RESTRICTED SUBSTANCE LIST

Sustainable Production
Assignment - III

ANKITA
 Restricted Substance List
Aromatic Amines from Azo Dimethylfumarate (DMFu)
Colorants Flame-retardant chemicals
Disperse dyes Formaldehyde
Other Colorants Glycols
Dyes Carcinogenic or Halogenated Solvents
Equivalent Concern Metals
Chlorophenols Organotin Compounds
BISPHENOL A Perfluorinated and Polyfluorinated Chemicals (PFCs)
Chlorinated Paraffin Phthalates
Chlororganic Carriers Polycyclic Aromatic Hydrocarbons (PAHs)
Dimethylformamide (DMFa) Volatile Organic Compounds (VOCs)
 DYES
Azo Amines, Disperse Dyes, Other Colorants

Most cases of textile dermatitis arise from inappropriate dye selection

Dyes have low perspiration fastness on the textile substrate
e.g. Disperse dyes on nylon (nylon stocking allergy) now use acid dyes instead
Certain disperse dyes (e.g Blue 106/Blue 124) on nylon/elastane (leotards) in heavy
depths of shade with poor perspiration fastness
A high incidence of bladder cancer has long been associated with workers involved in
the manufacture of benzidine dyes, and also with workers in the dyeing industry
handling the manufactured benzidine dyes
Azo Amines
Azo dyes represent about 70% of all dyes used worldwide.
Azo dyes and pigments are colorants that incorporate one or several azo groups (-N=N-) bond with
aromatic compounds.

Under certain conditions, azo colourants can undergo a cleavage of the -N=N- azo bond to form
NH2 group or an Amino group. Such a compound is called an amine.

Some amines are carcinogenic in nature i.e. they can cause cancer and hence
there is a ban on usage of dyes and pigments that can release such amines.

http://nimkartek.com/blog/banned-amines-in-textile-and-leather/
Thousands of azo dyes exist, but only those
which degrade to form the listed cleavable
amines are restricted. Azo dyes that release
these amines are regulated and should no
longer be used for dyeing of textiles.

There are 26 types of carcinogenic primary

aromatic amines (PAAs) originated from azo
dyes in commercial textile products.

http://nimkartek.com/blog/banned-amines-in-textile-and-leather/
S. No. Substance CAS No.
1. 4-aminodiphenyl 92-67-1
2. Benzidine 92-87-5
3. 4-chloro-o-toluidine 95-69-2
4. 2-naphthylamine 91-59-8
5. o-Aminoazotoluene 97-56-3
6. 2-amino-4-nitrotoluene 99-55-8
7. 4-chloroaniline 106-47-8
8. 2,4-diaminoanisole 615-05-4
9. 4,4-diaminodiphenylmethane 101-77-9
10. 3,3-dichlorobenzidine 91-94-1
11. 3,3-dimethoxybenzidine 119-90-4
12. 3,3-dimethylbenzidine 119-93-7
3,3-dimethyl-
13. 838-88-0
4,4diaminodiphenylmethane
14. 4-cresidine 120-71-8
 4,4-methylene-bis-(2-
15. 101-14-4
chloroaniline)
16. 4,4-oxydianiline 101-80-4
17. 4,4-thiodianiline 139-65-1
18. 2-aminotoluene 95-53-4
19. 2,4-diaminotoluene 95-80-7
20. 2,4,5-trimethylaniline 137-17-7
21. 2-methoxyaniline 90-04-0
22. 4-aminoazobenzene 60-09-3
23. 2,4-Xylidine 60-09-3
24. 2,6-Xylidine 87-62-7
25. 5-Chloro-2-methylaniline 95-79-4
26. p-Phenylenediamine 106-50-3
27. N,N-Dimethylaniline 121-69-7
28. Aniline 62-53-3
Test methods to be used for the analysis of Banned Amines in Finished Articles are:

Substrate Type Test Method

ISO 24362-1:2014
Textile
GB/T 17592 (China)

ISO 24362-3:2014
Textile (for 4-aminoazobenzene)
GB/T 23344 (China)

Natural Leather (All amines except 4- ISO 17234-1: 2015

aminoazobenzene) GB/T 19942 (China)

Leather (for 4-aminoazobenzene) ISO 17234-2: 2011

Maximum Allowable Concentration on finished articles is 20 mg/Kg.

