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(IDE.CN='trans-Dichlorobis(ethylenediamine)cobalt(III) chlor- 1 substances in
1. Query 2017-11-17 18h:29m:12s (EST)
ide') Reaxys

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Reaxys ID 16768284 View in Reaxys 1/1

CAS Registry Number: 13408-72-5; 14040-32-5; 14040-33-6;


20594-10-9; 20594-11-0
Chemical Name: trans-dichlorobis(ethylenediamine)co-
balt(III) chloride; trans-dichlorobis cobalt(III) bis(ethylenediam-
mine) chloride; trans-dichlorido-bis-(ethylenediamine)cobalt(III)
chloride; trans-[cobalt(III)dichloride(ethylenediamine)2](chlor-
Cl
(v4)
ide); trans-dichlorido-bis(ethylenediamine)cobalt(III) chloride;
Cl
H (v4)
NH
2 N+
Co2 N
trans-dichloro-bis-ethylene diamine cobalt(III) chloride; trans-di-
NOC-6(v6)
HCl H 2
2 (v4)
chlorobis(1,2-diaminoethane)cobalt(III) chloride
(v4)
Linear Structure Formula: C4H16Cl2CoN4 (1+)*Cl(1-)
Molecular Formula: C4H16Cl2CoN4*Cl
Molecular Weight: 285.55
Type of Substance: Coordination compound
InChI Key: GVMSQWCTZLHSQH-UHFFFAOYSA-K
Note:
Substance Label (1)
Label References
4 Cooper, Rachel J.; Jane, Reuben T.; Jeffs, Thomas E.; Hartshorn, Richard M.; Tasker, Peter A.; Chemi-
cal Communications; vol. 48; nb. 77; (2012); p. 9583 - 9585, View in Reaxys
Purification (1)
Purification References
(method)
purification de- Jackson, W. Gregory; Kuzmission, A. G.; Cooper, J. N.; Henry, J. C.; Inorganic Chemistry; vol. 28;
scribed (1989); p. 1553 - 1559 ; (from Gmelin), View in Reaxys
Melting Point (1)
1 of 1 Melting Point [C] 229
Comment (Melting with decomposition
Point)
Abdel-Halim, Hamzeh M.; Abu-Surrah, Adnan S.; Baker, Hutaf M.; Zeitschrift fur Naturforschung - Section B Jour-
nal of Chemical Sciences; vol. 61; nb. 11; (2006); p. 1346 - 1350 ; (from Gmelin), View in Reaxys
Density (3)
1 of 3 Density [gcm-3] 1.88
Type (Density) crystallographic
Becker, K. A.; Grosse, G.; Plieth, K.; Naturwissenschaften; vol. 42; (1955); p. 254 - 255, View in Reaxys; vol. Co:
SVol.B2; 98, page 520 - 522 ; (from Gmelin), View in Reaxys
2 of 3 Density [gcm-3] 1.84
Type (Density) crystallographic
Becker, K. A.; Grosse, G.; Plieth, K.; Naturwissenschaften; vol. 42; (1955); p. 254 - 255, View in Reaxys; vol. Co:
SVol.B2; 98, page 520 - 522 ; (from Gmelin), View in Reaxys
3 of 3 Density [gcm-3] 1.8165
Measurement Tempera- 20
ture [C]
Comment (Density) ref. temp. 4 Deg C
Spacu, P. G.; Bull. Sect. Sci. Acad. Roum.; vol. 21; (1938); p. 35 - 37, View in Reaxys; vol. Co: SVol.B2; 98, page
520 - 522 ; (from Gmelin), View in Reaxys
Adsorption (MCS) (2)
1 of 2 Description (Adsorption Adsorption
(MCS))
Temperature (Adsorp- 25
tion (MCS)) [C]
Partner (Adsorption goethite
(MCS))
Cooper, Rachel J.; Jane, Reuben T.; Jeffs, Thomas E.; Hartshorn, Richard M.; Tasker, Peter A.; Chemical
Communications; vol. 48; nb. 77; (2012); p. 9583 - 9585, View in Reaxys

