different structures. Explain their geometries

on basis of VESPER theory.

(b) Derive an equation to finding the radius of nth orbit of an atom.

3. (a) Draw molecular orbital diagram of O2 and explain its paramagnetic behavior.

(b) Discuss sp3 and sp2 hybridization with the help of one example of each.