DISPERSE DYES

Disperse dyes are a class of water-insoluble dyes that penetrate the fiber system of synthetic or
manufactured fibers and are held in place by physical forces without forming chemical bonds.

Restricted disperse dyes are suspected of causing allergic reactions and are called allergenic
dyes.

The allergenic disperse dyes refer to the dyes that will cause allergy to skin, mucous membrane
or respiratory passage allergy of human body or animal.

It is mainly used on polyester & nylon. Rarely used on acetate and viscose.

Often found in stockings and sportswear and synthetic lining materials in footwear.

http://www.cmatcl.com/ContentFiles/73/Dyes%20in%20Textile%20_2_.pdf
http://garmentstech.com/allergenic-disperse-dyes-its-uses/
 Limit Value Final Product
CAS No. Substance Test Method

2475-45-8 C.I. Disperse Blue 1

2475-46-9 C.I. Disperse Blue 3

12222-97-8 C.I. Disperse Blue 102

Not detected. Prohibited.
12223-01-7 C.I. Disperse Blue 106

61951-51-7 C.I. Disperse Blue 124 DIN 54231:2005

Laboratory Limit 75 ppm
2832-40-8 C.I. Disperse Yellow 3 each as impurities.
730-40-5 C.I. Disperse Orange 3
12223-33-5,
C.I. Disperse Orange 37/76
13301-61-6
2872-52-8 C.I. Disperse Red 1
OTHER CARCINOGENIC COLORANTS
 Most of these substances are regulated and should no longer be used for dyeing of textiles.

Limit Value Final

CAS No. Substance Test Method
Product
1937-37-7 Direct Black 38

2602-46-2 Direct Blue 6

573-58-0 Direct Red 28

632-99-5 Basic Violet 14

250 ppm
DIN 542317
2475-45-8 Disperse Blue 1
2475-46-9 Disperse Blue 3
2475-46-9 Basic Blue 26 (with Michlers Ketone > 0.1%)
10309-95-2 Basic Green 4
82-28-0 Disperse Orange 11
CHLOROPHENOLS
Chlorophenols are polychlorinated compounds used as preservatives or pesticides.

Pentachlorophenol (PCP) and tetrachlorophenol (TeCP) are sometimes used to

prevent mold and kill insects when growing cotton and when storing/ transporting
fabrics. PCP and TeCP can also be used as preservatives in print pastes.

Due to its toxicity to the aquatic environment, pentachlorophenol (PCP) is banned in textile products
worldwide. Above certain levels, long-term exposure to some chlorophenols may result in the
development of particular cancers.

Safer Alternatives-
Biocide, preservative and mold control products that do not contain chlorophenols, for example:
Zinc-2-pyridinthiol-N-oxide
2,2-dihydroxy-5,5-dichlorodiphenylmethane-ester
 CAS No. Substance Limit Value Final Product Test Method

CHOROPHENOLS
87-86-5 Pentachlorophenol (PCP) Not Detected
64 LFGB 82.02.812
Mono-, Di-, Trichlorophenols Or
Various (TriCP) and Tetrachorophenol (0.05 ppm each)
DIN EN ISO 17070:2015
(TeCP)
59-50-7 4-Chloro-3-methyl phenol
OTHERS
624-49-7 Dimethyl fumarate (DMFu)
Solvent extraction / GC-
90-43-7 o-Phenylphenol (OPP) MS, LC-MS for
Usage Ban
26530-20-1 confirmation
26172-55-4
Sensitizing Isothiazolinones
2682-20-4
2634-33-5
 BISPHENOL A
Testing required for food-contact items including water bottles and mouth guards
Banned from use as a monomer in the production of items that come into contact with food.
Used in the production of epoxy resins, polycarbonate plastics, flame retardants and PVC.
It is reported that Bisphenol A is an endocrine disrupter, which can mimic the body's own
hormones and may lead to negative health effect.
Prohibited from use in food and drink containers, and items intended to come into contact with
the oral cavity.
Safer alternative - bisguaiacol-F (BGF) (Under study)

CAS No. Substance Limit Value Final Product Test Method

DIN EN ISO 18857-2

80-05-7 Bisphenol- A (BPA) 1 ppm
(mod)

http://www.cirs-reach.com/Testing/Bisphenol_BPA_Testing.html
https://www.acs.org/content/acs/en/pressroom/newsreleases/2014/march/potentially-safer-
greener-alternative-to-bpa-could-come-from-papermaking-waste.html
Chlorinated Paraffin
May be used as flame retardants or as fat liquoring agents in leather production. They also can be used
as plasticizers
It can be found in plastic, rubber, adhesives, paints and lacquers, coatings, plasticisers, fat-liquoring
agents and leather.
It can cause skin dryness and cracking, and are carcinogenic. They are highly toxic to aquatic organisms,
do not readily break down in the environment and have a high potential to accumulate in living
organisms.
Alternatives alternatives include alkylphosphates and sulfonated fatty-acid esters and are available for
specific applications.