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2 of 2 Description (Adsorption Adsorption
(MCS))
Partner (Adsorption -alumina
(MCS))
Vivier, Vincent; Aguey, Francois; Fournier, Jeanine; Lambert, Jean-Francois; Bedioui, Fethi; Che, Michel;
Journal of Physical Chemistry B; vol. 110; nb. 2; (2006); p. 900 - 906 ; (from Gmelin), View in Reaxys
Association (MCS) (1)
1 of 1 Description (Association self-association
(MCS))
Jimenez; Garcia-Fernandez; Grueso; Fernandez; Marin; Sanz; Torrado; Villegas; Gonzalez; Stuerekow; Leon;
Leria; MacHuca; Martinez; Morales; Villa-Bernaldez; Prado-Gotor; Chemical Physics Letters; vol. 417; nb. 4-6;
(2006); p. 509 - 514 ; (from Gmelin), View in Reaxys
Conformation (1)
Object of Investi- References
gation
Conformation Baldwin, M. E.; Journal of the Chemical Society; (1960); p. 4369 - 4376, View in Reaxys; vol. Co: SVol.B2;
206, page 777 - 779 ; (from Gmelin), View in Reaxys
Crystal Phase (5)
Description (Crys- References
tal Phase)
prisms Joergensen, S. M.; Journal fuer Praktische Chemie (Leipzig); vol. 39; (1889); p. 16 - 16, View in Reaxys;
Zsako; Pokol; Novak; Varhelyi; Dobo; Liptay; Journal of Thermal Analysis and Calorimetry; vol. 64; nb. 2;
(2001); p. 843 - 856, View in Reaxys; vol. Co: MVol.B; 100, page 238 - 241 ; (from Gmelin), View in Reaxys
Powder X-ray Dif- Dash; Ajikumar; Kamruddin; Tyagi; Thermochimica Acta; vol. 334; nb. 1-2; (1999); p. 141 - 148 ; (from
fraction Gmelin), View in Reaxys
needles Jackson; Begbie; Inorganica Chimica Acta; vol. 61; nb. C; (1982); p. 167 - 172 ; (from Gmelin),
View in Reaxys
Structure of the Becker, K. A.; Grosse, G.; Plieth, K.; Zeitschrift fuer Kristallographie, Kristallgeometrie, Kristallphysik, Kris-
solid tallchemie; vol. 112; (1959); p. 375 - 384, View in Reaxys; vol. Co: SVol.B2; 98, page 520 - 522 ; (from Gme-
lin), View in Reaxys
Single Crystal X- Becker, K. A.; Grosse, G.; Plieth, K.; Naturwissenschaften; vol. 42; (1955); p. 254 - 255, View in Reaxys;
ray Diffraction vol. Co: SVol.B2; 98, page 520 - 522 ; (from Gmelin), View in Reaxys
Crystal Property Description (8)
Colour & Other Comment (Crystal References
Properties Property Descrip-
tion)
green Blakeley, Christine; Tobe, Martin L.; Journal of the Chemical Society, Dalton Transac-
tions: Inorganic Chemistry (1972-1999); (1987); p. 1775 - 1778, View in Reaxys; Leaist,
Derek G.; Australian Journal of Chemistry; vol. 41; (1988); p. 469 - 482, View in Reaxys;
Uspensky, A.; Tschibisoff, K.; Z. Anorg. Chem.; vol. 164; (1927); p. 331 - 331,
View in Reaxys; Werner, A.; Jantsch, G.; Ber.; vol. 40; (1907); p. 262 - 271,
View in Reaxys; Werner, A.; King, V. L.; Ber.; vol. 44; (1911); p. 1890 - 1890,
View in Reaxys; Werner, A.; Schmidt, R.; Liebigs Annalen der Chemie; vol. 386; (1912);
p. 114 - 114, View in Reaxys; Werner, A.; Schmidt, R.; Liebigs Annalen der Chemie; vol.
386; (1912); p. 126 - 126, View in Reaxys; Werner, A.; Schmidt, R.; Liebigs Annalen der
Chemie; vol. 386; (1912); p. 56 - 56, View in Reaxys; Werner, A.; Ber.; vol. 40; (1907); p.
272 - 287, View in Reaxys; Werner, A.; Ber.; vol. 44; (1911); p. 875 - 875,
View in Reaxys; Werner, A.; Liebigs Annalen der Chemie; vol. 386; (1912); p. 13 - 95,
View in Reaxys; Werner, A.; Liebigs Annalen der Chemie; vol. 386; (1912); p. 165 - 165,
View in Reaxys; Werner, A.; Liebigs Annalen der Chemie; vol. 386; (1912); p. 166 - 166,
View in Reaxys; Werner, A.; Liebigs Annalen der Chemie; vol. 386; (1912); p. 250 - 250,
View in Reaxys; vol. Co: MVol.B; 47, page 118 - 121, View in Reaxys; vol. Co: MVol.B;
51, page 127 - 130, View in Reaxys; vol. Co: MVol.B; 65, page 159 - 162,
View in Reaxys; vol. Co: MVol.B; 74, page 178 - 180, View in Reaxys; vol. Co: MVol.B;
91, page 217 - 218, View in Reaxys; Joergensen, S. M.; Journal fuer Praktische Chemie
(Leipzig); vol. 41; (1890); p. 448 - 448, View in Reaxys; Morgan, G. T.; Main Smith, J.
D.; Journal of the Chemical Society; vol. 125; (1924); p. 2000 - 2000, View in Reaxys;
Morgan, G. T.; Main Smith, J. D.; Journal of the Chemical Society; vol. 125; (1924); p.
2004 - 2004, View in Reaxys; Uspensky, A.; Tschibisoff, K.; Z. Anorg. Chem.; vol. 164;
(1927); p. 329 - 329, View in Reaxys; Werner, A.; Liebigs Annalen der Chemie; vol. 386;
(1912); p. 1 - 1, View in Reaxys; Werner, A.; Liebigs Annalen der Chemie; vol. 386;
(1912); p. 48 - 48, View in Reaxys; vol. Co: MVol.B; 107, page 253 - 254,

