Tonnage Hydrogen Supply

Experience, Capabilities
and Reliability
 Who Is Air Products?

Global atmospheric, process and

specialty gases, performance materials,
equipment and services provider
Serving industrial, energy, technology
and healthcare markets worldwide
Fortune 500 company
Operations in over 40 countries
18,900 employees worldwide
Known for our innovative culture and
operational excellence
Corporate responsibility commitment

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 Air Products
Sales into Diverse Markets

$10.1 billion company

Diverse markets and geographies
Positioned for continued long-term value creation
FY11 Business Segment Sales FY11 Geographic Sales

Merchant Asia
Tonnage (24%)
(40%) (33%)
United
States
(38%)

Europe
Equipment Electronics & (31%)
& Energy Performance Canada/Latin
(4%) Materials America (7%)
(23%)

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 Refining Hydrogen and Energy
Driving Hydrogen Growth

Transport fuels growth

More heavy, sour crude
Clean fuels legislation 45%

4
 Shifting Customers Buying Habits . . .
Outsourcing Refinery H2 Needs
PRIOR TO 1990 AWARDS 1990-2010 AWARDS
Mostly Petrochemicals Refiners Acceptance Grows

ONSITE & ONSITE &

PIPELINE PIPELINE

MAKE CASE
MAKE CASE

Global Trend in U.S., Canada, Europe,

Latin America, India, China, Asia

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 Air Products Global Hydrogen Capabilities
and Experience
Worldwide leadership position in outsourced hydrogen
production & recovery
40% market share based on volume
Maintained 40% for 15 years
Strong focus on the refining and chemical industries
Over 30 hydrogen supply contracts with refiners
Own and operate over 50 SMRs around the world
Established reputation for high reliability operation
Over 1000 operating years for hydrogen plants
Complete technology portfolio in hydrogen, CO,
syngas equipment
Proprietary separation systems
(membrane, PSA, cold boxes)
Global Alliance with Technip for
reforming technology

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 Air Products Operating Experience
On-Purpose HyCO Plants: Total Capacity 2,500 MMSCFD
HANNIBAL MISSOURI, USA H2 1991 HYDRO-CHEM
GEISMAR I LOUISIANA, USA SYNGAS/H2 1985 HEAT RESEARCH/Air Products
SACRAMENTO I CALIFORNIA, USA H2 1986 HYDRO-CHEM
SACRAMENTO II CALIFORNIA, USA H2 1989 HOWE-BAKER
CINCINNATI OHIO, USA H2 1992 HOWE-BAKER
KUANTAN MALAYSIA H2 1992 HOWE-BAKER
PORTO MAGHERA ITALY H2 1992 KTI
TOLUCA MEXICO H2 1992 HOWE-BAKER
TUSCOLA ILLINOIS, USA H2 1993 HOWE-BAKER
MARTINEZ I CALIFORNIA, USA H2 1993 KTI/Air Products
TARANTO ITALY H2 1994 KIT/Air Products
PERNIS NETHERLANDS H2 1994 M.W. KELLOGG
MARTINEZ II CALIFORNIA, USA H2 1995 KTI/Air Products
WILMINGTON CALIFORNIA, USA H2 1995 KTI/Air Products
LAPORTE III TEXAS, USA H2//CO 1995 TDC POX-KTV/Air Products
PASADENA TEXAS, USA H2 1996 KTI/Air Products
CAMACARI BRAZIL H2/CO 1997 KTI/Air Products
BANTING MALAYSIA H2 1997 KTI/Air Products
SALISBURY MARYLAND, USA H2 1998 KTI/Air Products
SINGAPORE SINGAPORE SYNGAS/ H2 1999 KIT/Air Products
GALLATIN TENNESSEE, USA H2 1999 KTI/Air Products
MIDLAND MICHIGAN, USA H2 1999 KTIBAKER/Air Products
CARSON CALIFORNIA, USA H2 1999 KTI/Air Products
RALEIGH NORTH CAROLINA, USA H2 2000 KTI/Air Products
BAYTOWN HyCO TEXAS, USA SYNGAS/CO 2000 TDC/Air Products
PT. ARTHUR I TEXAS, USA H2 2000 KTI/Air Products

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 Air Products Operating Experience
On-Purpose HyCO Plants: Total Capacity 2,500 MMSCFD
GEISMAR II LOUISIANA, USA H2 /SYNGAS/CO 2001 Air Products
ZHUHAI I ZHUHAU, CHINA H2 2001 CALORIC
LLANWERN WALES, UK H2 2002 KTI/Air Products
TARRAGONA SPAIN H2 2002 TECHNIP/Air Products
CRESSIER SWITZERLAND H2 2003 TECHNIP/Air Products
CATLETTSBURG KENTUCKY, USA H2 2003 TECHNIP/Air Products
MANTOVA II ITALY H2 2004 TECHNIP/Air Products
WESTLAKE LOUISIANA, USA H2 2004 TECHNIP/Air Products
ZIBO SHANDONG, CHINA H2 2004 CALORIC
NEW ORLEANS D LOUISIANA, USA H2 2004 TECHNIP/Air Products
ZHUHAI II ZHUHAI, CHINA H2 2004 CALORIC
ZHANG JIAGANG JIANGSU, CHINA H2 2004 CALORIC
PIOMBINO ITALY H2 2005 CALORIC
WESTPORT I MALAYSIA H2 2005 CALORIC
CONVENT LOUISIANA, USA H2 2005 TECHNIP/Air Products
TAIWAN TAIWAN H2 2006 CALORIC
PT. ARTHUR II TEXAS, USA H2 2006 TECHNIP/Air Products
EDMONTON I ALBERTA, CAN H2 2006 TECHNIP/Air Products
SARNIA ONTARIO, CAN H2 2006 TECHNIP/Air Products
JOLIET ILLINOIS, USA H2 2006 TECHNIP/Air Products