Alternatives include alkylphosphates and sulfonated fatty-acid esters

CAS No. Substance Limit Value Final Product Test Method
Short-chain chlorinated Paraffins
85535-84-8
(SCCP) (C10-C13)
50 ppm EN ISO 18219:2016
Medium-chain chlorinated
85535-84-9
Paraffins (MCCP) (C14-C17)
http://source.ethicalfashionforum.com/article/10-toxic-chemicals-to-avoid-in-your-products
Chlororganic Carriers
Chlorobenzenes and chlorotoluenes (chlorinated aromatic hydrocarbons) can be used as carriers in the dyeing
process of polyester or wool/ polyester fibres. They can also be used as solvents.

CAS No. Substance Limit Value Final Product Test Method

Various Chlorotoluene (2,3,4)
Various Dichlorotoluene
Various Trichlorotoluene
Various Tetrachlorotoluene
877-11-2 Pentachlortoluene
Various Dichlorobenzene 0.1 ppm DIN 54232:2010
Various Trichlorobenzene
Various Tetrachlorobenzene
608-93-5 Pentachlorobenzene
118-74-1 Hexachlorobenzene
95-50-1 1,2-Dichlorobenzene
Dimethylformamide
DMFa is a solvent used in plastics, rubber, and polyurethane (PU) coating.
Water-based PU does not contain DMFa and is therefore preferable.

Uses
As solvent in synthesis of chemicals.
As solvent in the production of polyurethane coated textiles such as artificial leather, rain
and protection wear, footwear, medical mattress covers, surgical incise films etc
as solvent in the production of synthetic fibres
In other applications such as in the electronic industry, in formulation of mixtures, as gas
stabiliser in acetylene cylinders, in the production of medical devices
Alternatives - For many reactions, it can be replaced with dimethyl sulfoxide

CAS No. Substance Limit Value Final Product Test Method

DIN CEN ISO/TS
68-12-2 Dimethylformamide (DMFa) 500 ppm
16189:2013

https://www.linkedin.com/pulse/dimethylformamide-dmf-applications-alternatives-iqbal-hossain
https://echa.europa.eu/documents/10162/34ec457d-045e-4836-82ee-2753fcb32b62
Dimethylfumarate
DMFu is an anti-mold agent used in sachets in packaging to prevent
the buildup of mold, especially during shipping.

Used in Couches and Shoes.

Common symptoms of DMFu include itchy skin, irritation, redness, burns, and even acute
respiratory problems in some serious cases.

CAS No. Substance Limit Value Final Product Test Method

624-49-7 Dimethylfumarate (DMFu) 0.1 ppm CEN ISO/TS 16186:2012

http://www.bureauveritas.com/services+sheet/eu-bans-dimethyl-
fumarate_13534?presentationtemplate=bv_master_v2/Services_sheet_full_story_presentation_v2
Flame-retardant chemicals

They arre rarely used to meet flammability requirements in

childrens clothing and adult products.
They should no longer be used in apparel and footwear.

Health issues related to flame retardants are infertility, birth defects,

neurodevelopmental delays, reduced IQ and behavioral problems in
children, hormone disruptions, and cancer.
CAS No. Substance Limit Value Final Test Method
Product
25637-99-4
Hexabromocyclododecane20 (HBCDD)
3194-55-6
Various Polybrominated biphenyls (PBBs)
Penta-bromodiphenyl ether (pentaBDE) Solvent extraction / GC-MS
32534-81-9

32536-52-0 Octa-bromodiphenyl ether (octaBDE)