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View in Reaxys; Linhard, M.; Stirn, G.; Z. Anorg. Chem.; vol. 268; (1952); p. 105 - 127,
View in Reaxys; Spacu, P. G.; Bull. Sect. Sci. Acad. Roum.; vol. 21; (1938); p. 35 - 37,
View in Reaxys; vol. Co: SVol.B2; 104, page 535 - 538, View in Reaxys; vol. Co:
SVol.B2; 98, page 520 - 522, View in Reaxys; Kalalova, E.; Populova, O.; Russian Jour-
nal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii); vol. 27;
(1982); p. 1777 - 1782; Zhurnal Neorganicheskoi Khimii; vol. 27; (1982); p. 3145 - 3152,
View in Reaxys; Obashi, Masayoshi; Matsukawa, Tokuo; Journal of the Physical Soci-
ety of Japan; vol. 53; nb. 12; (1984); p. 4420 - 4424, View in Reaxys; Zsako; Pokol; No-
vak; Varhelyi; Dobo; Liptay; Journal of Thermal Analysis and Calorimetry; vol. 64; nb.
2; (2001); p. 843 - 856, View in Reaxys; Vivier, Vincent; Aguey, Francois; Fournier,
Jeanine; Lambert, Jean-Francois; Bedioui, Fethi; Che, Michel; Journal of Physical
Chemistry B; vol. 110; nb. 2; (2006); p. 900 - 906, View in Reaxys; Casadesus, Merit-
xell; Coogan, Michael P.; Davies, Elenna; Ooi, Li-ling; Inorganica Chimica Acta; vol.
361; nb. 1; (2008); p. 63 - 78, View in Reaxys; vol. Co: MVol.B; 100, page 238 - 241 ;
(from Gmelin), View in Reaxys
deep green Abdel-Halim, Hamzeh M.; Abu-Surrah, Adnan S.; Baker, Hutaf M.; Zeitschrift fur Na-
turforschung - Section B Journal of Chemical Sciences; vol. 61; nb. 11; (2006); p. 1346 -
1350, View in Reaxys; Jackson; Begbie; Inorganica Chimica Acta; vol. 61; nb. C;
(1982); p. 167 - 172 ; (from Gmelin), View in Reaxys
green aq.-ethanol Dey, Kamalendu; Bandyopadhyay, Debasish; Bhar, Jayanta Kumar; Synthesis and
Reactivity in Inorganic and Metal-Organic Chemistry; vol. 18; (1988); p. 849 - 870 ; (from
Gmelin), View in Reaxys
dull green Rindermann, W.; Eldik, R. van; Inorganica Chimica Acta; vol. 64; (1982); p. L203 -
L204 ; (from Gmelin), View in Reaxys
green H2O Linhard, M.; Weigel, M.; Z. Anorg. Chem.; vol. 271; (1952); p. 101 - 114,
View in Reaxys; vol. Co: SVol.B2; 98, page 520 - 522 ; (from Gmelin), View in Reaxys
green water Werner, A.; Ber.; vol. 44; (1911); p. 875 - 875, View in Reaxys; Joergensen, S. M.; Jour-
nal fuer Praktische Chemie (Leipzig); vol. 39; (1889); p. 16 - 16, View in Reaxys; Joer-
gensen, S. M.; Journal fuer Praktische Chemie (Leipzig); vol. 39; (1889); p. 18 - 18,
View in Reaxys; vol. Co: MVol.B; 100, page 238 - 241 ; (from Gmelin), View in Reaxys
emerald green Joergensen, S. M.; Journal fuer Praktische Chemie (Leipzig); vol. 39; (1889); p. 16 - 16,
View in Reaxys; vol. Co: MVol.B; 100, page 238 - 241 ; (from Gmelin), View in Reaxys
dark green vol. Co: SVol.B2; 98, page 520 - 522, View in Reaxys; Bailar, J. C.; Fernelius, W. C.,
Inorganic syntheses, Bd. 2, New York-London 1946, S. 222/5 ; (from Gmelin),
View in Reaxys
Crystal System (1)
Crystal System References
Monoclinic Becker, K. A.; Grosse, G.; Plieth, K.; Naturwissenschaften; vol. 42; (1955); p. 254 - 255, View in Reaxys;
vol. Co: SVol.B2; 98, page 520 - 522, View in Reaxys; Dash; Ajikumar; Kamruddin; Tyagi; Thermochimica
Acta; vol. 334; nb. 1-2; (1999); p. 141 - 148 ; (from Gmelin), View in Reaxys
Electrolytic Conductivity (1)
1 of 1 Electrolytic Conductivity 0.1005 - 0.1546
[Sl/(cmmol)]
Temperature (Electrolyt- 25
ic Conductivity) [C]
Solvent (Electrolytic H2O
Conductivity)
Kind of Conductivity Molar conductivity
Comment (Electrolytic dilution 125 l/mol; depending on time;
Conductivity)
Werner, A.; Herty, Ch.; Z. phys. Ch.; vol. 38; (1901); p. 341 - 341, View in Reaxys; vol. Co: MVol.B; 100, page 238 -
241 ; (from Gmelin), View in Reaxys
Enthalpy of Formation (1)
Enthalpy of For- Temperature (En- References
mation [Jmol-1] thalpy of Forma-
tion) [C]
-729100 25 vol. Co: SVol.B2; 98, page 520 - 522, View in Reaxys; Rossini, F. D.; Wagman, D. D.;
Evans, W. H.; Levine, S.; Jaffe, I.; Circ. Bur. Stand. Nr. 500 (1952) 259 ; (from Gmelin),
View in Reaxys