EDMONTON II ALBERTA, CAN H2 2008 TECHNIP/Air Products

GARYVILLE LOUISIANA, USA H2 2009 TECHNIP/Air Products
CORPUS CHRISTI TEXAS, USA H2 2010 LINDE
BATON ROUGE LOUISIANA, USA H2 2010 TECHNIP/Air Products
ROTTERDAM NETHERLANDS H2 2011 TECHNIP/Air Products
WESTPORT II MALAYSIA H2 2011 CALORIC
LULING LOUISIANA, USA H2 2012 TECHNIP/Air Products

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 Air Products SMRs Under Construction
On-Purpose HyCO Plants: Capacity U/C >300 MMSCFD
DETROIT MICHIGAN, USA H2 2012 TECHNIP/Air Products
CHENGDU SICHUAN, CHINA H2 /SYNGAS 2012 TECHNIP/Air Products
ST. CHARLES LOUISIANA, USA H2 2013 TECHNIP/Air Products

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 Global Refining H2 Capacity Awarded
New Business Announcements Since 2001
Capacity
Air Products Key Customer Location (MMSCFD)
ConocoPhillips, Citgo Westlake, Louisiana 110
Murphy Oil New Orleans, Louisiana 40
Marathon Catlettsburg, Kentucky 34
Suncor (Petro-Canada), Imperial Oil Edmonton, Alberta 71
Suncor (Petro-Canada II) Edmonton, Alberta 105
Suncor Sarnia, Ontario 81
Motiva Convent, Louisiana 110
Marathon Garyville, Louisiana 120
ExxonMobil Baton Rouge, Louisiana >100
ExxonMobil Baytown Expansion, Texas 70
Valero Pt. Arthur II SMR, Cogen 110
ExxonMobil Joliet, Illinois 18
Repsol Tarragona, Spain 63
Petro-Plus Cressier, Switzerland 8
MOL Mantova, Italy 15
MarkWest Energy Partners, Citgo Corpus Christi, Texas >30
ExxonMobil, Shell Botlek, Netherlands >100
Air Products Pipeline System Luling, Louisiana >100
Marathon Detroit, Michigan >50
PetroChina Sichuan, China >90
Valero St. Charles, Louisiana >150
Total Awarded: >1.6 Billion

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 Strong Hydrogen Sarnia
Pipeline Positions Canada
40
40

Edmonton, Suncor

Canada Air Products

Canada LHY
40
Shell
Refinery
16
16 ST.
CLAIR
Petro-Canada RIVER
Imperial Oil
Dominguez
Channel
91
Southern
Sherwood
405 California Park 21
Corunna
14
190th 630
St.
14
710
Rotterdam
Carson H2
110 Long
VAN NESS Beach
AVE. Arpt. Europoort
Sepulveda BP
Blvd Carson
Pernis
Shell
Conoco Phillips Wilmington
1 Carson Zwijndrecht
Anaheim Botlek
Street
Valero
Wilmington
Conoco Phillips
Wilmington Wilmington H2
110 To Moerdijk

Air Products HyCO facilities

H2 pipeline
CO pipeline
Syngas pipeline

Air Products H2 Pipeline

Air Products H2 Plants - USGC

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 Global Alliance with Technip

Technip brings proven SMR design, detail

engineering skills
Air Products brings separation technology,
process integration, process controls and
operations experience
Partnership on >30 plants since 1992
Joint development initiatives bring project
execution efficiencies for each new plant
Multiple project execution
Wealth of information at www.h2alliance.com

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 How do we achieve high reliability?

Plant Maintenance
Personnel Program

Training Spare Parts

Program Availability

Plant
Technical
Design
Support

Operations Shared
Procedure Operating
Experience
Reliability Plant
Testing Documentation

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 Reliability through Standardization

Design
Top Fired Technip Reformer (since 1992)
Company Specific Criteria
Technology and Hardware
DCS, Transmitters, Valves, Compressors, etc.
Execution
In house process, systems, environmental
engineering (up-front)
Project, construction, start-up and commissioning
Operations
Global HyCO Line Management, central support
Maintenance
Global HyCO specialists for turn-arounds,
trouble-shooting
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 HYCO Supply Reliability
Why Air Products?
Unplanned Downtime Events / > 60 MMSCFD Plants

* Includes Large HyCO sites > 60 MMSCF/D / (140 MT/D) plants

15 * Excluding Force Majeure / Downtime = Anytime Product Flow goes to Zero
 Why Work With Air Products
#1 H2 supplier to the refining industry
We understand safety and reliability expectations and will design
accordingly
We understand the refining processes that use our hydrogen
Highest HyCO onstream record of any industrial gas company
We are focused on minimizing the number of shutdowns
Air Products is willing to link our revenue to operating performance
Air Products has critical mass from 60+ plants to quickly solve any
problem that does arise, brings 1000+ HyCO plant-operating years of
experience
Alliance with Technip has executed >30 projects over last
15 years
Dedicated/experienced project resources
Focus on schedule
Preferred position with suppliers
We will find the lowest cost, most innovative solution
Air Products has experience with various feedstocks and process
configurations, including cogeneration
Proprietary separation systems (membrane, PSA, cold box)
Will work with the customer to quickly develop the optimal plant
Lower cost than refiners make case
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