1163-19-5 Deca-bromodiphenyl ether (decaBDE)
78-30-8 Tri-o-cresyl phosphate
26-72-7 Tris(2,3-dibromopropyl) phosphate (TRIS) 5 ppm
KOH digestion / headspace
545-55-1 Tris(1-aziridinyl)-phosphine oxide (TEPA) analysis of ethyleneimine
fragment by GC-MS
115-96-8 Tris(2-chloroethyl) phosphate (TCEP)
2,2-Bis(bromomethyl)-1,3-propanediol (BBMP) Solvent extraction / GC-MS
3296-90-0
or LC-MS
13674-87-8 Tris(1,3-dichloro-isopropyl) phosphate (TDCP)
79-94-7 Tetrabromobisphenol A (TBBPA)
Formaldehyde
Formaldehyde acts as an agent in textile finish resins which helps to prevent
shrinkage and to make a fabric crease-resistant. Other qualities of textile finish
resins include rendering fabric perspiration proof, waterproof and mothproof.

After textile dyes, formaldehyde and textile finish resins (also called durable-
press resins or permanent press clothing finishes) are the most frequently
reported allergens. The release of formaldehyde can irritate mucous membranes
and the respiratory tract.
CAS No. Substance Limit Value Final Product Test Method
Textile: JIS L 1041-1983
A (Japan Law 112) or EN
Adults and children: 75 ppm ISO 14184- 1:2011
Infant/Toddler: 16 ppm See Leather: ISO 17226-
50-00-0 Formaldehyde
Table 1 on page 6 for age 2:2008 and ISO 17226-
ranges and sizing. 1:2008 confirmation
method in case of
interferences.
http://source.ethicalfashionforum.com/article/10-toxic-chemicals-to-avoid-in-your-products
 Glycols
In apparel and footwear, glycols have a wide range of uses including as solvents for finishing/cleaning,
printing agents, and dissolving and diluting fats, oils and adhesives

Exposure to glycol ethers may cause damage to a developing fetus and low fertility in men.

CAS No. Substance Limit Vale Final Product Test Method

111-96-6 Bis(2-methoxyethyl)-ether
110-80-5 2-ethoxyethanol
111-15-9 2-ethoxyethyl acetate
110-71-4 Ethylene glycol dimethyl ether High-performance liquid
50 ppm chromatography (HPLC),
109-86-4 2-methoxyethanol LC-MS
110-49-6 2-methoxyethylacetate
70657-70-4 2-methoxypropylacetate
112-49-2 Triethylene glycol dimethyl ether
Halogenated Solvents
In apparel and footwear, solvents are used as finishing/cleaning and printing agents, for dissolving
and diluting fats, oils and adhesives (e.g., in degreasing or cleaning operations).

They may affect central nervous system, kidneys and liver, cause dermatitis and irritation of skin,
eyes, upper respiratory tract and mucous membranes.

Over-exposure in poorly ventilated space may lead to depression, headache, sleepiness,

unconsciousness and even death.

Some chlorinated solvents cause cancer in rats and mice at high exposure levels.
CAS No. Substance Limit Vale Final Product Test Method
107-06-2 1,2-dichloroethane
5 ppm
75-09-2 Methylene chloride
GC-MS
127-18-4 Tetrachloroethylene
40 ppm
79-01-6 Trichloroethylene
http://www.idc-online.com/technical_references/pdfs/chemical_engineering/Halogenated_solvents.pdf
Metals
A range of heavy metals are used in textile dyes and pigments, some of the most toxic being
antimony, cadmium, lead, mercury and chromium VI.

Antimony can be found in cotton, synthetic fibres and leather.

Cadmium is present in pigments and dyes applied to natural and synthetic textiles and leather.
In particular it is found in red, orange, yellow and green dyes.
Lead and mercury are present in dyes used across natural and synthetic textile fibres, though
not contained in high-quality dyes.
Chrome VI is mainly found in poorly tanned leathers and can be found on wool, cashmere and
angora garments where it is used as a mordant in after-chrome dyeing processes.

Harmful Effects :
High levels of lead can seriously affect the nervous system.
Cadmium and lead and Chromium VI are classified as carcinogens.
Mercury and lead have been classified as priority hazardous substances

http://source.ethicalfashionforum.com/article/10-toxic-chemicals-to-avoid-in-your-products
Aleternatives:

DyStar, a german based sustainable textile auxiliaries and colorants supplier has
launched a new Levafix ECO Black dye, compliant with Oeko-Tex standard 100, free
of heavy metals and restricted aromatic amines.
US based company Greener Shades offer a range of heavy metal free acid dyes,
used for silk, wool, nylon and animal fibres.