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Elsevier Properties SA and used under license.
Interatomic Distances and Angles (1)
Description References
Interatomic dis- Becker, K. A.; Grosse, G.; Plieth, K.; Zeitschrift fuer Kristallographie, Kristallgeometrie, Kristallphysik, Kris-
tances and an- tallchemie; vol. 112; (1959); p. 375 - 384, View in Reaxys; vol. Co: SVol.B2; 98, page 520 - 522 ; (from Gme-
gles lin), View in Reaxys
Magnetic Data (1)
Description (Mag- References
netic Data)
Diamagnetic Csaszar, J.; Acta Chimica Hungarica; vol. 130; nb. 5; (1993); p. 639 - 646 ; (from Gmelin), View in Reaxys
Magnetic Susceptibility (1)
Magnetic Sus- References
ceptibility
[10-6cm3mol-1]
-151 Berkman, S.; Zocher, H.; Z. phys. Ch.; vol. 124; (1926); p. 324 - 324, View in Reaxys; vol. Co: MVol.B; 100,
page 238 - 241 ; (from Gmelin), View in Reaxys
Mechanical Properties (1)
Description (Me- References
chanical Proper-
ties)
Molar volume Spacu, P. G.; Bull. Sect. Sci. Acad. Roum.; vol. 21; (1938); p. 35 - 37, View in Reaxys; vol. Co: SVol.B2; 98,
page 520 - 522, View in Reaxys; Daffner, Georg; Palmer, Donald A.; Kelm, Hartwig; Inorganica Chimica
Acta; vol. 61; nb. C; (1982); p. 57 - 68 ; (from Gmelin), View in Reaxys
Optics (2)
Description (Op- References
tics)
Circular dichroism Schipper, Pieter E.; Rodger, Alison; Journal of the American Chemical Society; vol. 107; (1985); p. 3459 -
3465, View in Reaxys; Rodger, Alison; Inorganica Chimica Acta; vol. 122; (1986); p. 25 - 30,
View in Reaxys; Schipper, Pieter E.; Rodger, Alison; Inorganica Chimica Acta; vol. 99; (1985); p. L41 -
L42 ; (from Gmelin), View in Reaxys
Magnetooptical Hollebone, Bryan R.; Langford, Cooper H.; Malkhasian, Aramice Y. S.; Canadian Journal of Chemistry;
effect vol. 63; (1985); p. 1918 - 1921 ; (from Gmelin), View in Reaxys
Solubility (MCS) (4)
1 of 4 Comment (Solubility not readily sol. in water
(MCS))
Swain, Trilochan; Mohanty, Prakash; Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chem-
istry; vol. 41; nb. 5; (2011); p. 491 - 506 ; (from Gmelin), View in Reaxys
2 of 4 Comment (Solubility readily sol. in water
(MCS))
Sharma, Raj Pal; Bala, Rajni Sharma Ritu; Venugopalan; Journal of Molecular Structure; vol. 789; nb. 1-3;
(2006); p. 133 - 141 ; (from Gmelin), View in Reaxys
3 of 4 Comment (Solubility sparingly sol. in DMSO and DMF
(MCS))
Jackson; Begbie; Inorganica Chimica Acta; vol. 61; nb. C; (1982); p. 167 - 172 ; (from Gmelin), View in Reaxys
4 of 4 Comment (Solubility readily sol. in H2O;
(MCS))
vol. Co: SVol.B2; 98, page 520 - 522, View in Reaxys; Bailar, J. C.; Fernelius, W. C., Inorganic syntheses, Bd. 2,
New York-London 1946, S. 222/5 ; (from Gmelin), View in Reaxys
Space Group (1)
Space Group Comment (Space References
Group)
14 a = 9.49 Ang- Becker, K. A.; Grosse, G.; Plieth, K.; Naturwissenschaften; vol. 42; (1955); p. 254 -
stroem, b = 8.96 255, View in Reaxys; vol. Co: SVol.B2; 98, page 520 - 522 ; (from Gmelin),
Angstroem, c = View in Reaxys
6.26 Angstroem,
= 109.267
Transport Phenomena (MCS) (1)

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1 of 1 Description (Transport Diffusion
Phenomena (MCS))
Partner (Transport Phe- aq. HNO3
nomena (MCS))
Leaist, Derek G.; Australian Journal of Chemistry; vol. 41; (1988); p. 469 - 482 ; (from Gmelin), View in Reaxys
NMR Spectroscopy (11)
1 of 11 Description (NMR Spec- Spectrum
troscopy)
Nucleus (NMR Spectro- 1H
scopy)
Solvents (NMR Spectro- water-d2
scopy)
Mitkina, Tatiana V.; Sokolov, Maxim N.; Naumov, Dmitry Y.; Kuratieva, Natalia V.; Gerasko, Olga A.; Fedin,
Vladimir P.; Inorganic Chemistry; vol. 45; nb. 17; (2006); p. 6950 - 6955 ; (from Gmelin), View in Reaxys
2 of 11 Nucleus (NMR Spectro- 59Co
scopy)
Solvents (NMR Spectro- H2O
scopy)
Temperature (NMR 20
Spectroscopy) [C]
Comment (NMR Spec- Signals given
troscopy)
Reiter; Trachevskii; Rybii; Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya; vol. 26; nb. 9;
(2000); p. 636 - 640 ; (from Gmelin), View in Reaxys
3 of 11 Nucleus (NMR Spectro- 13C
scopy)
Solvents (NMR Spectro- further solvent(s)
scopy)
Temperature (NMR 20
Spectroscopy) [C]
Comment (NMR Spec- Signals given
troscopy)
Reiter; Trachevskii; Rybii; Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya; vol. 26; nb. 9;
(2000); p. 636 - 640 ; (from Gmelin), View in Reaxys
4 of 11 Nucleus (NMR Spectro- 14N
scopy)
Solvents (NMR Spectro- further solvent(s)
scopy)
Temperature (NMR 20
Spectroscopy) [C]
Comment (NMR Spec- Signals given
troscopy)
Reiter; Trachevskii; Rybii; Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya; vol. 26; nb. 9;
(2000); p. 636 - 640 ; (from Gmelin), View in Reaxys
5 of 11 Nucleus (NMR Spectro- 1H
scopy)
Solvents (NMR Spectro- D2O
scopy)
Comment (NMR Spec- Signals given
troscopy)
Csaszar, J.; Acta Chimica Hungarica; vol. 130; nb. 5; (1993); p. 639 - 646 ; (from Gmelin), View in Reaxys
6 of 11 Nucleus (NMR Spectro- 1H
scopy)

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Solvents (NMR Spectro- tetradeuteriomethanol
scopy)
Comment (NMR Spec- Signals given
troscopy)
Csaszar, J.; Acta Chimica Hungarica; vol. 130; nb. 5; (1993); p. 639 - 646 ; (from Gmelin), View in Reaxys
7 of 11 Nucleus (NMR Spectro- 13C
scopy)
Solvents (NMR Spectro- D2O
scopy)
Comment (NMR Spec- Signals given
troscopy)
Jackson, W. Gregory; Kuzmission, A. G.; Cooper, J. N.; Henry, J. C.; Inorganic Chemistry; vol. 28; (1989); p.
1553 - 1559 ; (from Gmelin), View in Reaxys
8 of 11 Description (NMR Spec- Spectrum
troscopy)
Nucleus (NMR Spectro- 1H
scopy)
Solvents (NMR Spectro- D2O
scopy)
Comment (NMR Spec- Signals given
troscopy)
Yakovlev, Yu. B.; Yumbuu, E. A.; Shagisultanova, G. A.; Russian Journal of Inorganic Chemistry (Translation of
Zhurnal Neorganicheskoi Khimii); vol. 30; (1985); p. 1601 - 1603; Zhurnal Neorganicheskoi Khimii; vol. 30; (1985);
p. 2813 - 2816 ; (from Gmelin), View in Reaxys
9 of 11 Nucleus (NMR Spectro- 59Co
scopy)
Solvents (NMR Spectro- H2O
scopy)
Comment (NMR Spec- Signals given
troscopy)
Tarasov, V. P.; Kapanadze, T. Sh.; Tsintsadze, G. V.; Buslaev, Yu. A.; Sov. J. Coord. Chem. (Engl. Transl.); vol. 9;
(1983); p. 370 - 379; Koordinatsionnaya Khimiya; vol. 9; (1983); p. 647 - 657 ; (from Gmelin), View in Reaxys
10 of 11 Nucleus (NMR Spectro- 13C
scopy)
Solvents (NMR Spectro- water-d2
scopy)
Temperature (NMR 25
Spectroscopy) [C]
Comment (NMR Spec- Signals given
troscopy)
Dash, Kailash C.; Roychaudhury, Goutam; Journal of Molecular Structure; vol. 72; (1981); p. 269 - 280 ; (from
Gmelin), View in Reaxys
11 of 11 Description (NMR Spec- Spectrum
troscopy)
Nucleus (NMR Spectro- 1H
scopy)
Solvents (NMR Spectro- H2O
scopy)
Comment (NMR Spec- Signals given
troscopy)
Kostromina. N. A.; Reiter, L. G.; Golubkova, V. V.; Sov. Prog. Chem. (Engl. Transl.); vol. 46/12; (1980); p. 13 - 17;
Ukrainskii Khimicheskii Zhurnal (Russian Edition); vol. 46; (1980); p. 1248 - 1253 ; (from Gmelin), View in Reaxys
IR Spectroscopy (10)

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1 of 10 Description (IR Spectro- Bands
scopy)
Solvent (IR Spectrosco- potassium bromide
py)
Comment (IR Spectro- 400 cm**-1 - 4500 cm**-1
scopy)
Dash; Ajikumar; Kamruddin; Tyagi; Thermochimica Acta; vol. 334; nb. 1-2; (1999); p. 141 - 148 ; (from Gmelin),
View in Reaxys
2 of 10 Description (IR Spectro- Bands
scopy)
Solvent (IR Spectrosco- KBr
py)
Comment (IR Spectro- 1000 cm**-1 - 3240 cm**-1
scopy)
Csaszar, J.; Acta Chimica Hungarica; vol. 130; nb. 5; (1993); p. 639 - 646 ; (from Gmelin), View in Reaxys
3 of 10 Description (IR Spectro- Bands
scopy)
Solvent (IR Spectrosco- potassium bromide
py)
Comment (IR Spectro- 293 cm**-1 - 1592 cm**-1
scopy)
Mulet, D.; Calafat, A. M.; Fiol, J. J.; Terron, A.; Moreno, V.; Inorganica Chimica Acta; vol. 138; (1987); p. 199 -
204 ; (from Gmelin), View in Reaxys
4 of 10 Description (IR Spectro- Bands
scopy)
Solvent (IR Spectrosco- nujol
py)
Comment (IR Spectro- 294 cm**-1 - 365 cm**-1
scopy)
Daffner, Georg; Palmer, Donald A.; Kelm, Hartwig; Inorganica Chimica Acta; vol. 61; nb. C; (1982); p. 57 - 68 ;
(from Gmelin), View in Reaxys
5 of 10 Description (IR Spectro- Bands
scopy)
Solvent (IR Spectrosco- not given
py)
Comment (IR Spectro- 400 cm**-1 - 3300 cm**-1
scopy)
Baldwin, M. E.; Journal of the Chemical Society; (1960); p. 4369 - 4376, View in Reaxys; vol. Co: SVol.B2; 206,
page 777 - 779 ; (from Gmelin), View in Reaxys
6 of 10 Description (IR Spectro- Bands
scopy)
Solvent (IR Spectrosco- mineral oil
py)
Comment (IR Spectro- 1100 cm**-1 - 1150 cm**-1
scopy)
Chamberlain, M. M.; Bailar, J. C.; Journal of the American Chemical Society; vol. 81; (1959); p. 6412 - 6415,
View in Reaxys; vol. Co: SVol.B2; 98, page 520 - 522 ; (from Gmelin), View in Reaxys
7 of 10 Solvent (IR Spectrosco- not given
py)
Signals [cm-1] 3300
Svatos, G. F.; Curran, C.; Qagliano, J. V.; Journal of the American Chemical Society; vol. 77; (1955); p. 6159 -
6163 ; (from Gmelin), View in Reaxys