http://source.ethicalfashionforum.com/article/10-toxic-chemicals-to-avoid-in-your-products
 CAS No. Substance Limit Value Final Product Test Method
Antimony (Sb)
(Found in or used as a catalyst in
7440-36-0 polymerization of polyester, flame Extractable: 30 ppm EN ISO 17294-2:2014
retardants, fixing agents,
pigments and alloys..)
Arsenic (As)
(Arsenic and its compounds can
be used in preservatives, Extractable: 0.2 ppm Total:
7440-38-2 EN ISO 17294-2 :2014
pesticides and defoliants for 100 ppm
cotton, synthetic fibers, paints,
inks, trims and plastics. )
Barium (Ba)
(Barium and its compounds can
be used in pigments for inks,
Extractable: 1,000 ppm
7440-39-3 plastics, surface coatings, as well EN ISO 17294-2:2014
(Lab : 100 ppm)
as in dyeing, mordant, filler in
plastics, textile finish, and leather
tanning.)
 CAS No. Substance Limit Value Final Product Test Method
Cadmium (Cd)
(Cadmium compounds are used
Extractable: 0.1 ppm Total:
as pigments (especially in red, EN ISO EN ISO 17294-
7440-43-9 Adults: 75 ppm Children and
orange, yellow and green); as a 2:2014
Infant/Toddler: 40 ppm
stabilizer for PVC; and in
fertilizers, biocides and paints.
Chromium (Cr)
(Chromium compounds can be
used as dyeing additives, dye- Extractable for textiles: 1
7440-47-3 fixing agents, color fastness after- ppm Leather footwear for EN ISO 17294-2:2014
treatments, dyes for wool, silk Infant/ Toddler: 60 ppm
and polyamide (especially dark
shades) and leather tanning.)
Chromium VI
Textile: EN ISO 17294-2
(Though typically associated with Leather: 3 ppm Knitted
Leather: EN 17075-
18540-29-9 leather tanning, Chromium VI also textiles for Infant/Toddler:
1:2015 Ageing test is
may be used in the dyeing of wool 0.5 ppm
used at brand discretion.
after the chroming process)
 CAS No. Substance Limit Value Final Product Test Method
Cobalt (Co)
(Cobalt and its compounds can be
7440-48-4 used in alloys, pigments, dyestuff, Extractable: 1 ppm EN ISO 17294-2
and the production of plastic
buttons.)
Copper (Cu)
(Copper and its compounds can
7440-50-8 be found in alloys and pigments, Extractable: 25 ppm EN ISO 17294-2:2014
and in textiles as an antimicrobial
agent.)
Extractable: Adults and
Children: 1 ppm
Lead (Pb)
Infant/Toddler: 0.2 ppm
(May be associated with plastics,
7439-92-1 Total: 90 ppm Lead in surface EN ISO 17294-2:2014
paints, inks, pigments and surface
coating: 90 ppm Includes
coatings.)
Childrens products (up to 12
years)
 CAS No. Substance Limit Value Final Product Test Method
Mercury (Hg)
(Mercury compounds can be
present in pesticides and as Extractable: 0.02 ppm Total:
7439-97-6 EN ISO 17294-2:2014
contaminants in caustic soda 0.5 ppm
(NaOH). They may also be used in
paints.)
Nickel (Ni)
(Nickel and its compounds can be
used for plating alloys and
7440-02-0 improving corrosion-resistance Extractable: 1 ppm EN ISO 17294- 2:2014
and hardness of alloys. They can
also occur as impurities in
pigments and alloys.)
Selenium (Se)
(May be found in synthetic fibres,
7782-49-2 Extractable: 500 ppm EN ISO 17294-2:2014
paints, inks, plastics and metal
trims. )
 CAS No. Substance Limit Value Final Product Test Method

Tin Screening (all materials)

Tin 0.1 mg/kg If Tin > 0.1
(May be found in metal items,
7440-31-5 mg/kg, organotin analysis EN ISO 17294-2:2014
coatings. polymers, paints and
required
adhesives.)
Organotin Compounds
Class of chemicals combining Tin and Organics such as butyl and phenyl groups
Theyre used in apparel and footwear manufacturing to prevent body odour caused by the breakdown of human
body sweat.

Organotins are also used as a heat stabiliser in PVC or as catalysts in the production of polymeric materials such as
polyester. They also may be used in anti-fungal agents and biocides or preservatives for textile and leather.