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8 of 10 Description (IR Spectro- Bands
scopy)
Solvent (IR Spectrosco- KBr
py)
Signals [cm-1] 1587
Merritt, P. E.; Wiberley, S. E.; Journal of Physical Chemistry; vol. 59; (1955); p. 55 - 57 ; (from Gmelin),
View in Reaxys
9 of 10 Description (IR Spectro- Bands
scopy)
Solvent (IR Spectrosco- potassium bromide
py)
Signals [cm-1] 1587
vol. Co: SVol.B2; 98, page 520 - 522 ; (from Gmelin), View in Reaxys
10 of 10 Description (IR Spectro- Spectrum
scopy)
Solvent (IR Spectrosco- not given
py)
Comment (IR Spectro- 400 cm**-1 - 3300 cm**-1
scopy)
vol. Co: SVol.B2; 206, page 777 - 779 ; (from Gmelin), View in Reaxys
Mass Spectrometry (1)
Comment (Mass References
Spectrometry)
Fragmentation Games, David E.; Gower, John L.; Kane-Maguire, Leon A. P.; Journal of the Chemical Society, Dalton
pattern Transactions: Inorganic Chemistry (1972-1999); (1981); p. 1994 - 1996, View in Reaxys; Pierce, Janelle;
Bush, Kenneth L.; Walton, R. A.; Cooks, R. G.; Journal of the American Chemical Society; vol. 103; nb.
10; (1981); p. 2583 - 2588 ; (from Gmelin), View in Reaxys
UV/VIS Spectroscopy (28)
1 of 28 Description (UV/VIS Band assignment
Spectroscopy)
Solvent (UV/VIS Spec- water
troscopy)
Comment (UV/VIS 249 nm - 620 nm
Spectroscopy)
Anbalagan; Maharaja Mahalakshmi; Ganeshraja; Journal of Molecular Structure; vol. 1005; nb. 1-3; (2011); p. 45
- 52 ; (from Gmelin), View in Reaxys
2 of 28 Description (UV/VIS Spectrum
Spectroscopy)
Solvent (UV/VIS Spec- not given
troscopy)
Comment (UV/VIS 350 nm - 800 nm
Spectroscopy)
Mitkina, Tatiana V.; Sokolov, Maxim N.; Naumov, Dmitry Y.; Kuratieva, Natalia V.; Gerasko, Olga A.; Fedin,
Vladimir P.; Inorganic Chemistry; vol. 45; nb. 17; (2006); p. 6950 - 6955 ; (from Gmelin), View in Reaxys
3 of 28 Description (UV/VIS Band assignment
Spectroscopy)
Solvent (UV/VIS Spec- methanol
troscopy)
Absorption Maxima (UV/ 608
VIS) [nm]
Abdel-Halim, Hamzeh M.; Abu-Surrah, Adnan S.; Baker, Hutaf M.; Zeitschrift fur Naturforschung - Section B Jour-
nal of Chemical Sciences; vol. 61; nb. 11; (2006); p. 1346 - 1350 ; (from Gmelin), View in Reaxys

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use only. Reaxys and the Reaxys trademark are owned and protected by Reed
Elsevier Properties SA and used under license.
4 of 28 Description (UV/VIS Spectrum; Band assignment
Spectroscopy)
Solvent (UV/VIS Spec- neat (no solvent, solid phase)
troscopy)
Comment (UV/VIS 310 nm - 800 nm
Spectroscopy)
Vivier, Vincent; Aguey, Francois; Fournier, Jeanine; Lambert, Jean-Francois; Bedioui, Fethi; Che, Michel;
Journal of Physical Chemistry B; vol. 110; nb. 2; (2006); p. 900 - 906 ; (from Gmelin), View in Reaxys
5 of 28 Description (UV/VIS Spectrum; Band assignment
Spectroscopy)
Solvent (UV/VIS Spec- water
troscopy)
Comment (UV/VIS 310 nm - 800 nm
Spectroscopy)
Vivier, Vincent; Aguey, Francois; Fournier, Jeanine; Lambert, Jean-Francois; Bedioui, Fethi; Che, Michel;
Journal of Physical Chemistry B; vol. 110; nb. 2; (2006); p. 900 - 906 ; (from Gmelin), View in Reaxys
6 of 28 Description (UV/VIS Spectrum; Band assignment
Spectroscopy)
Solvent (UV/VIS Spec- acetonitrile
troscopy)
Comment (UV/VIS 310 nm - 800 nm
Spectroscopy)
Vivier, Vincent; Aguey, Francois; Fournier, Jeanine; Lambert, Jean-Francois; Bedioui, Fethi; Che, Michel;
Journal of Physical Chemistry B; vol. 110; nb. 2; (2006); p. 900 - 906 ; (from Gmelin), View in Reaxys
7 of 28 Description (UV/VIS Spectrum; Band assignment
Spectroscopy)
Solvent (UV/VIS Spec- dimethyl sulfoxide
troscopy)
Comment (UV/VIS 310 nm - 800 nm
Spectroscopy)
Vivier, Vincent; Aguey, Francois; Fournier, Jeanine; Lambert, Jean-Francois; Bedioui, Fethi; Che, Michel;
Journal of Physical Chemistry B; vol. 110; nb. 2; (2006); p. 900 - 906 ; (from Gmelin), View in Reaxys
8 of 28 Description (UV/VIS Spectrum; Band assignment
Spectroscopy)
Solvent (UV/VIS Spec- N,N-dimethyl-formamide
troscopy)
Comment (UV/VIS 310 nm - 800 nm
Spectroscopy)
Vivier, Vincent; Aguey, Francois; Fournier, Jeanine; Lambert, Jean-Francois; Bedioui, Fethi; Che, Michel;
Journal of Physical Chemistry B; vol. 110; nb. 2; (2006); p. 900 - 906 ; (from Gmelin), View in Reaxys
9 of 28 Description (UV/VIS Spectrum; Band assignment
Spectroscopy)
Solvent (UV/VIS Spec- H2O
troscopy)
Comment (UV/VIS 357.143 nm - 625 nm
Spectroscopy)
Csaszar, J.; Acta Chimica Hungarica; vol. 130; nb. 5; (1993); p. 639 - 646 ; (from Gmelin), View in Reaxys
10 of 28 Description (UV/VIS Spectrum; Band assignment
Spectroscopy)
Solvent (UV/VIS Spec- N,N-dimethylformamide=DMF
troscopy)
Comment (UV/VIS 357.143 nm - 625 nm
Spectroscopy)

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use only. Reaxys and the Reaxys trademark are owned and protected by Reed
Elsevier Properties SA and used under license.
Csaszar, J.; Acta Chimica Hungarica; vol. 130; nb. 5; (1993); p. 639 - 646 ; (from Gmelin), View in Reaxys
11 of 28 Description (UV/VIS Band assignment
Spectroscopy)
Solvent (UV/VIS Spec- methanol
troscopy)
Comment (UV/VIS 389.105 nm - 613.121 nm
Spectroscopy)
Csaszar, J.; Acta Chimica Hungarica; vol. 130; nb. 5; (1993); p. 639 - 646 ; (from Gmelin), View in Reaxys
12 of 28 Description (UV/VIS Band assignment
Spectroscopy)
Solvent (UV/VIS Spec- dimethylsulfoxide=DMSO
troscopy)
Comment (UV/VIS 400 nm - 611.995 nm
Spectroscopy)
Csaszar, J.; Acta Chimica Hungarica; vol. 130; nb. 5; (1993); p. 639 - 646 ; (from Gmelin), View in Reaxys
13 of 28 Solvent (UV/VIS Spec- nitric acid
troscopy)
Comment (UV/VIS aq. HNO3
Spectroscopy)
Absorption Maxima (UV/ 525
VIS) [nm]
Leaist, Derek G.; Australian Journal of Chemistry; vol. 41; (1988); p. 469 - 482 ; (from Gmelin), View in Reaxys
14 of 28 Solvent (UV/VIS Spec- nitric acid
troscopy)
Comment (UV/VIS aq. HNO3
Spectroscopy)
Absorption Maxima (UV/ 625
VIS) [nm]
Leaist, Derek G.; Australian Journal of Chemistry; vol. 41; (1988); p. 469 - 482 ; (from Gmelin), View in Reaxys
15 of 28 Solvent (UV/VIS Spec- neat (no solvent, solid phase)
troscopy)
Comment (UV/VIS 354 nm - 617 nm
Spectroscopy)
Mulet, D.; Calafat, A. M.; Fiol, J. J.; Terron, A.; Moreno, V.; Inorganica Chimica Acta; vol. 138; (1987); p. 199 -
204 ; (from Gmelin), View in Reaxys
16 of 28 Description (UV/VIS Spectrum
Spectroscopy)
Solvent (UV/VIS Spec- H2O
troscopy)
Comment (UV/VIS 400 nm - 650 nm
Spectroscopy)
Rodger, Alison; Inorganica Chimica Acta; vol. 122; (1986); p. 25 - 30 ; (from Gmelin), View in Reaxys
17 of 28 Description (UV/VIS Spectrum
Spectroscopy)
Solvent (UV/VIS Spec- further solvent(s)
troscopy)
Comment (UV/VIS 400 nm - 650 nm
Spectroscopy)
Schipper, Pieter E.; Rodger, Alison; Inorganica Chimica Acta; vol. 99; (1985); p. L41 - L42 ; (from Gmelin),
View in Reaxys

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use only. Reaxys and the Reaxys trademark are owned and protected by Reed
Elsevier Properties SA and used under license.
18 of 28 Description (UV/VIS Spectrum; Band assignment
Spectroscopy)
Solvent (UV/VIS Spec- H2O
troscopy)
Comment (UV/VIS 400 nm - 650 nm
Spectroscopy)
Schipper, Pieter E.; Rodger, Alison; Journal of the American Chemical Society; vol. 107; (1985); p. 3459 - 3465 ;
(from Gmelin), View in Reaxys
19 of 28 Description (UV/VIS Spectrum
Spectroscopy)
Solvent (UV/VIS Spec- solid
troscopy)
Comment (UV/VIS 200 nm - 850 nm
Spectroscopy)
Kalalova, E.; Populova, O.; Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khi-
mii); vol. 27; (1982); p. 1777 - 1782; Zhurnal Neorganicheskoi Khimii; vol. 27; (1982); p. 3145 - 3152 ; (from Gme-
lin), View in Reaxys
20 of 28 Description (UV/VIS Band assignment
Spectroscopy)
Solvent (UV/VIS Spec- not given
troscopy)
Comment (UV/VIS 200 nm - 450.45 nm
Spectroscopy)
Lever, A. B. P.; Pickens, S. R.; Inorganica Chimica Acta; vol. 45; (1980); p. L185 - L188 ; (from Gmelin),
View in Reaxys
21 of 28 Description (UV/VIS Spectrum
Spectroscopy)
Solvent (UV/VIS Spec- not given
troscopy)
Comment (UV/VIS 250 nm - 550 nm
Spectroscopy)
Babaeva, A. V.; Rudyi, R. I.; Zhurnal Neorganicheskoi Khimii; vol. 1; nb. 5; (1956); p. 42 - 51; Zhurnal Neorganiche-
skoi Khimii; vol. 1; (1956); p. 921 - 929, View in Reaxys; vol. Co: SVol.B2; 98, page 520 - 522 ; (from Gmelin),
View in Reaxys
22 of 28 Description (UV/VIS Spectrum
Spectroscopy)
Solvent (UV/VIS Spec- not given
troscopy)
Comment (UV/VIS 357.143 nm - 625 nm
Spectroscopy)
Basolo, F.; Ballhausen, C. J.; Bjerrum, J.; Acta Chemica Scandinavica (1947-1973); vol. 9; (1955); p. 810 - 814,
View in Reaxys; vol. Co: SVol.B2; 95, page 513 - 516 ; (from Gmelin), View in Reaxys
23 of 28 Description (UV/VIS Band assignment
Spectroscopy)
Solvent (UV/VIS Spec- H2O
troscopy)
Comment (UV/VIS 241 nm - 621 nm
Spectroscopy)
DAVIES; MAMALIS; PETROW; STURGEON; BEAVEN; HOLIDAY; JOHNSON; The Journal of pharmacy and phar-
macology; vol. 4; nb. 7; (1952); p. 448 - 465, View in Reaxys; vol. Co: SVol.B2; 95, page 513 - 516 ; (from Gmelin),
View in Reaxys
24 of 28 Description (UV/VIS Spectrum
Spectroscopy)