Silicone-based finishes (for example, fire retardants and water repellency) may also contain organotins.

It can affect immune and reproductive systems. As endocrine disrupters, they have been shown to prevent the
bodys hormones working properly, and can cause muscular weakness, breathing problems and severe skin, eye
and mucous membrane irritation

Alternatives:
Calcium-zinc stabilisers may be used in the form of metal carboxylates.
Organic-based stabilisers are calcium-zinc stabilisers with zinc replaced by organic costabilisers

http://source.ethicalfashionforum.com/article/10-toxic-chemicals-to-avoid-in-your-products
CAS No. Substance Limit Value Final Product Test Method

Mono-, Di- & Tri-butyltin

Various
derivatives
Mono-, Di- & Tri-methyltin
Various Solvent extraction +
derivatives
0.1 ppm each ISO 17353 [RL=0.05]
Mono-, Di- & Tri-phenyltin
Various
derivatives
Mono-, Di- & Tri-octyltin
Various
derivatives
Ortho-phenylphenol
OPP can be used for its preservative properties in leather or as a carrier in dyeing processes

CAS No. Substance Limit Value Final Product Test Method

GC-MS, LC-MS for
90-43-7 Ortho-phenylphenol (OPP) 1,000 ppm
confirmation
Perfluorinated and
Polyfluorinated Chemicals (PFCs)
Perfluorinated chemicals (PFCs) are widely used across the
industry for their non-stick and water-resistant properties, making
textile and leather products breathable while also water and stain
proof. Mostly used for outdoor apparel and footwear.

PFCs have been known to affect the liver and to alter levels of
growth and reproductive hormones. Highly resistant to
degradation, certain PFCs are banned in Europe

CAS No. Substance Limit Value Final Product Test Method

Perfluorooctane Sulfonate
2795-39-3 All materials with a
(PFOS)
repellent finish applied: 1 CEN/TS 15968:2014
Perfluorooctanoic Acid (PFOA) g/m2 each
3825-26-1
and its salts and esters

http://source.ethicalfashionforum.com/article/10-toxic-chemicals-to-avoid-in-your-products
Phthalates
Esters of Ortho-phthalic acid (Phthalates) are a class of organic
compound commonly added to plastics to increase flexibility.
They are sometimes used to facilitate the molding of plastic by
decreasing its melting temperature.
Phthalates can be found in:
Flexible plastic components (e.g., PVC)
Print pastes
Adhesives
Plastic buttons
Plastic sleevings
Polymeric coatings

Harmful effects of Pthalates : Irritation of the eyes

(lacrimation), skin, nose, throat; headache, dizziness, nausea;
possible polyneuropathy, vestibular dysfunction, pain,
numbness, weakness, exhaustion
http://enhs.umn.edu/current/5103/phth/harmful.html
http://saferchemicals.org/chemicals/phthalates/
Alternatives : DINCH, ATBC, DOTP, TXIB, TOTM, DEHA http://www.chemanager-online.com/en/topics/chemicals-
distribution/phthalates-and-their-alternatives
CAS No. Substance Limit Value Final Product Test Method
28553-12-0 Di-Iso-nonylphthalate (DINP)
117-84-0 Di-n-octylphthalate (DNOP)
117-81-7 Di(2-ethylhexyl)-phthalate (DEHP)
26761-40-0 Diisodecylphthalate (DIDP)
85-68-7 Butylbenzylphthalate (BBP)
Di(C7-C11 alkyl) phthalate (DHNUP), linear +
68515-42-4
branched
Textile: GC-MS, EN ISO
Di(C6-C8 alkyl) phthalate (DIHP), branched, C7 500 ppm each
71888-89-6 14389:2014 Leather: GC-
rich Total: 1,000 ppm
MS
117-82-8 Di(2-methoxyethyl) phthalate (DMEP)
84-75-3 Di-n-hexylphthalate (DnHP)
605-50-5 Diisopentylphthalate (DIPP)
776297-69-9 n-Pentylisopentylphthalate (NPIPP)
68515-50-4 Dihexylphthalate, branched + linear
1,2-Benzenedicarboxylic acid, dipentylester,
84777-06-0
branched + linear
Polycyclic Aromatic Hydrocarbons (PAHs)
PAHs are natural components of crude oil and are common residues
from oil refining.
Oil residues containing PAHs are added to rubber and plastics as a
softener or extender and may be found in rubber, plastics, lacquers
and coatings
PAHs can be present as impurities in Carbon Black.
They also may be formed from thermal decomposition of recycled
materials during reprocessing

Occupational exposures to high levels of pollutant mixtures containing

PAHs has resulted in symptoms such as eye irritation, nausea, vomiting,
diarrhoea and confusion.