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use only. Reaxys and the Reaxys trademark are owned and protected by Reed
Elsevier Properties SA and used under license.
Solvent (UV/VIS Spec- not given
troscopy)
Basolo, F.; Journal of the American Chemical Society; vol. 72; (1950); p. 4393 - 4397, View in Reaxys; vol. Co:
SVol.B2; 111, page 555 - 557 ; (from Gmelin), View in Reaxys
25 of 28 Solvent (UV/VIS Spec- not given
troscopy)
Absorption Maxima (UV/ 476.19
VIS) [nm]
Shibata, Y.; J. Coll. Sci., Imp. Univ. Tokyo; vol. 37; nb. 2; (1915); p. 24 - 24, View in Reaxys; Shibata, Y.; J. Coll.
Sci., Imp. Univ. Tokyo; vol. 37; nb. 2; (1915); p. 25 - 25, View in Reaxys; vol. Co: MVol.B; 100, page 238 - 241 ;
(from Gmelin), View in Reaxys
26 of 28 Solvent (UV/VIS Spec- H2O
troscopy)
Comment (UV/VIS 250 nm - 700 nm
Spectroscopy)
Schleicher, C.; Ueber Absorptionsspektren von Komplexsalzen, Dissert. Zuerich, 1921, S. 23, View in Reaxys;
Schleicher, C.; Ueber Absorptionsspektren von Komplexsalzen, Dissert. Zuerich, 1921, S. 42 ; (from Gmelin),
View in Reaxys
27 of 28 Solvent (UV/VIS Spec- not given
troscopy)
Comment (UV/VIS 250 nm - 600 nm
Spectroscopy)
Gordienko, A.; Untersuchungen ueber die Beziehung zwischen Farbe und Konstitution chemischer Verbindungen,
Dissert. Zuerich 1912, S. 90, View in Reaxys; Gordienko, A.; Untersuchungen ueber die Beziehung zwischen Farbe
und Konstitution chemischer Verbindungen, Dissert. Zuerich 1912, S. 91, View in Reaxys; vol. Co: MVol.B; 100,
page 238 - 241 ; (from Gmelin), View in Reaxys
28 of 28 Solvent (UV/VIS Spec- water
troscopy)
Comment (UV/VIS 250 nm - 700 nm
Spectroscopy)
vol. Co: MVol.B; 100, page 238 - 241 ; (from Gmelin), View in Reaxys
Raman Spectroscopy (1)
Description (Ram- References
an Spectroscopy)
Raman Vivier, Vincent; Aguey, Francois; Fournier, Jeanine; Lambert, Jean-Francois; Bedioui, Fethi; Che, Mi-
chel; Journal of Physical Chemistry B; vol. 110; nb. 2; (2006); p. 900 - 906 ; (from Gmelin), View in Reaxys
Luminescence Spectroscopy (1)
Description (Lu- References
minescence
Spectroscopy)
X-ray emission Obashi, Masayoshi; Matsukawa, Tokuo; Journal of the Physical Society of Japan; vol. 53; nb. 12; (1984);
spectrum p. 4420 - 4424 ; (from Gmelin), View in Reaxys
Use (4)
Laboratory Use References
and Handling
information on Hernandez, Billy; Wang, Yanju; Zhang, Dong; Selke, Matthias; Chemical Communications; nb. 9; (2006);
use p. 997 - 999 ; (from Gmelin), View in Reaxys
stable for pro- Hernandez, Billy; Wang, Yanju; Zhang, Dong; Selke, Matthias; Chemical Communications; nb. 9; (2006);
longed period in p. 997 - 999 ; (from Gmelin), View in Reaxys
CD3OD-DMF-d7
handling descri- Paulraj, K.; Balasubramaniam, T. M.; Raman, M.; Ramalingam, S. K.; Indian Journal of Chemistry, Section
bed A: Inorganic, Physical, Theoretical & Analytical; vol. 25; nb. 1; (1986); p. 44 - 47 ; (from Gmelin),
View in Reaxys
thermal decompo- Wendlandt, W. W.; Texas J. Sci.; vol. 10; (1958); p. 271 - 279; C. A.; (1959); p. 6864, View in Reaxys; vol.
sition; Co: SVol.B2; 98, page 520 - 522 ; (from Gmelin), View in Reaxys

Copyright 2017 Reed Elsevier Properties SA. All rights reserved. Authorized 13/13 2017-11-17 18:29:33
use only. Reaxys and the Reaxys trademark are owned and protected by Reed
Elsevier Properties SA and used under license.