Health effects from chronic or long-term exposure to PAHs may include

decreased immune function, cataracts, kidney and liver damage (e.g.
jaundice), breathing problems, asthma-like symptoms
http://www.toxipedia.org/display/toxipedia/Polycyclic+Aromatic+Hydrocarbons
CAS No. Substance Limit Value Final Product Test Method
83-32-9 Acenaphtene
120-12-7 Anthracene
191-24-2 Benzo(g,h,i)perylene
No individual restriction
86-73-7 Fluorene
Total : 10 ppm
193-39-5 Indeno(1,2,3-cd)pyrene
91-20-3 Naphthalene
129-00-0 Pyrene AFPS GS 2014
56-55-3 Benzo(a)anthracene
50-32-8 Benzo(a)pyrene
205-99-2 Benzo(b)fluoranthene 1 ppm each
192-97-2 Benzo[e]pyrene Total : 10 ppm
218-01-9 Chrysene
53-70-3 53-70-3 Dibenzo(a,h)anthracene
Volatile Organic Compounds (VOCs)
VOCs should not be used in textile auxiliary chemical preparations.
They are also associated with solvent-based processes such as
solvent based Polyurethane coatings and glues/ adhesives. They
should not be used for any kind of facility cleaning or spot cleaning.

The health effects of volatile organic compounds will depend on the

nature of the volatile organic compound, the level of exposure, and
the length of exposure.

Long-term exposure to volatile organic compounds can cause

damage to the liver, kidneys, and central nervous system. Short-term
exposure to volatile organic compounds can cause eye and
respiratory tract irritation, headaches, dizziness, visual disorders,
fatigue, loss of coordination, allergic skin reactions, nausea, and
memory impairment.
CAS No. Substance Limit Vale Final Product Test Method
71-43-2 Benzene 5ppm
56-23-5 Carbon tetrachloride
67-66-3 Chloroform
Various Dichloroethylene
For general VOC
127-19-5 Dimethylacetamide (DMAC)
screening: GC/MS
76-01-7 Pentachloroethane headspace 120 C, 45
20 ppm each minutes. Except for
Various Tetrachloroethane
Total : 1,000 ppm DMAC: DIN CEN ISO/TS
127-18-4 Tetrachloroethylene (PER)
16189:2013
108-88-3 Toluene
Various Trichloroethane
79-01-6 Trichloroethylene
1330-20-7 Xylenes (meta-, ortho-, para-)
 Other Limits or Restrictions
CAS No. Substance Limit Value Final Product Test Method

All products: Textile

AATCC 81 GB/T7573-
None pH Materials 4.0 7.5
2009

Two tests for

confirmation: Beilsteins
Test* Burning test for
the presence of chlorine.
Infrared Analysis*
Polyvinyl-chloride (PVC) Spectroscopy (IR) with or
Prohibited from use in all
9002-86-2 (Plastic items, flexilble plastics, without solvent
products and all materials.
screen printing inks) extraction. Positive
results for both tests
indicate PVC. * PVC test
methods are qualitative,
therefore the 10% limit
is estimated sensitivity.
Glossary
GC- MS : Gas Chromatography with Mass Spectrometer
LC- MS : LiquidChromatography with Mass Spectrometer
CAS Number : It is a short string of text that refers to a chemical substance.
CAS Numbers contain a sequence of up to ten numerical digits separated into
three groups by two hyphens.
References
https://www.wewear.org/assets/1/7/RSL12english-March2013.pdf - AAFA Restricted
Substance List (RSL) (Version Date: March 2013)

Nike, Inc. Restricted Substances List & Sustainable Chemistry Guidance Release date: January
18, 2017 http://www.nikeincchemistry.com/restricted-substance-list/

Restricted Substances List (RSL) - July 2014 ( 20102015 Levi Strauss & CO.)

http://about.puma.com/damfiles/default/sustainability/environment/zdhc/program-
documents/MRSL-41e10a19cf66527dba8c81660613c403.pdf
Manufacturing Restricted Substances List Zero Discharge of Hazardous Chemicals Programme